Preparation method of room temperature cured high temperature tolerant flexible epoxy adhesive

A high temperature resistant, flexible epoxy technology, applied in the direction of adhesive type, adhesive, epoxy resin, etc., can solve the problem, can only be used in the environment of 100 ~ 150 ℃, can not meet the strength, can not be cured, etc. problems, to achieve the effect of simple and convenient use, high impact strength, and high use temperature

Inactive Publication Date: 2004-11-17
SICHUAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the performance of epoxy adhesives in the prior art is not ideal enough, that is, some have good flexibility and high impact strength, but poor temperature resistance, and can only be used in the environment of 100-150 ° C, and cannot be used in the environment. Long-term use at high temperatures; on the contrary, some have better high temperature resistance and can be used in high temperature environments, but the flexibility is very poor, and the impact strength at room temperature is less than 20MPa, which cannot meet the strength requirements. The flexibility is ok, but it cannot be cured at room temperature (25±5°C)
Therefore the epoxy adhesive of prior art can't be suitable for carrying out bonding operation at normal temperature, and the environment that service temperature and impact resistance requirements are relatively high, as many civil structures, train rail signal shielding, aerospace vehicle Component bonding in the fields of structure, drilling rig brake pads, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A. The composition of the toughening component and the temperature-resistant component in the adhesive component is calculated in parts by weight.

[0030] a. The composition of the toughening component:

[0031] Epoxy resin E51 100 parts

[0032] 20 parts of liquid-terminated carboxylated nitrile rubber

[0033] 30 parts liquid end hydroxy nitrile rubber

[0034] 4,4 diaminodiphenylmethane tetrafunctional epoxy resin 10 parts

[0035] b. Composition of temperature-resistant components:

[0036] Epoxy resin E20 80 parts

[0037] Temperature-resistant modifier 50 parts

[0038] Silicone resin 50 parts

[0039] Phenolic resin F648 48 parts

[0040] Among them, the silicone resin is synthesized and prepared by itself from 40 parts of diphenyldichlorosilane, 10 parts of dimethyldichlorosilane and 3 parts of boric acid.

[0041] B. The composition of the curing component in terms of the same weight unit parts is as follows:

[0042] a. Main curing agent

[0043] Po...

Embodiment 2

[0062] A. The composition of the toughening component, the temperature-resistant component and the plasticizer in the adhesive component are all calculated in the same weight unit.

[0063] a. The composition of the toughening component:

[0064] Epoxy Resin-E50 100 parts

[0065] Liquid end carboxyl nitrile rubber 40 parts

[0066] 4,4 diaminodiphenylmethane tetrafunctional epoxy resin 5 parts

[0067] Resorcinol functional epoxy resin 6 parts

[0068] b. Composition of temperature-resistant components:

[0069] Epoxy resin E20 90 parts

[0070] Silicone resin 60 parts

[0071] Phenolic resin F648 40 parts

[0072] c. Plasticizer

[0073] 2 parts dibutyl phthalate

[0074] B. The composition of the curing component in terms of the same weight unit parts is as follows:

[0075] a. Main curing agent

[0076] Polyetheramine 100 parts

[0077] b. Curing accelerator

[0078] Hexamethylenediamine 6 parts

[0079] Dicyandiamide 6 parts

[0080] 4 parts of 2-ethyl-methy...

Embodiment 3

[0087] A. The composition of the toughening component, the temperature-resistant component and the plasticizer in the adhesive component are all calculated in the same weight unit.

[0088] a. The composition of the toughening component:

[0089] Epoxy Resin-E51 100 parts

[0090] Liquid end carboxyl nitrile rubber 25 parts

[0091] 20 parts liquid end hydroxy nitrile rubber

[0092] 7 parts of 4,4 diaminodiphenylmethane tetrafunctional epoxy resin

[0093] Resorcinol difunctional epoxy resin 4 parts

[0094] b. Composition of temperature-resistant components:

[0095] Epoxy resin (E20) 100 parts

[0096] Silicone resin (self-synthesized) 60 parts

[0097] Phenolic resin (F648) 45 parts

[0098] Among them, the silicone resin is prepared by self-synthesis from 50 parts of diphenyldichlorosilane, 10 parts of dimethyldichlorosilane and 5 parts of boric acid.

[0099] c. Plasticizer

[0100] 5 parts dibutyl phthalate

[0101] B. The composition of the curing component i...

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Abstract

The invention discloses a preparation method of room temperature cured high temperature tolerant flexible epoxy adhesive, wherein the adhesive comprises a binding component and a hardening component, wherein the binding component includes flexibilizing constituent, heatproof constituent and plasticity agent, the hardening constituent comprises main hardening agent and hardening accelerating agent. The epoxy adhesive provided by the present invention has good tenacity and high binding strength.

Description

1. Technical field [0001] The invention relates to the technical field of adhesives, and more specifically relates to an epoxy adhesive prepared by mixing and preparing an adhesive component and a curing component when using epoxy resin as a base material and a preparation method thereof. 2. Background technology [0002] Epoxy adhesives with epoxy resin as the main component have high bonding strength and can be used for bonding between metal, ceramic, glass, wood, plastic and other material components. In the prior art, various epoxy adhesives with different properties have been developed according to the different use environments of the bonding parts, which have contributed to social and economic construction. However, the performance of epoxy adhesives in the prior art is not ideal enough, that is, some have good flexibility and high impact strength, but poor temperature resistance, and can only be used in the environment of 100-150 ° C, and cannot be used in the enviro...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J163/00
Inventor 孙杨宣包建军刘艳王晓青韩璐佟裕廷
Owner SICHUAN UNIV
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