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Conversion coating for aluminum and its alloys and articles thereof

a technology of conversion coating and aluminum alloy, which is applied in the field of conversion coating for aluminum and its alloys, can solve the problems of oxidized or phosphate generated conversion coatings being brittle, not and chromates and related toxic materials being displaced by less toxic alternatives, etc., to achieve corrosion resistance and easy to accept applied coatings

Inactive Publication Date: 2009-07-16
SAN FU CHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0005]This invention provides an aqueous conversion coating composition for the aluminum and its alloys metals, to generate an outer protective in-situ coating on the aluminum and aluminum alloy. The protective conversion coating composition has as its essential ingredients thereof protein compounds or proteins that will react with the aluminum and aluminum alloy to generate in-situ a coating that will more easily accept applied coatings and provide for a more corrosion resistant surface.
[0006]The invention also provides non-toxic aluminum and aluminum alloy aqueous coating composition where in the essential ingredient is non-toxic protein to provide an outer protective coating for the non-toxic aluminum and aluminum alloy and wherein the protein has a molecular mass of from 16,700 to 1,000,000 and provides a concentration of 0.1 to 10%, the pH of the composition is from 4.0 to 10.0, the protein is selected from the group consisting of casein, dried egg white, gelatin, serum albumin, hemoglobin, lacto globulin, gliadin. and mixtures thereof, and the composition provides an in-situ conversion coating on the metal that will provide oxidation resistance to the metal for at least 5 days at room temperature and allow the conversion coated metal to be painted such that a cured painted metal showed no signs of blistering and no signs of adhesion failure, and the composition provides an in-situ conversion coating on the metal that allows the conversion coated metal to be electroless plated and then placed in an oven at 350° F. for one half hour, removed and immediately quenched in water and the plated metal showed no signs of blistering or loss of adhesion.

Problems solved by technology

As a result, chromates and related toxic materials are being displaced by less toxic alternatives.
Oxidized or phosphate generated conversion coatings tend to be brittle.
Such a surface need to painted shortly after being produced as it will quickly form a hydrophobic surface and as a result will not easily accept applied coatings.
These processes are rather difficult to properly apply and even with the use of the above processing steps, the plating of aluminum and its alloys is a very difficult process.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0017]A 0.032 inch thick 3.0 inch by 10 inch panel of “7075-T6” aluminum Alloy was cleaned in a mild alkaline cleaner at 150° F. for three minutes, rinsed in D.I. water, soaked in a 20% nitric acid solution at 100° F. for two minutes to remove any alloyed metals or metal oxides, rinsed again in D.I. water and then made the cathode of an electrolytic cell consisting of:

[0018]1.0% Casein

[0019]0.038% potassium hydroxide

[0020]0.3% potassium salt of Glycolic acid

[0021]Phosphoric acid used to adjust PH to 7.5

[0022]Balance water

[0023]The proteins compounds and / or proteins were plated out on the surface of the metal with a current density of 14 amps per square foot for four seconds. The metal was then rinsed, dried and allowed to sit in the open for one week before being painted with an Epoxy Polyamide primer as outlined in MIL-DTL-5541F. When cured, the panel was tested for adhesion as outlined in the specification and showed no signs of adhesion failure or blistering.

example 2

[0024]A 0.032 inch thick 3.0 inch by 10 inch panel of “7075-T6” aluminum alloy was cleaned in a mild alkaline cleaner at 150° F. for three minutes, rinsed in D.I. water, soaked in a 20% nitric acid solution at 100° F. for two minutes to remove any alloyed metals or metal oxides, rinsed again in D.I. water and then made the cathode of an electrolytic cell consisting of:

[0025]1.0% Casein

[0026]0.25% Phosphoric acid (85%) to adjust the PH to 3.0

[0027]Balance D.I. water

[0028]The proteins compounds and / or proteins were plated out on the surface of the metal with a current density of 14 amps per square foot for four seconds. The metal was then rinsed, dried and allowed to sit in the open for one week before being painted with an Epoxy Polyamide primer as outlined in MIL-DTL-5541F. When cured the panel was tested for adhesion as outlined in the specification and showed no signs of adhesion failure or blistering.

example 3

[0029]A 0.032 inch thick, 3.0 inch by 10 inch panel of “1175” aluminum alloy (pure aluminum) was cleaned in a mild alkaline cleaner at 150° F. for three minutes, rinsed in D.I. water and then made the cathode of an electrolytic cell consisting of:

[0030]1.0% Casein

[0031]0.50% potassium hydroxide to adjust the PH to 9.0

[0032]Balance D.I. water

[0033]The proteins compounds and / or proteins were plated out on the surface of the metal with a current density of 14 amps per square foot for four seconds. The metal was then rinsed, dried and allowed to sit in the open for one week before being painted with a commercial solvent based polyurethane paint. After being allowed to cure the coating was tested for paint adhesion according to ASTM-D3359 and tested for wet paint adhesion according to AAMA 2605. There were no signs of paint adhesion failure.

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Abstract

I provide a non-toxic protein and protein compound conversion coated metal article, a painted or plated non-toxic protein and protein compound conversion coated metal article, the aqueous coating solution to provide the in-situ conversion protective coating, and a process of preparing the article. The article is a metal selected from the group consisting of aluminum and aluminum alloy. The solution has a pH of 3.0 to 12.0 and preferably 4.0 to 10.0 and a protein and protein compound concentration of 0.1 to 10% by weight and the protein and protein compound have a molecular mass of 16,700 to 1,000,000.

Description

FIELD OF INVENTION[0001]The present invention relates to the application and generation of a non-toxic and environmentally safe protein or protein compounds based conversion coating for aluminum and its alloys. More particularly the invention relates to a composition and a method of conversion coating aluminum and its alloys with a non-toxic and environmentally friendly protein composition that reacts in-situ with the surface of the metal to generate a conversion coating that incorporates the metal.BACKGROUND OF THE INVENTION[0002]The chemical conversion coating of aluminum and its alloys is known in the art as a process whereby the surface of the metal is chemically converted to a surface that more easily accepts applied coatings, i.e. paint, and / or increases the corrosion resistance of the metal. An industry accepted process for the conversion coating of aluminum and its alloys makes use of known carcinogens such as chromates (see: MIL-DTL-80716B and / or ASTM B449). As a result, ch...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): B05D3/00C07K2/00B32B15/04C07K14/00
CPCC07K14/4732C07K14/76C07K14/78C07K14/805C25D11/04C23C18/1848C23C18/31C25D9/02C25D11/02C23C18/1692Y10T428/31678
Inventor BIBBER, JOHN W.
Owner SAN FU CHEM CO LTD
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