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Treatment of alkaline bauxite residue

a technology of alkali bauxite and residue, which is applied in the direction of biological water/sewage treatment, multi-stage water/sewage treatment, separation process, etc., can solve the problem of unsuitable disposal of untreated liquid portion

Active Publication Date: 2015-10-08
RIOTINTO ALCAN INT LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The patent describes a process for treating liquid waste from plants that use the Bayer process for making chemicals. The process involves using a flocculant to settle the waste liquor and prepare it for further treatment. This process can be used to dispose of waste from such plants, rather than simply storing it in large ponds. The process can also be used on an industrial scale and can process the entire output of a plant. The recycling of compacted slurry containing hydrotalcite can improve settling and capture contaminants from the waste liquor. Adding a flocculant to the process can also improve settling behavior and allow for higher treatment rates of the waste. The process reduces fresh water consumption and minimizes damage to the flocculant during transfer. Additionally, using excess seawater can act as a buffer against poor quality effluent. The process can involve dewatering or mixing the compacted slurry directly with residue from the refinery. Overall, the patent describes a technical solution for efficiently processing and disposing of waste from chemical plants.

Problems solved by technology

This means that the liquid portion of waste from a Bayer process can be treated to remove heavy metals and other materials that make the untreated liquid portion unsuitable for disposal.

Method used

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  • Treatment of alkaline bauxite residue
  • Treatment of alkaline bauxite residue
  • Treatment of alkaline bauxite residue

Examples

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Embodiment Construction

[0049]With regard to FIG. 1, the Bayer process involves contacting bauxite with a hot solution of sodium hydroxide (NaOH) in a digester 10 to dissolve the alumina in the bauxite as aluminium hydroxide ([Al(OH)4]−), whilst other solid impurities from the bauxite remain largely undissolved.

[0050]The digester 10 operates at a temperature in the range of 140 to 280° C., depending upon the phase of aluminium oxide contained in the bauxite feed.

[0051]The hot solution, which is now loaded with aluminium trihydroxide, is then clarified in a settling and filtering stage 12 to remove solid impurities as waste. The products from this process are pregnant liquor and a Bayer process slurry waste stream containing gangue material suspended in a liquor stream containing caustic soda and dissolved aluminium.

[0052]The clarified pregnant liquor is then transferred to a precipitation stage 14, where the clarified liquor is cooled to cause aluminium trihydroxide (Al(OH)3) to precipitate.

[0053]The alumi...

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Abstract

A process is disclosed for treating a Bayer process waste comprising a slurry containing bauxite residue and dissolved aluminium. The process comprises supplying the waste to a settling area to cause the bauxite residue to settle out of the slurry, thereby producing a supernatant liquor. The process further comprises neutralizing the supernatant liquor with a solution containing magnesium and calcium to produce a neutralized slurry containing precipitated hydrotalcites and thickening the neutralized slurry to produce a clarified effluent and a compacted slurry containing the precipitated hydrotalcites, part of said compacted slurry being recirculated to the supernatant liquor to be neutralized and / or directly to the neutralizing step The clarified effluent and the compacted slurry are disposed of separately. Also disclosed is a plant for treating a Bayer process waste.

Description

TECHNICAL FIELD[0001]The invention disclosed relates to the production of alumina from bauxite. In particular, it relates to waste produced by the Bayer process in the course of extracting alumina from bauxite. More particularly, a process is disclosed for treating a Bayer process waste comprising bauxite residue and dissolved alumina.BACKGROUND ART[0002]Subjecting bauxite to the Bayer process produces a pregnant caustic liquor containing dissolved alumina and a bauxite residue slurry. In order to extract alumina from the pregnant liquor, it is first subjected to solid liquid separation steps to separate the bauxite residue. The alumina-bearing liquor is then treated to precipitate aluminium trihydroxide that is subsequently refined to produce alumina, which is in turn processed into aluminium metal.[0003]The separated bauxite residue is often in the form of a slurry that contains a significant volume of caustic liquor. The slurry is delivered to storage ponds where the bauxite resi...

Claims

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Application Information

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IPC IPC(8): C02F9/00C01F7/02C22B3/12C02F1/52C02F1/66C01F7/066C01F7/785
CPCC02F9/00C02F1/5236C02F1/66C02F2103/16C01F7/02C02F2101/10C22B3/12A62D3/33C01F7/066A62D2101/43A62D2101/24C01F7/785
Inventor ANDERSON, JOHN VICTORROUSSEAUX, JEAN-MARCPELOQUIN, GUYO'BRIEN, BEN
Owner RIOTINTO ALCAN INT LTD