High petential magnesium alloy sacrificial anode material and its manufacturing method

A sacrificial anode and magnesium alloy technology, which is applied in the field of high-potential casting magnesium sacrificial anode materials, can solve the problems of complex manufacturing process, low current efficiency and high production cost, and achieve the effects of simple manufacturing process, low cost and convenient industrial production.

Inactive Publication Date: 2006-01-11
TAIYUAN UNIV OF TECH
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AI-Extracted Technical Summary

Problems solved by technology

But the disadvantage is that their current efficiency is not high, generally only about 50%
[0006] Magnesium alloy sacrificial anodes are divided into low potential and high potential. As high potential magnesium alloy sacrificial anodes, Mg-Mn al...
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Method used

The structure characteristic of this high-potential magnesium alloy sacrificial anode material is that in the crystal grain interior of α-Mg, there are fine Mn phase particles dispersedly distributed, and there are...
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Abstract

A high-potential Mg alloy used as consumable anode for the underground oil or gas pipeline, storage tank and water pipe is prepared through micro-alloying the Mg-Mn alloy by Mg-Ca and Mg-RE intermediate alloys, and refining by use of special refining agent to obtain Mg MnRECa alloy, which contains proportionally Mn, Ce, Ca, Si, Cu, Ni, Fe and Mg. Its advantages are high open-circuit potential 1.7-1.8 (-V) and high current efficiency (55-60%).

Technology Topic

High potentialGas pipeline +8

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  • High petential magnesium alloy sacrificial anode material and its manufacturing method
  • High petential magnesium alloy sacrificial anode material and its manufacturing method
  • High petential magnesium alloy sacrificial anode material and its manufacturing method

Examples

  • Experimental program(3)

Example Embodiment

[0023] Implementation mode 1:
[0024] The chemical composition of the high potential magnesium alloy sacrificial anode material (by mass percentage wt%) is: Mn0.500%, Ce1.000%, Ca0.010%, Si≤0.050%, Cu≤0.020%, Ni≤0.001%, Fe ≤0.030%, the rest is Mg.
[0025] I. Preparation, 1# magnesium ingot 88%, electrolytic manganese 4%, Mg-Ca (containing Ca20%) master alloy 5% and Mg-RE (containing Ce50%) master alloy 3% and preheating and baking; II. Put magnesium in SF 6 +CO 2 After melting under gas protection, add electrolytic manganese and NaF flux 5%/(accounting for manganese addition) at 780°C, add appropriate amount of Mg-Ca and Mg-RE master alloy for alloying treatment after holding at 760°C for 10 minutes; III .When the melt temperature is controlled at 760℃, add 1.00% of the melt weight of the magnesium sacrificial anode self-made special refining agent (calculated as the mass percentage wt%: MgCl 2 20%, KCl25%, BaCl 2 14%, MgF 2 15%, CaF 2 16%, NaF10%) for refining; IV. Let it stand for 40 minutes, and after the detected components are qualified, it is poured into a metal mold within a temperature range of 760°C to solidify and form.
[0026] The structure of this high-potential magnesium alloy sacrificial anode material is characterized by the dispersion of fine Mn phase particles within the grains of α-Mg, and the presence of Mg on the grain boundaries. 2 Ca and Mg 2 The particles and grain structure of the Ce phase are all formed by equiaxed crystals (as shown in Figure 1), the potential is 1.7 (-V), and the current efficiency is 55%.

Example Embodiment

[0027] Implementation mode 2:
[0028] The chemical composition of the high potential magnesium alloy sacrificial anode material (by mass percentage wt%) is: Mn2.000%, Ce0.100%, Ca0.500%, Si≤0.050%, Cu≤0.020%, Ni≤0.001%, Fe ≤0.030%, the rest is Mg.
[0029] I. Prepare materials, weigh 93% of 1# magnesium ingot, 2% of electrolytic manganese, 2% of Mg-Ca3% and Mg-RE master alloy and preheat and bake; II. Put magnesium in SF 6 +CO 2After melting under gas protection, add electrolytic manganese and NaF flux 10%/(manganese addition) at 800°C, add appropriate amount of Mg-Ca and Mg-RE master alloy for alloying treatment after holding at 780°C for 15 minutes; III. When the temperature of the melt is controlled at 780°C, add a special self-made refining agent for magnesium sacrificial anode of 1.50% by weight of the melt (calculated by mass percentage wt% as: MgCl 2 30%, KCl21%, BaCl 2 11%, MgF 2 10%, CaF220%, NaF8%) for refining; IV. Let it stand for 60 minutes, and after the detected composition is qualified, it is poured into a metal mold at a temperature of 740°C to solidify and form.
[0030] The structure of this high-potential magnesium alloy sacrificial anode material is characterized by the dispersion of fine Mn phase particles within the grains of α-Mg, and the presence of Mg on the grain boundaries. 2 Ca and Mg 2 The particles and grain structure of the Ce phase are all formed by equiaxed crystals (as shown in Figure 2), the potential is 1.80 (-V), and the current efficiency is 60%.

Example Embodiment

[0031] Implementation mode 3:
[0032] The chemical composition of the high potential magnesium alloy sacrificial anode material (by mass percentage wt%) is: Mn1.000%, Ce0.600%, Ca1.000%, Si≤0.050%, Cu≤0.020%, Ni≤0.001%, Fe ≤0.030%, the rest is Mg.
[0033] I. Prepare materials, weigh 97% of 1# magnesium ingot, 1% of electrolytic manganese, 1% of Mg-Ca and Mg-RE master alloy and preheat and bake; II. Put magnesium in SF 6 +CO 2 After melting under gas protection, add electrolytic manganese and NaF flux 7.5%/(addition of manganese) at 790°C, add appropriate amount of Mg-Ca and Mg-RE master alloy for alloying treatment after holding at 770°C for 12 minutes; III. When the melt temperature is controlled at 770°C, 1.25% of the melt weight is added to the self-made special refining agent for magnesium sacrificial anode (calculated by mass percentage wt%: MgCl 2 28%, KCl16%, BaCl 2 18%, MgF 2 20%, CaF 2 12%, NaF6%) for refining; IV. Let it stand for 50 minutes, and after the detected components are qualified, it is poured into a metal mold within a temperature range of 750° C. to solidify and form.
[0034] The structure of this high-potential magnesium alloy sacrificial anode material is characterized by the dispersion of fine Mn phase particles within the grains of α-Mg, and the presence of Mg on or near the grain boundaries. 2 Ca and Mg 2 The particles and grain structure of the Ce phase are all formed by equiaxed crystals (as shown in Figure 3), the potential is 1.75 (-V), and the current efficiency is 58%.

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