Process for comprehensive using waste water of phosphatic fertilize and phosphorous chemical industrial
A technology for industrial wastewater and phosphorus chemical industry, which is applied in chemical instruments and methods, water/sewage treatment, phosphate material treatment, etc. It can solve the problems of patent applications and reports of no substitute for pH adjusters, and achieve economical treatment. cost, cost-saving effect
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Embodiment 1
[0015] Implementation 1: Operate according to the following steps to process phosphate rock with low carbonate content:
[0016] (1) Grinding or grinding the carbonate-type phosphate rock containing 3% (mass fraction) of MgO until the mineral monomers are dissociated, adding clear water and stirring to adjust the mineral content to 40%;
[0017] (2) Add acid waste water: raw ore at a ratio of 0.5:1, stir well, and adjust the pH value of the slurry to 3-5.
[0018] (3) The adjusted ore pulp enters the flotation machine, and the flotation collector is added at the same time. After aeration and scraping, the phosphorus concentrate with an MgO content of 0.5% (mass fraction) can be obtained, and the phosphorus concentrate is useful The component recovery rate reaches more than 94%.
Embodiment 2
[0019] Implementation 2: operate according to the following steps to process phosphate rock with higher carbonate content:
[0020] (2) Grinding or grinding the carbonate-type phosphate rock containing 8% (mass fraction) of MgO until the mineral monomers are dissociated, adding clear water and stirring to adjust the mineral content to 40%;
[0021] (2) Add acid waste water: raw ore at a ratio of 0.7:1, stir well, and adjust the pH value of the slurry to 3-5.
[0022] (3) The adjusted ore pulp enters the flotation machine, and the flotation collector is added at the same time. After aeration and scraping, the phosphorus concentrate with an MgO content of 0.5% (mass fraction) can be obtained, and the phosphorus concentrate is useful The component recovery rate reaches more than 91%.
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