Optical compensating sheet , polarizing plate and liquid crystal display device
A technology for optical compensation sheets and films, applied in the field of optical compensation sheets, can solve the problems of deterioration of optical properties, incomplete research on existing technologies, and reduction of strength.
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[0341] Next, a method for producing a thin film using a coating liquid in the present invention will be described. The preparation method and equipment of the polymer film can use the currently known solution casting film forming method and solution casting film forming device called the cylinder method or the conveyor belt method for the preparation of the polymer film.
[0342] The film forming process will be described. The coating solution (cellulose acylate solution) prepared in the dissolver (tank) is temporarily stored in the storage tank, and the final preparation is performed to defoam the coating solution containing air bubbles. It is important to remove aggregates and foreign matter by precise filtration of the prepared coating liquid. Specifically, it is preferable to use a filter having a pore size as small as possible within a range in which components in the coating liquid are not removed. Filtration uses a filter with an absolute filtration precision of 0.1 to...
Embodiment 1
[0730](Manufacture of cellulose acylate film)
[0731] The following composition was put into the mixing tank, and it stirred, heating, and each component was dissolved, and the cellulose acylate solution was prepared.
[0732] Composition of cellulose acylate solution
[0733] 100 parts by mass of cellulose acetate with a degree of acetylation of 60.9%
[0734] Triphenyl phosphate (plasticizer) 7.8 parts by mass
[0735] Diphenyl diphenyl phosphate (plasticizer) 3.9 parts by mass
[0736] Dichloromethane (the first solvent) 295 parts by mass
[0737] Methanol (the second solvent) 68 parts by mass
[0738] 1-butanol (the third solvent) 2 parts by mass
[0739] In another mixing tank, 16 parts by mass of the following delayed rising agent, 80 parts by mass of methylene chloride, and 20 parts by mass of methanol were charged and stirred while heating to prepare a delayed rising agent solution.
[0740] delayed ascension agent
[0741]
[0742] 474 parts by mass of the ...
Embodiment 2
[0762] (Manufacture of cellulose acylate film)
[0763] The following composition was put into the mixing tank, and it stirred, heating, and each component was dissolved, and the cellulose acylate solution was prepared.
[0764] Composition of cellulose acylate solution
[0765] 100 parts by mass of cellulose acetate with an acetylation degree of 60.7%
[0766] Polyether urethane (plasticizer) 16 parts by mass
[0767] (B-236, Sumitomo Bayeruretan Co., Ltd., Desumoko-ru176)
[0768] Dichloromethane (the first solvent) 290 parts by mass
[0769] Methanol (the second solvent) 73 parts by mass
[0770] 1-butanol (the third solvent) 2 parts by mass
[0771] In another mixing tank, 16 parts by mass of the delayed rising agent used in Example 1, 80 parts by mass of methylene chloride, and 20 parts by mass of methanol were charged, stirred while heating, and a delayed rising agent solution was prepared.
[0772] 484 parts by mass of the cellulose acylate solution and 15 parts b...
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