Reducing agents for use in thermographic recording materials

a technology of thermographic recording and reducing agent, which is applied in the field of thermographic recording materials, can solve the problems of insufficient light stability over the whole sensitometric range, unsatisfactory archivability, and unsatisfactory colour neutrality, and achieves low d.sub.min, high d.sub.max, and improved archivability

Inactive Publication Date: 2000-07-25
AGFA NV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

It is therefore an object of the present invention to provide thermographic recording materials whose prints have high D.sub.max and low D.sub.m...

Problems solved by technology

However, prints produced with direct thermal recording materials using reducing agents according to the teaching of U.S. Pat. No. 5,582,...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

invention examples 1 & 2

and INVENTION EXAMPLES 1 & 2

Preparation of aqueous dispersion of silver behenate

9000 g of silver behenate were added with stirring to 9000 g of a 10% aqueous solution of Surfactant Nr 5 diluted with 20,146 g of deionized water and the mixture stirred for 30 minutes with a KOTTHOFF.TM. stirrer. The resulting dispersion was then passed four times through a MICROFLUIDICS.TM. high pressure homogenizer at a pressure of 400 bar to obtain a finely divided aqueous silver behenate dispersion.

Preparation of a Tone Modifier Dispersion

The tone modifier dispersion was prepared by first dissolving 8.8 g of K7598 in 71.4 g of deionized water by first adding the gelatin, then allowing the gelatin to swell for 30 minutes and finally heating to 50.degree. C. 20 g of T01 was added with ULTRA-TURRAX.TM. stirring to this gelatin solution at 50.degree. C., and the stirring continued for a further 5 minutes. Finally the resulting dispersion was pumped through a DYNOMILL.TM. (a horizontal bead mill from BA...

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Abstract

A substantially light-insensitive black and white monosheet thermographic recording material is provided comprising a support and a thermosensitive element containing a substantially light-insensitive organic silver salt, a 1,2-dihydroxyphenyl-compound in thermal working relationship therewith and a binder, wherein the 1,2-dihydroxyphenyl-compound is represented by formula (I): where R is -P(=O)R1R2, -SOxR3, -CN, -NO2 or -CR4=NR5 when n is 0; R is -P(=O)R1R2, -SOxR3, -CN, -NO2, -CR4=NR5 or -COR6 when n is an integer; R1 and R2 are independently an alkyl, an aryl, an alkoxy, an aryloxy, a hydroxy or an amino group; R3 is an alkyl, an aryl or an amino group; R4 is an alkyl or an aryl group or hydrogen; R5 is an alkyl, an aryl, a hydroxy, an alkoxy, an aryloxy, an acyl or an amino amino group; R6 is an alkyl, an aryl, an alkoxy, an aryloxy, a hydroxy or an amino group or hydrogen; x is 1, 2 or 3; and the benzene ring of the 1,2-dihydroxyphenyl-compound represented by the formula (I) may be further substituted.

Description

The present invention relates to black and white substantially light-insensitive thermographic recording materials comprising a thermosensitive element containing a substantially light-insensitive organic silver salt and a novel reducing agent.Thermal imaging or thermography is a recording process wherein images are generated by the use of thermal energy. In thermography three approaches are known:1. Direct thermal formation of a visible image pattern by image-wise heating of a recording material containing matter that by chemical or physical process changes colour or optical density.2. Image-wise transfer of an ingredient necessary for the chemical or physical process bringing about changes in colour or optical density to a receptor element.3. Thermal dye transfer printing wherein a visible image pastern is formed by transfer of a coloured species from an image-wise heated donor element onto a receptor element.Most of the "direct" thermographic recording materials are of the chemic...

Claims

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Application Information

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IPC IPC(8): G03C1/498
CPCG03C1/49827G03C1/49863G03C1/4989G03C2200/45G03C1/498
Inventor TERRELL, DAVIDLOCCUFIER, JOHANDEFIEUW, GEERTHOOGMARTENS, IVAN
Owner AGFA NV
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