Hydrosilation in high boiling natural vegetable oils

Abstract

An improved process is provided for the preparation of siloxane-oxyalkylene and siloxane-alkyl copolymer compositions via a hydrosilation reaction in the presence of high boiling point natural vegetable oils as the reaction solvent. The reaction solvent need not be removed from the block copolymer product, and indeed is beneficial to remain with the copolymer particularly when the copolymer is used as a surfactant for polyurethane foam formulations. Soybean oil and linseed oil are the preferred high boiling natural oil solvents when the copolymer product is to be used in the preparation of the surfactants for polyurethane foams. High resiliency polyurethane foam prepared with these natural oils present in the surfactant preparation afforded improved compression sets, wet compression sets and humid aged compression sets. Additionally, the use of the surfactants made with natural oils as a reaction solvent or consequently surfactants post diluted with natural oils when employed in the preparation of polyurethane foam afforded foams with greatly reduced amounts of "glass fogging".

Description

This invention relates in general to an improved process for the preparation of organopolysiloxane surfactants. In one aspect, this invention is directed to a process for the preparation of improved siloxanc-oxyalkylene copolymer compositions. In a further aspect, the invention is directed to siloxane-oxyalkylene and siloxane-alkyl copolymers and organosiloxanes that are suitable for use as surfactants in, for instance, polyurethane foam, coatings applications, or personal care products.The preparation of siloxane-oxyalkylence or siloxane-alkyl copolymers by the hydrosilation reaction of an organohydrogen siloxane and an unsaturated olefin hydrocarbon or polyoxyalkylene is well known and reported in the literature. The hydrosilation reaction is typically performed in a low molecular weight, highly volatile hydrocarbon solvent such as benzene, toluene or xylene so as to compatibilize the reactants and aid in transfer and filtration of the copolymer products, or to moderate the exothe...

AI Technical Summary

Benefits of technology

By conducting the hydrosilation reaction in the manner indicated above, and employing the high boiling point natural vegetable oils, improvements arc obtained in aspects of the reaction, such as reaction rate, reaction yield, reaction selectivity, reaction processing during manufacture or reaction product processing in polyurethane foam, personal care and coatings applications. For example, when at least 20 weight percent (based on the total weight of reactants) soybean oil is used, it aids in the handling of the reactants

Problems solved by technology

In the majority of the aforementioned processes, the hydrocarbon solvent is removed after the hydrosilation reaction is completed, since in most cases, the solvent is too flammable, toxic or otherwise detrimental to the final product or further processing steps in which the copolymer is utilized.

However, disadvantages attend their use.

Such disadvantages include: (A) IPA competes with the unsaturated polyether for the silanic sites (SiH) on the siloxane backbone resulting in the formation of the isopropoxysilyl, (CH.sub.3).sub.2 CHOSi, functional group which reduces surfactant performance in urethane foam; (B) IPA reacts with isocyanate in polyurethane foam formulations effectively lowering the isocyanate index of the formulation, so that the IPA must be stripped from the product and recovered, a process which is both time consuming and expensive; (C) IPA is miscible with water which is harmful in the manufacture of polyurethane foam surfactants; and (D) toluene and IPA are flammable which creates additional manufacturing problems.

In addition, prolonged stripping of surfactants manufacture