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Liquid crystal film and laminated film for optical devices

A liquid crystal film, liquid crystal technology, applied in optics, polarizing elements, nonlinear optics, etc., can solve the problems of deformation, inability to follow the polarizer, cracks in the liquid crystal alignment layer, etc.

Inactive Publication Date: 2009-07-08
NIPPON OIL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, an optical film made of an alignment layer of a liquid crystal compound has a problem that, for example, it cannot follow the shrinkage of the polarizing plate in a long-term dry-wet reciprocating test (cycle test) in a high-temperature environment test and a high-temperature and high-humidity environment test. , appearance abnormalities such as cracks (cracks) or deformation are likely to occur on the liquid crystal alignment layer
In particular, when the alignment-fixed liquid crystal material layer is used for liquid crystal alignment at a temperature above the liquid crystal transition point and a polymer liquid crystal in a glass state at a temperature below the liquid crystal transition point, because the balance between the liquid crystal orientation and the liquid crystal orientation , so there are limitations in improving the mechanical strength of the liquid crystal material layer by increasing the molecular weight, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0106] On the upper surface of the liquid crystal material layer 1 obtained in the preparation example (the surface opposite to the polyimide film), a UV-curable acrylic adhesive with a glass transition temperature of 105° C. was coated with a thickness of 5 μm as an acrylic resin layer. 1. A polyethylene terephthalate (PET) film 1 with a thickness of 50 μm is laminated thereon, and the acrylic resin layer 1 is cured by UV irradiation of about 600 mJ. Then, the polyimide film is peeled off from the integrated laminate of the PET film 1 / cured acrylic resin layer 1 / liquid crystal substance layer 1 / polyimide film to transfer the liquid crystal substance layer onto the PET film 1. , to obtain a laminate comprising PET film 1 / cured acrylic resin layer 1 / liquid crystal substance layer 1.

[0107] Furthermore, a UV-curable acrylic adhesive having a Tg=110° C. was applied to a thickness of 5 μm on the upper surface of the liquid crystal substance layer 1 of the laminate as the acrylic...

Embodiment 2

[0111] A laminated film for an optical element was obtained in the same manner as in Example 1 except that an adhesive of Tg=54° C. was used as the UV-curable acrylic resin layer 1 .

Embodiment 3

[0113] Except for using an adhesive with Tg=108°C as the UV-curable acrylic resin layer 1 and an adhesive with Tg=62°C as the UV-curable acrylic resin 2, the rest were exactly the same as in Example 1, and an optical Laminated film for components.

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PUM

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Abstract

Provide a kind of liquid crystal thin film, it is characterized in that, even in the severe environment test such as high temperature test and dry-wet reciprocating test of high temperature and high humidity test, as the thin liquid crystal thin film that does not produce abnormal appearance such as crack in the liquid crystal alignment layer, is based on A liquid crystal film formed by laminating a layer of a cured acrylic resin layer / an orientation-immobilized liquid crystal substance layer / a cured acrylic resin layer in this order, and at least one cured acrylic resin layer has a glass transition temperature (Tg) of 50 Above 200°C and below 200°C.

Description

technical field [0001] The present invention relates to a laminated film for optical elements formed by laminating liquid crystal films and polarizing films used in various optical elements. Background technique [0002] In recent years, optical films used in liquid crystal display devices have been required to have higher durability in addition to excellent optical performance. In particular, liquid crystal display devices for portable devices such as mobile phones and for vehicles are required to pass strict environmental tests assuming various usage conditions. [0003] A film (film) comprising an alignment layer of a liquid crystal compound, especially a film comprising a liquid crystal material immobilized to a nematic structure, a twisted nematic structure or a nematic hybrid structure, used as a color for a liquid crystal display element Compensation, viewing angle compensation elements, and excellent performance as optically active optical elements, etc., contribute...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G02B5/30G02F1/13363
Inventor 穗崎宪二佐藤晴义谷本顺一郎上坂哲也片冈健
Owner NIPPON OIL CO LTD