Method for treating chemical industry region tail water film-filter concentration liquid
A technology of chemical industrial parks and concentrates, applied in chemical instruments and methods, chemical/physical processes, neutralized water/sewage treatment, etc., can solve the problems of poor treatment effect of chemical oxidation method, secondary pollution, high treatment cost of evaporation concentration method, etc. question
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Embodiment 1
[0017] Put 10ml of composite functional adsorption resin NDA-88 into a jacketed glass adsorption column (Ф20×350mm). At room temperature (20-25°C), add 0.05%-0.3% polyaluminium-iron PACF to the membrane filter concentrate, stir for 10 minutes, let it stand for 10 minutes, filter, add 6mol / L sulfuric acid to adjust pH = 2-3, and use 30mL / h (the ratio of 30mL / h to resin volume 10mL is 3BV / h, that is, 3 resin bed volumes per hour) through the resin bed, and the processing capacity is 6000mL / batch (ie 600BV / batch). The COD of the original membrane filter concentrate is 628mg / L, and the COD of the effluent after resin adsorption is 77mg / L, which is colorless and transparent.
[0018] Use 20mL 6% (weight percent) NaOH aqueous solution and 30mL tap water at a temperature of 50±2°C to desorb the regenerated resin bed in turn. The desorption flow rate is 10mL / h (ie 1BV / h), and the COD desorption rate is 96.5%. . Finally, the resin was washed with 10 mL of 3% hydrochloric acid and 10...
Embodiment 2
[0020] Other operating conditions are the same as implementation example 1, the membrane filtration concentrated solution adsorption flow rate is doubled, after pretreatment, pass through the resin bed with the flow rate of 60mL / h (being 6BV / h), the adsorption treatment effect is as follows: former membrane filter concentrated solution The COD is 628mg / L, the COD of the adsorbed water is 89mg / L, and the COD removal rate is 85.8%. Use 30mL of 3% (weight percent) NaOH aqueous solution and 30mL of tap water at a temperature of 40±2°C to desorb the regenerated resin bed sequentially. The desorption flow rate is 5mL / h (ie 0.5BV / h), and the COD desorption rate is 96.6 %.
Embodiment 3
[0022] Other operating conditions are the same as implementation example 1, and the adsorption treatment effect is as follows: the COD of the concentrated solution of the former membrane filter is 416mg / L, the COD of the adsorbed water is 72mg / L, and the removal rate of COD is 82.7%. The desorption agent is 20mL 8% NaOH aqueous solution, and the desorption rate is 97.5%.
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