Security laminates with interlaminated transparent embossed polymer hologram
a polymer hologram and laminate technology, applied in the direction of film/foil adhesives, adhesive processes with surface pretreatment, instruments, etc., can solve the problems of adverse effects on the brilliance of the hologram, the inability to obtain sufficient adhesion of the outermost surface of the hri-layer, and the embossed hologram not being able to withstand tamper-proof interlamination, etc., to achieve the effect of increasing the brillian
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example 1
[0117]This example illustrates that only certain organic solvents are capable of conditioning a HRI layer to a state wherein the adhesion of the HRI layer via an adhesive layer to a foil can be improved while maintaining the brilliance of the hologram.
[0118]In INVENTIVE SAMPLES 1 to 4 and COMPARATIVE SAMPLES 2 and 3 a hologram as described above was mounted on a 23 μm thick poly(ethylene terephthalate) support. The outermost surface of the ca. 100 nm evaporated zinc sulphide layer was conditioned by spreading different organic liquids thereon using a Braive® coating apparatus with a wire-rod with a contact time of 200 s before the liquids evaporated and drying at 60° C. for 5 minutes and in COMPARATIVE SAMPLE 1 no conditioning was performed.
[0119]An adhesive composition was prepared by mixing 50 g of Liofol UK 3640, a polyurethane solvent (ethyl acetate) adhesive, with 1 g of Hardener Liofol UK 6800 layer and this composition was applied using a Braive coating apparatus with a 10 μm...
example 2
[0130]This example illustrates that the addition of certain organic solvents to the adhesive composition result in excellent adhesion while even improving the brilliance. The combination of the solvent in the adhesion composition also has the advantage that the laminate is obtained in a faster and more economical way due to the abolition of the organic solvent pretreatment steps.
[0131]In INVENTIVE SAMPLES 5 to 8 a hologram as described above was mounted on a 23 μm thick poly(ethylene terephthalate) support. An adhesive composition was prepared by mixing 50 g of Liofol UK 3640, a polyurethane solvent (ethyl acetate) adhesive, with 1 g of Hardener Liofol UK 6800 layer and 20 g of diluent given in table 2 and this composition was applied to the hologram foil as supplied using a Braive® coating apparatus with a 10 μm wire-rod to the solvent-conditioned outermost surface of the foil of INVENTIVE SAMPLE 1 with an adhesive layer coating and to the non-conditioned outermost surface of the f...
example 3
[0136]In INVENTIVE SAMPLE 9 and COMPARATIVE SAMPLE 4 a hologram foil as described above was produced on a 23 μm thick poly(ethylene terephthalate) support. The outermost surface of the ca. 100 nm evaporated zinc sulphide layer was coated with a 3.5% by weight solution of S-LEC BL5HP, a polyvinyl butyral from Sekisui Chemical, in methylethylketone using a Braive coating apparatus with a 10 μm wire-rod integrally over the whole foil and the layer dried for 10 minutes at 50° C. giving a surface coverage of 0.35 g / m2.
[0137]An adhesive composition was prepared by mixing 50 g of Liofol UK 3640, a polyurethane solvent (ethyl acetate) adhesive, with 1 g of Hardener Liofol UK 6800 layer and this composition was applied using a Braive coating apparatus with a 10 μm wire-rod to the outermost surface of the foil of INVENTIVE SAMPLE 9 with a poly(vinyl butyal)-coating and COMPARATIVE SAMPLE 4 without a poly(vinyl butyral)-coating on the zinc sulphide-coated side of the support and was dried for ...
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