Sputtering target, Al wiring film and electronic component
a technology of wiring film and sputtering target, which is applied in the direction of metallic material coating process, solid-state device, foundry mould, etc., can solve the problems of dust or splash, difficult to obtain sputtering film, and complicated structure of sputtering film, so as to suppress the formation of giant dust particles
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embodiment 1
[0093] First, 0.5% by weight of Cu with respect to Al is compounded with Al. An ingot of intended composition is produced by use of continuous casting method (atmospheric fusion). The ingot undergoes hot rolling, cold rolling and heat treatment. Thereafter, by machining the ingot an Al alloy target of a diameter of 320 mm and a thickness of 20 mm is prepared. At this time, by varying each condition of hot rolling, cold rolling and heat treatment, 10 pieces of Al alloy targets different in dispersion degree of Cu are obtained. The dispersion degree of Cu is measured and evaluated by use of the EPMA apparatus shown in the aforementioned Table 1.
[0094] The dispersion degree of Cu is shown in Table 3. The dispersion degree of Cu, in the mapping of EPMA analysis, shows an area ratio (%) of a portion of which count number of detection sensitivity is 22 or more in a measurement area of 20×20 μm, and, an area ratio (%) of a portion of which count number is 22 or more in an observation area...
embodiment 2
[0097] With 10 pieces of Al alloy targets prepared in the embodiment, except for changing the sputtering method to reflow sputtering, under identical conditions as those of embodiment 1, Al alloy films are formed and the number of dust particles is similarly measured. The results are shown in Table 4.
TABLE 4DispersionDegree of CuDust SizeSample20 ×200 ×Under0.2 to0.3 toOverNo.20 μm200 μm0.2 μm0.3 μm100 μm100 μm135.60.295100212.41.8842038.53.81121041.31.59800521.90.67410670.159.41528935890788.568.71886760498875.474.12328251730989.887.3132956310891083.469.41207799573
[0098] As obvious from Table 4, according to the sputtering targets of the present invention, the dust particles of a size of 0.3 μm or more are also suppressed from occurring. In particular, the giant dust particles that cause problems in the reflow sputtering or the like are suppressed from occurring. The Al alloy films formed by use of such sputtering targets can remarkably improve the product yield based on the decre...
embodiment 3
[0099] To Al, various kinds of elements (Si, Cr, Y, Ni, Nd, Pt, Ir, Ta, W and Mo) are added with the respective compounding amounts shown in Table 5. The respective compounded bodies are treated by use of continuous casting method (atmospheric fusion) to prepare ingots of intended compositions. Each of the ingots undergoes hot rolling, cold rolling and heat treatment. Thereafter, due to machining, Al alloy targets of a diameter of 320 mm and a thickness of 20 mm are prepared. At this time, by selecting properly the respective conditions of hot rolling, cold rolling and heat treatment, the dispersion degree of the added elements are controlled within the range stipulated by the present invention. The dispersion degrees of the respective added elements are measured similarly with embodiment 1.
[0100] With the respective Al alloy targets thus obtained, due to the reflow sputtering method, on each Si substrate of a diameter of 8 inches, an Al alloy film of a thickness of 300 nm is forme...
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Abstract
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