High efficient copper foil and producing method thereof
A manufacturing method and technology of copper foil, applied in the direction of printed circuit manufacturing, chemical instruments and methods, and improvement of metal adhesion of insulating substrates, can solve the problems of transmission loss deterioration and dependence, and achieve improvement of high-frequency transmission loss, high-viscosity The effect of bonding strength
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Embodiment 1
[0039] (1) Manufacturing conditions and electrolyte composition of electrolytic copper foil
[0040] As the production conditions of the electrolytic copper foil implemented in the present invention, the electrolyte composition and electrolytic conditions used for the production of the electrolytic copper foil are shown in Tables 3A to C (hereinafter referred to as Examples A to C), and also in Table 3 as a comparative example. D of Table 3 shows the composition of the electrolytic solution and the electrolysis conditions used for producing the untreated copper foil.
[0041] condition
copper
MPS
HEC
glue
Cl
A
90g / l
80g / l
0.8ppm
5ppm
40ppm
60A / dm 2
60℃
B
90g / l
80g / l
1ppm
5.5ppm
40ppm
60A / dm 2
60℃
C
90g / l
80g / l
1ppm
4ppm
2ppm
40ppm
60A / dm 2
60℃
...
Embodiment 2
[0067] (1) Foil-making conditions of untreated copper foil, surface plating type and adhesion amount (mg / dm 2 )
[0068] Untreated copper foil with a thickness of 35 μm was produced using the untreated copper foil foil-making conditions and solution composition of Example C and Comparative Example D of Example 1, and the surface treatment shown in Table 9 was performed.
[0069] (2) Performance
[0070] Table 10 shows the bonding strength between the treated Rz and the polyimide substrate of the surface-treated copper foil in Table 9.
[0071] Condition No.
[0072] C
[0073] As shown in Table 10, applying nickel plating, zinc plating, cobalt plating, alloy plating of these metals, chromate treatment and coupling agent treatment on untreated copper foil can improve heat resistance, HCl resistance, and rust resistance. force.
[0074] On the other hand, the results of measuring the transmission loss (dB / m) of the copper foil surface-treated under t...
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