Iron-based brazing filler metals

a filler metal and iron-based technology, applied in the direction of manufacturing tools, lighting and heating equipment, soldering apparatus, etc., can solve the problems of significant replacement device and associated labor costs, adversely affecting the propensity of stainless steel to leach, and poor corrosion resistance of heat exchangers using copper as the brazing filler metal. , to achieve the effect of low nickel leaching rate and effective general corrosion resistan

Inactive Publication Date: 2006-05-04
METGLAS INC
View PDF5 Cites 21 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0013] The present invention provides a method to fabricate heat exchangers and other articles of manufacture by brazing components thereof with an iron-based brazing filler metal composition. Brazed assemblies advantageously exhibit effective general corrosion resistance and low rates of leaching of nickel into fluids passing through either side of the heat exchanger. As a result, the heat exchanger is highly suited for exposure to items intended for ingestion by humans or animals.
[0014] In a first aspect, the present invention provides a method to manufacture assemblies, especially assemblies which include parts comprising stainless steels. Such assemblies comprise parts joined using iron-based brazing filler metals. When manufactured, the assemblies are characterized by general corrosion resistance and by low leaching rates of nickel. The method comprises: juxtaposing at least two parts to define one or more joints therebetween; supplying to the one or more joints an iron-based brazing filler metal composition that is a ductile, amorphous brazing foil; heating the juxtaposed parts and the brazing filler metal to cause melting of the iron-based brazing filler metal; and cooling the melted iron-based brazing filler metal to produce a brazed joint that minimizes an amount of nickel leaching into a fluid contacting the brazed joint. The heating and cooling operations are generally carried out either in a protective gas atmosphere or in a vacuum.

Problems solved by technology

However, brazing manufacturing processes carried out at high temperatures may also adversely affect the propensity of the stainless steels to leach.
However, the corrosion resistance of heat exchangers having components brazed using copper as the brazing filler metal is poor.
Typically, such heat exchangers required frequent replacement, resulting in significant costs for the replacement device and the associated labor, as well as economic losses resulting from manufacturing downtime.
Unfortunately, it was also found that when such nickel-based brazing filler metals were used, an undesirably high amount of nickel often leached into water or other fluids flowing through such assemblies.
Not surprisingly, governmental regulations in some countries have imposed strict limitations on the amount of nickel which may be leached into fluids for human ingestion or consumption.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Iron-based brazing filler metals
  • Iron-based brazing filler metals
  • Iron-based brazing filler metals

Examples

Experimental program
Comparison scheme
Effect test

example 1

Preparation of Iron-based Brazing Filler Metal Strip

[0047] Strips of about 2.5 to 25 mm (about 0.10 to 1.00 inch) width and about 18 to 50 μm (about 0.0007 to 0.002 inch) thick are formed by squirting a melt of a preselected composition, such as the composition with the formula FeaCrbBcSidXe noted above, by overpressure of argon onto a rapidly rotating copper chill wheel (surface speed about 3000 to 6000 ft / min.). Metastable, ductile, homogeneous ribbons of substantially glassy alloys comprising essentially the compositions (atom percent) set forth in Table I are produced, wherein “bal.” for iron indicates a balance (100% minus the values stated for other components of the composition).

TABLE IFeCrCoNiMoWBSialloy 1bal.2.0156alloy 2bal.119alloy 3bal.1010alloy 4bal.1510alloy 5bal.1210

example 2

Characterization of Iron-based Brazing Filler Metal Strip

[0048] The liquidus and solidus temperatures of selected ribbons having compositions set forth in Table I are determined by a Differential Thermal Analysis (DTA) Technique. The individual samples are heated side by side with an inert reference material at a uniform rate, and a temperature difference between the individual sample and the inert reference material is measured as a function of temperature. A resulting curve, conventionally known as a thermogram, is a plot of relative changes in the temperatures of the sample and the reference materials during simultaneous heating vs. temperature, from which the beginning of melting and end of melting, which represent the solidus and liquidus temperatures, respectively, are determined. Values thus determined are set forth in Table II below.

TABLE IISolidusLiquidusalloy 11174° C. (2145° F.)1182° C. (2157° F.)alloy 21138° C. (2080° F.)1168° C. (2134° F.)alloy 31151° C. (2104° F.)1...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
thicknessaaaaaaaaaa
liquidus temperatureaaaaaaaaaa
liquidus temperatureaaaaaaaaaa
Login to view more

Abstract

A plurality of parts is brazed using an iron-based brazing filler metal. The parts generally include stainless steel, and the brazed assembly forms a heat exchanger characterized by effective corrosion resistance and low rates of leaching of nickel into fluids passing therethrough. The heat exchanger is especially suited for use in processing items intended to be ingested by humans or animals.

Description

BACKGROUND OF THE INVENTION [0001] 1. Field of the Invention [0002] The present invention relates to brazing of metal parts, and more particularly, to a homogeneous, ductile iron-based brazing material useful in brazing stainless steels, and a method for brazing stainless steel components to form articles of manufacture, wherein the brazed stainless steel components reduce the propensity of nickel to leach from such articles in water. [0003] 2. Description of the Prior Art [0004] Brazing is a process for joining metal parts, often of dissimilar composition, to each other. Typically, a filler metal that has a melting point lower than that of the metal parts to be joined together is interposed between the metal parts to form an assembly. The assembly is then heated to a temperature sufficient to melt the filler metal. Upon cooling, a strong, leak-tight joint is formed. The assembled parts may either constitute a finished article of manufacture or may form a sub-component for use in a ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(United States)
IPC IPC(8): C22C45/02
CPCB23K1/0012B23K2201/14C22C45/02F28D7/16F28D9/0037F28F3/025F28F9/0219F28F9/18B23K2101/14
Inventor RABINKIN, ANATOLDECRISTOFARO, NICHOLAS J.
Owner METGLAS INC
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products