Silicon rubber chemical copper-plating technique

A technology of electroless copper plating and silicone rubber, which is applied in the direction of liquid chemical plating, metal material coating technology, coating, etc., can solve the problems of copper plating on silicone rubber substrates, etc., and achieve good flexibility, stable work, cost saving effect

Inactive Publication Date: 2008-02-13
CHINA UNIV OF MINING & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Today's electroless copper plating process is widely used. It can achieve copper plating on substrates such as metals, ceramics, glass and plastics, and the process in this area is very mature. It includes degreasing, roughening, activation, sensitization and There are several processes of electroless copper plating, but it is impossible to achieve copper plating on silicone rubber substrates only by relying on these existing processes

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] Embodiment 1: Embodiment 1: select silicon rubber for use, put it into sodium hydroxide (NaOH) of 10 / L, sodium carbonate (Na2CO3) of 35g / L and trisodium phosphate (Na3PO3 12H2O) of 25g / L In the three-alkali solution composed, soak at a constant temperature of 80°C for 30 minutes to remove oil, and then wash with deionized water after degreasing; roughen with 200ml / L hydrochloric acid solution (HCl) solution for 2min, and then wash with deionized water; wash with 10g / L stannous chloride (SnCl2 6H2O) and 40ml / L hydrochloric acid solution (HCl) prepared solution sensitization 3min, then wash with deionized water; use 5g / L silver nitrate (AgNO3) and 10ml / L of ammonia water (NH3·H2O) was activated for 4 minutes and washed with deionized water; finally put it into the plating solution for electroless plating, the temperature was 22°C, the pH value was 12.5, and copper plating could be done after 30 minutes get the product. The plating solution consists of 18g / L copper sulf...

Embodiment 2

[0014] Example 2: Silicone rubber is soaked in 15 / L of sodium hydroxide (NaOH), 25g / L of sodium carbonate (Na2CO3) and 35g / L of trisodium phosphate (Na3PO3 12H2O) at a constant temperature of 80°C for 35min before use. Rinse with deionized water; roughen with 150ml / L hydrochloric acid solution (HCl) for 2 minutes and wash with deionized water; prepare with 12g / L stannous chloride (SnCl2 6H2O) and 40ml / L hydrochloric acid solution (HCl) Wash the resulting solution with deionized water after sensitization for 3 minutes; wash with deionized water after activating the solution prepared with 4g / L silver nitrate (AgNO3) and 10ml / L ammonia water (NH3·H2O) for 5min; finally Electroless copper plating is carried out at a temperature of 25°C and a pH of 12.5, and the product will be ready in 30 minutes. The plating solution consists of 15g / L copper sulfate (CuSO4 5H2O), 12ml / L formaldehyde (HCHO), 12g / L disodium ethylenediaminetetraacetic acid (EDTA (C10H14N2Na2O8 12H2O)), 15mg / L ferrou...

Embodiment 3

[0015] Example 3: Silicone rubber is soaked in 20 / L sodium hydroxide (NaOH), 20g / L sodium carbonate (Na2CO3) and 50g / L trisodium phosphate (Na3PO3·12H2O) solution at a constant temperature of 80°C for 40min before use. Rinse with deionized water; roughen with 250ml / L hydrochloric acid solution (HCl) for 3 minutes and wash with deionized water; prepare with 15g / L stannous chloride (SnCl2 6H2O) and 40ml / L hydrochloric acid solution (HCl) The solution was sensitized for 4 minutes and washed with deionized water; the solution prepared with 4g / L silver nitrate (AgNO3) and 10ml / L ammonia water (NH3·H2O) was activated for 4 minutes and then washed with deionized water; finally, the chemical Copper plating, the temperature is 25°C, the pH value is 13, and the product can be obtained after 25 minutes. The plating solution consists of 20g / L copper sulfate (CuSO4 5H2O), 14ml / L formaldehyde (HCHO), 16g / L disodium ethylenediaminetetraacetic acid (EDTA (C10H14N2Na2O8 12H2O)), 20mg / L ferrous...

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PUM

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Abstract

The invention relates to a silicone rubber chemical copper plating process, which belongs to the chemical copper plating process. The process is as follows: put the silicone rubber in a tri-alkali solution prepared by sodium hydroxide, sodium carbonate and trisodium phosphate, remove oil, and then wash with water; put it in hydrochloric acid solution to roughen, and wash with water; Soak and sensitize the silicone rubber with a solution prepared with hydrochloric acid solution, the pH value is 0.5-1.9, and wash with water; soak and activate the silicone rubber with a solution prepared with silver nitrate and ammonia water, and wash with water; add sulfuric acid Electroless copper plating is carried out in the copper plating solution, the pH value of the plating solution is required to be 12-13, and the copper plating product is obtained; the plating solution is composed of copper sulfate, formaldehyde, disodium edetate, potassium ferrocyanide and Dilute solution of sodium hydroxide. Advantages: 1. The electroless plating equipment is simple and cost-saving. 2. The copper plating layer on the surface of the silicone rubber is uniform and dense with high strength. 3. The micro-actuator with silicone rubber as the driving body has good flexibility, corrosion resistance and working stability. It can be divided into required shapes within a certain size range, and can work stably in wet and dry environments. .

Description

technical field [0001] The invention relates to a copper plating process, which is suitable for flexible conductive treatment of electrodes of micro-actuators, or other products requiring flexible conductive treatment, and is a silicone rubber chemical copper plating process. Background technique [0002] Microactuators have become a high-tech technology for understanding and transforming the world due to their small shape or small operating scale. Its application prospects are broad, involving medicine, aviation, bioengineering and other fields, and it has been valued by industrially developed countries. However, as general microactuators, they are easy to damage the operating object and destroy the working environment during work. They are weak in action, have no conductive function, are difficult to achieve continuous and smooth, have large mechanical impact, and have a short service life. Therefore, its current research is committed to the development of miniaturization ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C18/38C23C18/20
Inventor 王庆良徐玲利葛世荣张绪平
Owner CHINA UNIV OF MINING & TECH
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