Firming agent for surface layer of coal and its preparation method
A curing agent and surface layer technology, applied in chemical instruments and methods, other chemical processes, loading/unloading, etc., can solve problems such as health hazards, maintenance difficulties in public works departments, and elevated working environment temperature of electrical equipment to avoid dust. pollution effect
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Embodiment 1
[0027] Raw material ratio:
[0028] Raw material name Proportion (wt%) Raw material name Proportion (wt%)
[0029] Polyvinyl alcohol 0.5 Potassium permanganate solution (concentration is 1wt%) 0.4
[0030] Starch 4 Borax or boric acid solution (concentration is 5wt%) 2
[0031] Caustic soda solution (concentration of 10wt%) 4 water 99.1
[0032] Operation process:
[0033] As shown in Figure 1, according to the ratio of raw materials, add 50% of the total amount of water to the reaction kettle, then add 0.5% of polyvinyl alcohol, stir, and raise the temperature to 99°C to completely dissolve the polyvinyl alcohol. Cool down to 60°C and add Corn starch 4%, stirring and holding for 1h for graft modification; after modification, the material is cooled to 35℃, then 0.3% potassium permanganate solution is added, and the oxidation reaction is 1h. Observe the color of the solution and gradually change from purple to colorless ; Then, while stirring, slowly add 4% caustic soda solution in...
Embodiment 2
[0035] Raw material ratio:
[0036] Raw material name Proportion (wt%) Raw material name Proportion (wt%)
[0037] Polyvinyl alcohol 1.5 Potassium permanganate solution (concentration is 1wt%) 0.6
[0038] Starch 6 Borax or boric acid solution (concentration is 5wt%) 5
[0039] Caustic soda solution (concentration of 10wt%) 8 water 78.9
[0040] Operation process:
[0041] As shown in Figure 1, according to the ratio of raw materials, add 50% of the total amount of water to the reactor, then add 1.5% of polyvinyl alcohol, stir, and raise the temperature to 99°C to completely dissolve the polyvinyl alcohol. Cool down to 60°C and add Corn starch is 6%, stirred and kept for 1h for graft modification; after modification, the material is cooled to 35℃, then 0.6% potassium permanganate solution is added, and the oxidation reaction is for 1h. Watch the color of the solution and gradually change from purple to colorless ; Then, while stirring, slowly add 8% of the caustic soda solution in ...
Embodiment 3
[0043] Raw material ratio:
[0044] Raw material name Proportion (wt%) Raw material name Proportion (wt%)
[0045] Polyvinyl alcohol 1 Potassium permanganate solution (concentration of 1wt%) 0.4
[0046] Starch 5 Borax or boric acid solution (concentration is 5wt%) 3
[0047] Caustic soda solution (concentration of 10wt%) 6 water 84.6
[0048] Operation process:
[0049] As shown in Figure 1, according to the ratio of raw materials, add 50% of the total amount of water to the reactor, then add 1% of polyvinyl alcohol, stir, and heat up to 99°C to completely dissolve the polyvinyl alcohol. Cool down to 60°C and add Corn starch 5%, stir and keep for 1h for graft modification; after modification, the material is cooled to 35℃, then 0.5% potassium permanganate solution is added, and the oxidation reaction is 1h. Watch the color of the solution and gradually change from purple to colorless ; Then, while stirring, slowly add 6% of the caustic soda solution in the reaction kettle, the ma...
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