Waterproof type neutral ink with pigment in Nano level for pen, and preparation method

A gel pen ink, nanoscale technology

Inactive Publication Date: 2007-10-10
苏州三威纳米科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Compared with the dye type, a nano-scale pigment gel pen ink can effectively solve the problems of fading and bleeding, but the pigment type gel pen ink produced by the ordinary production process and formula has a large particle size, which affects Its permeability prolongs the drying time, and there will be plugging, disconnection, uneven ink output, etc.
[0003] Pigment-based inks are colored by dispersing fine particles of pigments in the medium used. The ideal dispersion system should have a "primary (primary) particle" pigment dispersion state. Nanoization of primary pigment particles will improve the quality and The use effect is greatly improved, but as the particles become smaller, the specific surface area will double, the van der Waals attraction between the particles will become larger, and t

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] First, add 83.6kg of deionized water into the pre-dispersion pot, add 0.20kg of acrylic resin, 8kg of ethylene glycol, 8kg of polyethylene glycol, and 0.2kg of bactericide under stirring, and stir and mix until all dissolve evenly, then stop stirring to obtain Thickener, set aside.

[0024] Next, add 67.6kg deionized water in the pre-dispersion pot, add 20kg ethylene glycol, 10kg polyethylene glycol, 2kg non-ionic active agent, 0.2kg bactericide, 0.2kg rust inhibitor under stirring and fully stir and mix, Until all dissolve evenly, stop stirring, obtain diluent, set aside.

[0025] Then add 72.5kg of deionized water into the pre-dispersion pot, add 8kg of ethylene glycol, 1.5kg of non-ionic multi-anchor multi-chain polymer in hyperdispersant, and 3kg of acrylic resin under stirring and mix until all are dissolved Evenly, finally add 15kg of P.Bk.7 black pigment under stirring, fully stir and mix, then carry out ultrafine grinding for 2 hours, stop grinding, discharge, ...

Embodiment 2

[0028] First, 79.35kg of deionized water is added to the pre-dispersion pot, and 0.45kg of xanthan gum, 10kg of glycerol, 10kg of glycol ether, and 0.2kg of bactericide are added under stirring, and stirred and mixed until all are dissolved evenly, and the stirring is stopped to obtain Thickener, set aside.

[0029] Next, 54.6kg deionized water is added in the pre-dispersion pot, under stirring, add 25kg glycerin, 15kg glycol ether, 5kg non-ionic active agent, 0.2kg bactericide, 0.2kg antirust agent and fully stir and mix until All dissolve evenly, stop stirring, obtain diluent, set aside.

[0030] Then add 45.5kg of deionized water into the pre-dispersion pot, add 15kg of ethylene glycol, 4.5kg of non-ionic multi-anchor multi-chain polymer in hyperdispersant, and 20kg of acrylic resin under stirring and mix until all are dissolved Evenly, finally add 15kg of P.Bk.7 black pigment under stirring, fully stir and mix, then perform ultrafine grinding for 8 hours, stop grinding, d...

Embodiment 3

[0033] First, add 81.5kg of deionized water into the pre-dispersion pot, add 0.30kg of acrylic resin, 9kg of ethylene glycol, 9kg of polyethylene glycol, and 0.2kg of bactericide under stirring, stir and mix until all dissolve evenly, stop stirring, and obtain Thickener, set aside.

[0034] Next, first add 61.1kg of deionized water into the pre-dispersion pot, add 22.5kg of ethylene glycol, 12.5kg of polyethylene glycol, 3.5kg of non-ionic active agent, 0.2kg of bactericide, and 0.2kg of rust inhibitor under stirring. Thoroughly stir and mix until all dissolve evenly, stop stirring, obtain diluent, and set aside.

[0035] Then add 49kg of deionized water into the pre-dispersion pot, add 11.5kg of ethylene glycol, 3.0kg of non-ionic multi-anchor multi-chain polymers in the hyperdispersant, and 11.5kg of acrylic resin under stirring and mix until all Dissolve evenly, and finally add 15kg of P.Bk.7 black pigment under stirring, fully stir and mix, then carry out ultrafine grindi...

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PUM

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Abstract

This invention provides a method for producing nanoscale pigment waterproof neutral pen ink, which comprises: nanoscale stock solution 40 wt. %, thickener 40-50 wt. %, and diluter 10-20 wt. %. The average particle size of the pigment is 100-200 nm. The method comprises: adding nanoscale stock solution into a blending pot, adding diluter under stirring, stirring for another 30-90 min, adding thickener, then stirring for 1-3 h, terminating stirring, and discharging. The ink has such advantages as good color, stable quality, fluent writing, high fatigue resistance, no demixing, separation or precipitation after a long-time storage, high solarization resistance, high waterproof performance, no toxicity, high production and usage safety, and no pollution. The ink can be widely used for metal ballpoint pen, polypropylene pen and plastic pen.

Description

technical field [0001] The invention relates to a gel pen ink, in particular to a nanoscale pigment waterproof gel pen ink and a manufacturing method thereof, belonging to the technical field of ink. Background technique [0002] At present, the high-grade special pen ink sold in the domestic and foreign markets has changed from dye type to pigment type. Compared with the dye type, a nano-scale pigment gel pen ink can effectively solve the problems of fading and bleeding, but the pigment type gel pen ink produced by the ordinary production process and formula has a large particle size, which affects Its permeability prolongs the drying time, and there will be plugging, disconnection, uneven ink output and other phenomena. [0003] Pigment-based inks are colored by dispersing fine particles of pigments in the medium used. The ideal dispersion system should have a "primary (primary) particle" pigment dispersion state. Nanoization of primary pigment particles will improve the ...

Claims

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Application Information

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IPC IPC(8): C09D11/16C09D11/18
Inventor 詹忆源张杏金
Owner 苏州三威纳米科技有限公司
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