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Waste vitriol re-use technics and apparatus for accumulator plate product

A waste sulfuric acid and storage battery technology, which is applied in the direction of lead-acid battery electrodes, battery recycling, recycling technology, etc., can solve the problems that battery plates cannot meet the requirements of environmental protection and production water reuse, high cost of environmental protection treatment, and affect the beauty of the site. , to achieve the effect of improving the comprehensive utilization rate, improving the level of environmental protection and economic benefits, and reducing the purchase cost

Inactive Publication Date: 2006-01-18
郝华
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AI Technical Summary

Problems solved by technology

In order to reduce environmental pollution, production companies and environmental protection departments use a large amount of caustic soda as a neutralizer in wastewater treatment. The problems are: first, the cost of environmental protection treatment is high in terms of funds, sites, and personnel; second, wastewater treatment stations It contains sodium sulfate, which will crystallize when its concentration reaches 10,000-20,000 mg / l. If the outbound water is reused for land flushing, greening, or as circulating water, white crystals will appear after the water evaporates, which will affect the The beauty of the venue
If it is discharged directly, it will cause environmental pollution
[0004] Therefore, with the continuous expansion of production scale, the original equipment of battery plate manufacturers cannot meet the requirements of environmental protection and production water reuse

Method used

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  • Waste vitriol re-use technics and apparatus for accumulator plate product
  • Waste vitriol re-use technics and apparatus for accumulator plate product
  • Waste vitriol re-use technics and apparatus for accumulator plate product

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[0033] 1) In the acid leaching process, after the waste acid solution is precipitated in a three-stage sedimentation tank, microfiltration or ultrafiltration membranes are used to treat the acid leaching process in the plate production (some battery plate manufacturers have no leaching acid process section) Waste acid liquid, the waste acid liquid is pumped into the microfiltration or ultrafiltration membrane circulation treatment unit, the concentrated liquid is discharged into the sewage treatment station of the factory for treatment or exported, and the filtrate is pumped into the circulation tank for storage; the waste acid liquid The concentration of iron ions in the medium is unstable. The microfiltration or ultrafiltration membrane treatment unit is mainly used as the pretreatment unit of the nanofiltration membrane treatment unit equipment to remove solids and suspended substances such as lead powder, lead oxide and lead sulfate in the waste sulfuric acid of leaching ac...

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Abstract

This invention relates to a process for recycling waste sulphuric acid in course of making accumulator pole plate and its device, comprising recycling lead by adding acid and fractional precipitation, alkali neutralization, chemical reaction and waste sulphuric acid transmission, and using the first and second films separating method to comprehensively treat waste sulphuric acid brought from drenching acid and chemical reaction. The invention has the advantages of lower production cost, saving water in maximum extent and improving the condition of water usage in factory district, improving environment protection level and economical benefit.

Description

technical field [0001] The invention relates to a technology and equipment for recycling waste sulfuric acid in the production of storage battery pole plates. Background technique [0002] At present, in the production of lead-acid battery plates at home and abroad, most of the dilute sulfuric acid is used in the chemical formation process, the leaching process and the chemical formation process (see image 3 ), the production of a large amount of waste sulfuric acid mostly takes the method of adding caustic soda to neutralize the waste acid or transporting it out. Due to the lack of economical and effective treatment methods for the reuse of sulfuric acid, it leads to waste of financial resources and manpower, low utilization rate of sulfuric acid, high cost of transportation, and causes the intermediate raw materials of the plate production process to consume a large amount of purchase costs and occupy a large amount of resources. Environmental protection resources at the ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/54H01M4/16
CPCY02E60/126Y02E60/10Y02W30/84
Inventor 郝华
Owner 郝华
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