Flexible printed wiring board and manufacturing method thereof
A flexible printing and circuit board technology, which is applied in the fields of printed circuit, printed circuit, multi-layer circuit manufacturing, etc., can solve the problem of low flexibility and achieve the effect of excellent dimensional stability
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[0042] Hereinafter, based on an Example and a comparative example, embodiment of this invention is demonstrated concretely. In the following examples, the coefficient of thermal expansion, the curl and adhesion of single-sided copper-clad products, and the curl of the film were measured by the methods described below.
[0043] That is, the thermal expansion coefficient is calculated by using a thermomechanical analyzer (TMA100) manufactured by Seiko Electronics Co., Ltd., after heating up to 250°C, cooling at a rate of 10°C / min, and calculating the average linear expansion coefficient between 240°C and 100°C And asked for.
[0044] The curling of single-sided copper-clad products is to measure the radius of curvature of copper-clad products with a size of 100mm×100mm after heat treatment and imidization.
[0045] The adhesive strength of single-sided copper-clad products is the value (kg / cm) obtained when the copper foil is peeled off at a speed of 50 mm / min in a direction of...
Synthetic example 1
[0053] 2532 g of N,N-dimethylacetamide was put into a glass reactor while blowing nitrogen gas, then 0.5 mol of DDE and 0.5 mol of MABA were added with stirring, and then completely dissolved. The solution was cooled to 10° C., and 1 mol of PMDA was added little by little to keep the reaction solution at a temperature of 30° C. or less. After the addition was completed, stirring was continued at room temperature for 2 hours to complete the polymerization reaction. The obtained polyimide precursor solution had a polymer concentration of 15% by weight, and an apparent viscosity measured at 25° C. with a B-type viscometer was 1000 mPa·s.
Synthetic example 2
[0055] Except having used 1 mol of DDE as a diamine component, and having used 1 mol of BTDA as an acid anhydride component, it carried out similarly to the synthesis example 1, and prepared the polyimide precursor solution. The obtained polyimide precursor solution had a polymer concentration of 15% by weight, and an apparent viscosity measured at 25° C. with a B-type viscometer was 300 mPa·s.
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