Method for treating chemical industry region tail water film-filter concentration liquid

A technology of chemical industrial parks and concentrates, applied in chemical instruments and methods, chemical/physical processes, neutralized water/sewage treatment, etc., can solve the problems of poor treatment effect of chemical oxidation method, secondary pollution, high treatment cost of evaporation concentration method, etc. question

Inactive Publication Date: 2008-07-09
NANJING UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the coagulation-sedimentation method has the disadvantages of large amount of mud production and easy to cause secondary pollution; the chemical oxidation method has the disadvantages of poor treatment effect and high cost; due to the low calorific value of waste water, the application of incineration method is also limited; Evaporation and concentration method has higher treatment cost
At present, the application of resin adsorption method to treat the tail water membrane filtration concentrate of chemical industrial parks has not been reported in the literature, but the resin adsorption method for the treatment of landfill leachate membrane filtration concentrate has been studied. The concentrated solution of the waste water has a brown-black color, a COD of about 5000-6000mg / L, and a pH of about 7. The main components are humus-like substances and some heavy metal ions, and most of them come from domestic waste landfills. Small, in terms of composition and properties, it is very different from the tail water membrane filter concentrate in the chemical industry park

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Put 10ml of composite functional adsorption resin NDA-88 into a jacketed glass adsorption column (Ф20×350mm). At room temperature (20-25°C), add 0.05%-0.3% polyaluminium-iron PACF to the membrane filter concentrate, stir for 10 minutes, let it stand for 10 minutes, filter, add 6mol / L sulfuric acid to adjust pH = 2-3, and use 30mL / h (the ratio of 30mL / h to resin volume 10mL is 3BV / h, that is, 3 resin bed volumes per hour) through the resin bed, and the processing capacity is 6000mL / batch (ie 600BV / batch). The COD of the original membrane filter concentrate is 628mg / L, and the COD of the effluent after resin adsorption is 77mg / L, which is colorless and transparent.

[0018] Use 20mL 6% (weight percent) NaOH aqueous solution and 30mL tap water at a temperature of 50±2°C to desorb the regenerated resin bed in turn. The desorption flow rate is 10mL / h (ie 1BV / h), and the COD desorption rate is 96.5%. . Finally, the resin was washed with 10 mL of 3% hydrochloric acid and 10...

Embodiment 2

[0020] Other operating conditions are the same as implementation example 1, the membrane filtration concentrated solution adsorption flow rate is doubled, after pretreatment, pass through the resin bed with the flow rate of 60mL / h (being 6BV / h), the adsorption treatment effect is as follows: former membrane filter concentrated solution The COD is 628mg / L, the COD of the adsorbed water is 89mg / L, and the COD removal rate is 85.8%. Use 30mL of 3% (weight percent) NaOH aqueous solution and 30mL of tap water at a temperature of 40±2°C to desorb the regenerated resin bed sequentially. The desorption flow rate is 5mL / h (ie 0.5BV / h), and the COD desorption rate is 96.6 %.

Embodiment 3

[0022] Other operating conditions are the same as implementation example 1, and the adsorption treatment effect is as follows: the COD of the concentrated solution of the former membrane filter is 416mg / L, the COD of the adsorbed water is 72mg / L, and the removal rate of COD is 82.7%. The desorption agent is 20mL 8% NaOH aqueous solution, and the desorption rate is 97.5%.

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Abstract

The invention discloses a treating method of tail water membrane filtering condensation fluid in chemical industry park, the steps of which are that the pre-treated membrane filtering condensation fluid goes through a device filled with resinous adsorbent under the common temperature and a flow quantity of 0.5-8BV / h, the absorbed water can be discharged after neutralizing with small capacity of alkali, desorbing and regenerating the resin by natrium hydroxydatum solution with the flow capacity of the desorbing agent is 0.5-3.0BV / h, the high concentration desorbing fluid disposes safely and the low concentration desorbing fluid can be periodically used to preparing next pluralities of desorbing agent. The invention can reduce the COD of the membrane filtering condensation fluid from about 600mg / L to about 80mg / L and finally realizes reducing and harmlessness of the polluted things of the membrane filtering condensation fluid. After desorbing of the resin, the desorbing rate is lager than 96%. The invention has the advantages of simple process, convenient operation, economy and high effective and good practicality without secondary pollution.

Description

technical field [0001] The invention relates to a method for treating the concentrated liquid of tail water membrane filtration in a chemical industrial park, specifically, a method for treating the concentrated liquid of tail water membrane filtration in a chemical industrial park by using a resin adsorbent. Background technique [0002] At present, my country has become a key area for the transfer of chemical industry in the world. A large number of chemical parks have been built along the coast and along the river. It is closer to the treatment method of urban domestic sewage, so the tail water after treatment is still difficult to meet the standard stably and contains many organic poisons, which will have a serious impact on the receiving water body. In the treatment of tail water, nanofiltration and reverse osmosis are more common methods for the treatment and reuse of chemical wastewater, but at the same time, a large amount of concentrated liquid is produced, which has...

Claims

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Application Information

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IPC IPC(8): C02F9/04C02F1/42C02F1/66B01J49/00B01J49/60
Inventor 李爱民闫蕾吴海锁张龙范俊钟声薛玉志王津南刘福强龙超周友冬卢宇飞
Owner NANJING UNIV
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