Unlock instant, AI-driven research and patent intelligence for your innovation.

Sputtering target, Al wiring film and electronic component

a technology of wiring film and sputtering target, which is applied in the direction of metallic material coating process, solid-state device, foundry mould, etc., can solve the problems of dust or splash, difficult to obtain sputtering film, and complicated structure of sputtering film, so as to suppress the formation of giant dust particles

Inactive Publication Date: 2005-11-17
KK TOSHIBA
View PDF5 Cites 5 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The solution significantly improves the yield and quality of Al wiring films by reducing defects and ensuring high denseness and orientation, while maintaining low resistance and excellent hillock resistance, thus enhancing the reliability of electronic components.

Problems solved by technology

Such protrusions, when generated in the Al wiring, adversely affect on the later process to cause problems.
Now, as higher integration, higher reliability and higher functionality of electronic devices such as semiconductor elements proceed, the structure thereof has become more complicated.
Since such sputtering films are difficult to obtain by use of the existing general sputtering methods, new sputtering methods such as long throw sputtering or reflow sputtering are being adopted.
In sputtering by the general sputtering method, when segregation or internal defect exists in a target, dust or splash may occur due to an extraordinary electric discharge or the like.
These cause defects during formation of DRAMs or TFT elements.
Further, in the long throw sputtering or reflow sputtering, there occur a problem that concavities or holes of relatively larger size occur in the sputtering films.
Accordingly, the yield of electronic devices such as DRAMs or TFT elements is deteriorated.
The existing dust preventive measure can not prevent the aforementioned giant dust particles or relatively large size concavities from occurring.
However, there is a problem that a generated intermetallic compound can adversely affect on etching property of the Al wiring.
This is largely detrimental in forming the fine wiring network.
The new defect modes occur in particular, when the new sputtering methods such as long throw sputtering or reflow sputtering are employed.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

embodiment 1

[0093] First, 0.5% by weight of Cu with respect to Al is compounded with Al. An ingot of intended composition is produced by use of continuous casting method (atmospheric fusion). The ingot undergoes hot rolling, cold rolling and heat treatment. Thereafter, by machining the ingot an Al alloy target of a diameter of 320 mm and a thickness of 20 mm is prepared. At this time, by varying each condition of hot rolling, cold rolling and heat treatment, 10 pieces of Al alloy targets different in dispersion degree of Cu are obtained. The dispersion degree of Cu is measured and evaluated by use of the EPMA apparatus shown in the aforementioned Table 1.

[0094] The dispersion degree of Cu is shown in Table 3. The dispersion degree of Cu, in the mapping of EPMA analysis, shows an area ratio (%) of a portion of which count number of detection sensitivity is 22 or more in a measurement area of 20×20 μm, and, an area ratio (%) of a portion of which count number is 22 or more in an observation area...

embodiment 2

[0097] With 10 pieces of Al alloy targets prepared in the embodiment, except for changing the sputtering method to reflow sputtering, under identical conditions as those of embodiment 1, Al alloy films are formed and the number of dust particles is similarly measured. The results are shown in Table 4.

TABLE 4DispersionDegree of CuDust SizeSample20 ×200 ×Under0.2 to0.3 toOverNo.20 μm200 μm0.2 μm0.3 μm100 μm100 μm135.60.295100212.41.8842038.53.81121041.31.59800521.90.67410670.159.41528935890788.568.71886760498875.474.12328251730989.887.3132956310891083.469.41207799573

[0098] As obvious from Table 4, according to the sputtering targets of the present invention, the dust particles of a size of 0.3 μm or more are also suppressed from occurring. In particular, the giant dust particles that cause problems in the reflow sputtering or the like are suppressed from occurring. The Al alloy films formed by use of such sputtering targets can remarkably improve the product yield based on the decre...

embodiment 3

[0099] To Al, various kinds of elements (Si, Cr, Y, Ni, Nd, Pt, Ir, Ta, W and Mo) are added with the respective compounding amounts shown in Table 5. The respective compounded bodies are treated by use of continuous casting method (atmospheric fusion) to prepare ingots of intended compositions. Each of the ingots undergoes hot rolling, cold rolling and heat treatment. Thereafter, due to machining, Al alloy targets of a diameter of 320 mm and a thickness of 20 mm are prepared. At this time, by selecting properly the respective conditions of hot rolling, cold rolling and heat treatment, the dispersion degree of the added elements are controlled within the range stipulated by the present invention. The dispersion degrees of the respective added elements are measured similarly with embodiment 1.

[0100] With the respective Al alloy targets thus obtained, due to the reflow sputtering method, on each Si substrate of a diameter of 8 inches, an Al alloy film of a thickness of 300 nm is forme...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
sizeaaaaaaaaaa
widthaaaaaaaaaa
diameteraaaaaaaaaa
Login to View More

Abstract

A sputtering target consists essentially of 0.1 to 50% by weight of at least one kind of element that forms an intermetallic compound with Al, and the balance of Al. The element that forms an intermetallic compound with Al is uniformly dispersed in the target texture, and in a mapping of EPMA analysis, a portion of which count number of detection sensitivity of the element is 22 or more is less than 60% by area ratio in a measurement area of 20×20 μm. According to such a sputtering target, even when a sputtering method such as long throw sputtering or reflow sputtering is applied, giant dusts or large concavities can be suppressed in occurrence.

Description

TECHNICAL FIELD [0001] The present invention relates to a sputtering target suitable for formation of wiring of low resistance, an Al wiring film using the same, and electronic components comprising the Al wiring film such as semiconductor elements, liquid crystal display devices, surface acoustic wave devices or the like. BACKGROUND ART [0002] Recently, semiconductor industry typical in LSI is rapidly advancing. In semiconductor elements such as DRAMs, as higher integration and reliability advance, accuracy required for fine machining is also getting higher and higher. Further, for also sputtering targets being employed in forming wiring or the like, a more homogeneous metallic layer is demanded to form. [0003] Among various kinds of metals for formation of the wiring, aluminum (Al) is attracting attention as formation material of low resistance wiring. Al is also expected as a wiring film being used as gate lines and signal lines of a TFT drive type liquid crystal display device (...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(United States)
IPC IPC(8): B22C1/00C22C21/00C22C21/02C22C21/04C22C21/12C22C21/14C22C27/00C22F1/00C22F1/04C23C14/32C23C14/34H01L21/285H01L21/3205H01L21/768H01L23/12H01L23/532
CPCC22C21/00C22F1/04C23C14/3414H01L21/2855H01L21/32051Y10T428/10H01L23/53219H01L2924/0002H01L21/76838H01L2924/00C09K2323/00
Inventor WATANABE, KOICHIISHIGAMI, TAKASHI
Owner KK TOSHIBA