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Heavy oil refining method

Inactive Publication Date: 2004-09-02
JGC CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0009] As a result of significant research to attain the object described above, the inventors have discovered that impurities in heavy oil can be efficiently removed to obtain a high quality refined oil having impurities removed to a high degree by using as a feedstock a heavy oil having a hydrogen content of 12 wt % or less, processing the heavy oil so that the hydrogen content is increased by a certain amount or greater by using a solvent extraction, and then processing the obtained deasphalted oil so that the hydrogen content is increased by a certain amount or greater by using a hydrorefining process.

Problems solved by technology

In contrast, residue oils, that is, bottom oils remained at a tower by distillation, have impurities concentrated and they exist in a state that makes them extremely difficult to remove.
In the case of a particularly high degree of refining, severe reaction conditions including high temperature and high pressure in the presence of hydrogen and a catalyst are necessary, a large amount of hydrogen and catalyst are consumed, and large investments including facilities expenses are necessary.
Thus, at present this is not economical.
Vacuum gas oil, whose molecular weight is higher than naphtha and contains much sulfur, is used as a feedstock for an ethylene plant, and is considered to be the limit for commercial operation.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

experimental example 1

[0055] A heavy oil, which is a residue having an API gravity of 14.3 (a hydrogen content of 11.25 wt %; a Ni+V metal content of 65 wtppm; a Conradson carbon residue (below, abbreviated "CCR") of 11.1 wt %; and a S content of 3.95 wt %) is charged into the solvent extraction process unit as a feed oil, and using a normal pentane solvent (a solvent / oil ratio of 8 / 1), a deasphalted oil (below, abbreviated "DAO") is obtained by extraction and separation so that the extraction rate is 81 wt %, subsequently this DAO is subject to a refining process under the following hydrorefining conditions, and thereby the refined oil 1 of the present invention is obtained.

[0056] Hydrorefining conditions: Ni / Mo+Ni / Co / Mo catalyst (a specific volume ratio of 1 / 9), a hydrogen partial pressure of 90 atm; an H.sub.2 / Oil ratio of 600 Nm.sup.3 / kl; a temperature of 380.degree. C.; and an LHSV of 0.5 (1 / hr).

[0057] The yield of the obtained DAO and the refined oil with respect to the feed oil, the hydrogen conte...

experimental example 2

[0058] The feed oil used in Experimental Example 1 is charged into the solvent extraction process unit, using a normal pentane solvent (a solvent / oil ratio of 8 / 1), the DAO is obtained by extraction and separation so as to attain an extraction rate of 84 wt %, and subsequently the DAO is subject to hydrorefining under conditions identical to those of Experimental Example 1 to obtain the refined oil 2 of the present invention.

[0059] The yield of the obtained DAO and the refined oil 2 with respect to the feed oil, the hydrogen content, the amount of increase in the hydrogen content in each process, the V+Ni content, the CCR, and the sulfur content are shown in Table 1.

experimental example 3

[0060] The feed oil used in Experimental Example 1 is charged into the solvent extraction process unit, using a normal pentane solvent (a solvent / oil ratio of 8 / 1), the DAO is obtained by extraction and separation so as to attain an extraction rate of 84 wt %, and subsequently the DAO is subject to a refining process under the following hydrorefining conditions to obtain the refined oil 3 of the present invention.

[0061] Hydrorefining conditions: Ni / Mo+Ni / Co / Mo catalyst (a specific volume ratio of 1 / 9), a hydrogen partial pressure of 85 atm; an H.sub.2 / Oil ratio of 600 Nm.sup.3 / kl; a temperature of 360.degree. C.; and an LHSV of 0.5 (1 / hr).

[0062] The yield of the obtained DAO and the refined oil 3 with respect to the feed oil, the hydrogen content, the amount of increase in the hydrogen content in each process, the V+Ni content, the CCR, and the sulfur content are shown in Table 1.

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Abstract

A refined oil is obtained by using a heavy oil having a hydrogen content of 12 wt % or less as a feed oil, and after carrying out a solvent extraction process such that the hydrogen content increases by 0.2 wt % over that of the feed oil, hydrorefining process is carried out such that the hydrogen content increases by 0.5 wt % over the extracted oil. Thereby, an inexpensive heavy oil can be used as a feedstock, and using a simple and reliable method, refined oil can be produced.

Description

[0001] The present invention relates to a refining method for heavy oil that can efficiently remove impurities derived from a crude oil by a solvent extraction process and a hydrorefining process, and in particular, to a method that can obtain a refined oil that is suitable as a feedstock for light olefin production from a heavy oil that could not be conventionally used as feedstock for light olefin production.[0002] Because of the presence of impurities originating from the source of the crude oil, oil products that have crude oil as a starting material are produced by implementing various types of physical and chemical refining processes, starting with atmospheric fractional distillation.[0003] Generally, distillate, that is, distillated oils drawn off from a tower by distillation, have minute amounts of the impurities and these impurities can be removed by a simple refining process. Thereby, they can be used s for automobile fuel, gas turbine fuel, petrochemical feedstock, or the...

Claims

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Application Information

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IPC IPC(8): C10G1/04C10G49/04C10G67/04C10G69/06
CPCC10G67/04C10G2400/20C10G67/049C10G67/0463C10G21/00
Inventor INOMATA, MAKOTOOKADA, TSUYOSHIHIGASHI, AKIRASASAKI, HAJIMEKASAHARA, SUSUMUFUJIMURA, YASUSHI
Owner JGC CORP
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