The utility model discloses a liquid sampling device of an on-line analysis instrument, which is arranged on an
ion exchanger in a matching way and comprises a sampling
pipe system and the on-line analysis instrument, the sampling
pipe system comprises a sampling guide
pipe and a plurality of sampling probes, the sampling guide pipe is horizontally arranged on the
ion exchanger body in a penetrating mode, the sampling end of the sampling guide pipe is communicated with the sampling probes, and the sampling probes are annularly and horizontally arranged around the sampling end of the sampling guide pipe at intervals; and the
tail end of the sampling conduit is connected with a water inlet interface of the on-line analysis instrument positioned outside the
ion exchanger. The sampling point is far away from the water producing tank or the water using point, and after sampling analysis, alarming and control are performed, so that enough reaction time is provided, unqualified product water can be prevented from entering the
ion exchange water producing tank to influence the
water quality of
produced water, and the
produced water is ensured to continuously reach the standard.