Plant based material useful in adsorbing petroleum products, processes for making these, and uses thereof

a plant-based material and petroleum product technology, applied in water cleaning, water/sludge/sewage treatment, scale removal and other directions, can solve the problems of affecting marine life, potable water, and causing ripening, and achieving the effect of reducing the number of contaminated water sources

Inactive Publication Date: 2014-04-17
SAUDI ARABIAN OIL CO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Oil spills, of course, have a tremendous negative impact on marine life, potable water, and create a “ripple effect” in, e.g., the tourist industry, health care in affected areas, etc.
Their efficacy, however, is hindered when the oil material to be adsorbed is combined with water.
Further, when these plant m...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0029]This example describes the manufacture of the particles of the invention. Date tree trimmings (referred to hereafter as “karab” or “petiole”) were collected, washed thoroughly, and then dried, overnight, at 105° C. After drying, the trimmings were chipped into smaller pieces, and then milled to achieve particles ranging from 1-5 mm in size. These particles were then dried again, to remove any residual water.

[0030]Animal fat (sheep fat), was used as the source of the materials used to coat the particles. Samples of the animal fat were placed in the thimbles of two different Soxhlet extractors with two different solvents and two parallel extractions were carried out. To elaborate, i.e., either hexane or petroleum ether, was placed in a still pot of a Soxhlet setup, in a manner well known to one of ordinary skill in the art. This resulted in selected extraction of lipids from the solid animal fat, into the liquid solvents. This was continued for different lengths of time (up to f...

example 3

[0037]Comparative tests were then carried out where coated, and uncoated particles, were added to containers holding the same amounts of both water, and crude oil. As with Example 2, equal quantities of the particles were added. Given their different densities, the crude oil floated on top of the water in each sample.

[0038]The uncoated particles adsorbed the water and, to the extent any oil was removed, it was a result of disturbance when the particles were removed from the container. In contrast, the coated particles adsorbed no water, but instead selectively adsorbed the crude oil. When the coated particles were removed, essentially clean, crude oil free water remained

[0039]The foregoing examples set forth a method for preparing an oil adsorbent particulate material, by dissolving a combining plant particulate material in a liquid form of a lipid or lipid mixture, under conditions favoring uniform coating of the particles with the lipid material. The resulting coated particles pro...

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Abstract

The invention relates to methods for making completely biodegradable, hydrophobic, oleophilic plant based materials which are useful in adsorption of petroleum products. The materials have an average diameter of from 1 to 5 mm, and an ash content of from 10% to 30%. The non-paraffin coating is an animal fat product, preferably produced by dissolving a pure animal fat and using this as the coating material.

Description

RELATED APPLICATION[0001]This application claims priority from U.S. Provisional Patent Application No. 61 / 714,906 filed Oct. 17, 2012, incorporated by reference in its entiretyFIELD OF THE INVENTION[0002]This invention relates to completely biodegradable, hydrophobic, oleophilic plant based materials which are useful in adsorption of crude oil, and other petroleum products, especially from spills in water. More particularly, it relates to plant particles (date palm tree particles, e.g.), which have had their normally hydrophilic surfaces modified by non-paraffin lipid materials, resulting in hydrophobic particles which are oleophilic and selectively adsorb oil and repel water.BACKGROUND AND PRIOR ART[0003]Every day, tens of millions of barrels of oil are transported over bodies of water which are also important sources of food and drinking water to millions of people. Oil spills, of course, have a tremendous negative impact on marine life, potable water, and create a “ripple effect”...

Claims

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Application Information

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IPC IPC(8): C09K3/32E02B15/00C02F1/28
CPCC09K3/32E02B15/00C02F1/286B01J20/22B01D17/0202B01J20/28004B01J20/28016B01J20/28019B01J20/305B01J20/3206B01J20/3231B01J20/3293B01J2220/4825C02F1/288C02F1/40C02F2101/32C02F2103/007C02F2103/08E02B15/101
Inventor YUSUF, ZAKIFADHEL, BANDARHAMMAD, AHAMD D.
Owner SAUDI ARABIAN OIL CO
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