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Polyether-containing copolymer

a polyether and copolymer technology, applied in the field of polyether-containing copolymers, can solve the problems of mixing not being able to remain, slowing down the work on the job, and affecting the characteristics of the final hardened product,

Inactive Publication Date: 2006-12-14
BASF CONSTR POLYMERS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0019] In general, the workability of gypsum, but also of other hydraulic binders, can be improved under hydraulic aspects by adding dispersants. In this connection, the copolymers according to this invention represent suitable dispersants because of their dispersing properties.

Problems solved by technology

On the other side, the cement mixture cannot remain fluid for a too long time, that means the set must not greatly be retarded, because this will slow down the work on the job and show negative influences on the characteristics of the final hardened products.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example 1

[0042] To a 1 liter four necked glass flask with a temperature controller, a reflux condenser and two dropping funnels 350 g water, 350 g (0.06 mol) of polyethylene glycol-5800-monovinylether and 4 g of a propylene oxide / ethylene oxide(PO-EO)-block polymer with a molecular mass of 2,000 g / mol (“defoamer”) and 25 g NaOH (20%) have been added. A mixture comprising 45 g (0.63 mol) of acrylic acid in 17 g water has been produced separately and 15 g of this mixture has been added to the polyethylene glycol-5800-monovinylether solution in the flask; the pH decreased to 8.0. Then 40 mg iron(II)sulfate-heptahydrate (“green vitriol”) and 3.6 g of a 50% hydrogen peroxide have been added. Within 20 minutes the remaining acrylic acid mixture and 34 g of a 10% Rongalite™ solution containing 6 g of mercaptoethanol have been added under a constant but differing mass flow. The temperature rose from 23 to 35° C. After the final addition the reaction mixture showed a pH of 4.8. The solution has been ...

preparation example 2

[0043] To the flask according to Example 1 450 g water, 450 g (0.06 mol) polyethylene glycol-7500-monovinylether and 14 g NaOH (20%) have been added. A mixture of 41.8 g (0.58 mol) of acrylic acid in 40 g water has been produced separately and added to the flask containing polyethylene glycol-7500-monovinylether solution; the pH decreased to 5.5. Then 40 mg iron(II)sulfate-heptahydrate (“green vitriol”) and 4 g Rongalite™ and 2 g mercaptoethanol have been added. Within 20 minutes a solution comprising 3.6 g 50% hydrogen peroxide in 34 g water have also been added. The temperature rose from 20 to 31° C. After the final addition, the reaction mixture showed a pH of 5.4. The solution has been stirred for 10 minutes at ambient temperature and subsequently has been neutralized with 60 g of a 20% sodium hydroxide solution. The product was a light yellow colored, clear and aqueous polymer solution with a solid concentration of 43% by weight.

preparation example 3

[0044] To the flask according to Example 1 490 g water, 350 g (0.06 mol) polyethylene glycol-5800-monovinylether and 10 g NaOH (20%) have been added. A mixture comprising 26 g (0.36 mol) of acrylic acid in 40 g water has been produced separately and added to the polyethylene glycol-monovinylether-solution; the pH decreased to 5.3. Then 40 mg iron(II)sulfate-heptahydrate (“green vitriol”) and 4 g Rongalite™ and 1.5 g mercaptoethanol have been added. After a short period of stirring 3.6 g 50% hydrogen peroxide have been added. The temperature rose from 20 to 29° C. Then the solution has been stirred for 10 minutes at ambient temperature and subsequently has been neutralized with 37 g of a 20% sodium hydroxide solution. The product was a light yellow colored, clear and aqueous polymer solution with a solid concentration of 40% by weight.

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Abstract

Copolymers include two monomer components, a) an olefinic unsaturated monocarboxylic acid comonomer or an ester or a salt thereof of an olefinic unsaturated sulfuric acid comonomer or a salt thereof, and b) an ether comonomer of the general formula (I) Components a) and b) are present in amounts of from 30 to 90 mol-% and from 70 to 10 mol-%, respectively, and comonomer component a) is selected from the group consisting of acrylic acid, methacrylic acid, crotonic acid, isocrotonic acid, allylsulfonic acid, vinylsulfonic acid and a salt thereof or an alkyl or hydroxyalkyl ester. Compositions including a hydraulic binder such as cement, gypsum, lime and anhydrite and the copolymer are also disclosed. The copolymer can be used as superplasticizer or dispersant for non-hardened (wet) and a hydraulic binder containing compositions.

Description

FIELD OF THE INVENTION [0001] This application is a continuation-in-part of Ser. No. 11 / 152,678 filed Jun. 14, 2005, pending, which is incorporated herein by reference in its entirety. [0002] This invention relates to a copolymer on a polyether basis comprising two monomer components and a method of use. BACKGROUND OF THE INVENTION [0003] Various types of organic compounds have been used to advantageously alter certain properties of wet hydraulic cement compositions. One class of components, which can collectively be called “superplasticizers” fluidify or plasticize the wet cement composition to obtain a more fluid composition. A controlled fluidity is desired, such that the aggregate used in mortars and concretes does not segregate from the cement paste. Alternatively, superplasticizers may allow the cement composition to be prepared using a lower water to cement ratio in order to obtain a composition having a desired consistency which often leads to a hardened cement composition h...

Claims

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Application Information

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IPC IPC(8): C08F20/06
CPCC04B24/2647C04B2103/308C08F220/26C08F216/1416C08F220/06C04B2103/32C08F216/145
Inventor BICHLER, MANFREDHOMMER, HERBERTWUTZ, KONRAD
Owner BASF CONSTR POLYMERS
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