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Optical film

A technology of optical film and protective film, applied in the field of optical film, which can solve the problems of reduced beam transmittance, difficulty in maintaining aging stability, and high cost of light-diffusing film

Active Publication Date: 2008-07-16
FUJIFILM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, to implement this method in a concrete way, expensive zirconia fine particles must be combined with a binder to correct the refractive index, making the light-diffusing film expensive
Furthermore, it is difficult to stably combine various diffusing agents, or sometimes it is necessary to apply two light-diffusing layers, and the resulting problem is that rapid mass production is hardly feasible
[0007] As for an inexpensive light-diffusing film, JP-A-2004-271666 describes a method using melamine particles as a diffusing agent, but this method has a problem in high-temperature and high-humidity environments (specifically, 80°C and 90% RH), overall beam transmittance decreases, and aging stability is difficult to maintain due to changes in light scattering properties

Method used

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Experimental program
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preparation example Construction

[0076]

[0077] Examples of the production method of the light-transmitting particles used in the present invention include suspension polymerization, emulsion polymerization, soap-free emulsion polymerization, dispersion polymerization, and seed polymerization, and the light-transmitting particles can be produced by any of the methods. These production methods can be referred to, for example, in Takayuki Ohtsu and Masaetus Kinoshita, Kobunshi Gosei no Jikken Ho (Experimental Technique for the Synthesis of Polymer ), page 130 and pages 146-147; Kagaku Dojin Sha, Gosei Kobunshi (Synthetic Polymer) , Vol.1, pp.246-290, Cit , Vol.3, pp.1-108; US Pat. -5-297506, JP-A-2002-145919, JP-A-2003-147039 and JP-A-2003-171432 described methods.

[0078] In the preparation methods of melamine resin particles, benzoguanamine-melamine formaldehyde particles, etc., amino resins that are not sufficiently cured, that is, low-condensation amino resins, sometimes remain as impurities aft...

Embodiment 1

[0504] The average particle diameter of the organic resin particles is measured as follows.

[0505] The 50% volume diameter (median diameter) obtained by a laser diffraction / scattering particle size distribution measuring instrument [Master Sizer 2000 (trade name), manufactured by Malvern Instruments Ltd.] was used as the average particle diameter.

[0506] The layer thickness measurements for the shells are as follows.

[0507] The epoxy resin for embedding, the particles of the present invention and the curing agent were loaded into the embedding plate and mixed thoroughly, and the mixture was cured overnight in an oven at 60°C. The cured product was sectioned with an ultramicrotome [ULTRACUT N (trade name, manufactured by Reichert-Nissen)], and the particle flakes were imaged with a transmission electron microscope (TEM). The actual layer thickness of the shell is measured on TEM pictures.

[0508] [refractive index]

[0509] The refractive index can be measured by the ...

Embodiment 2

[0625] (Synthesis of amino resin particles 4)

[0626] In a four-necked flask, 75 parts of melamine, 75 parts of benzoguanamine, 238 parts of 37% formaldehyde and 1.07 parts of 10% aqueous sodium carbonate were added to obtain a mixture. While stirring the mixture, the polymerization was carried out by raising the temperature to 85° C. to obtain an initial condensate having a water compatibility of 250%. Separately, 6 parts of nonionic surfactant EMULGEN 430 (manufactured by Kao Corp., polyoxyethylene oleyl ether) was dissolved in 2,455 parts of water, and the temperature of the surfactant aqueous solution was raised to 50°C, followed by stirring. The initial condensate obtained above was added to the aqueous surfactant solution under stirring to obtain an emulsion of the initial condensate. After adding thereto 90 parts of a 5% aqueous solution of dodecylbenzenesulfonic acid, the emulsion was condensed and cured by keeping at 50-60° C. for 3 hours to obtain an emulsion of a ...

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Abstract

An optical film comprises: a transparent support; and a hardcoat layer comprising a heat- and / or ionizing radiation-curable resin and an organic resin particle having a refractive index of 1.60 or more, wherein a percentage change in an entire beam transmittance between before and after the optical film is exposed to an environment at a temperature of 80 DEG C. and a relative humidity of 90% for 500 hours is 5% or less.

Description

1. Technical field [0001] The present invention relates to an optical film, and a polarizing plate and an image display each applying the optical film. More particularly, the present invention relates to an optical film intended to enhance viewing angle performance and visibility of displays (eg, CTR, PDP, ELD, SED, LCD) for image display in computers, word processors, televisions, etc. , and also relates to a polarizer and a display, in particular a liquid crystal display (LCD), each applying the optical film. 2. Background technology [0002] Liquid crystal displays usually consist of polarizers and liquid crystal cells. [0003] In the TN-type TFT liquid crystal display, an optical compensation film is inserted between the polarizing film and the liquid crystal, thereby realizing a liquid crystal display that ensures high display quality. [0004] However, there is a problem with this type of display, that is, tone reversal occurs in the downward direction of the panel....

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G02B5/30G02B1/04G02F1/1335
CPCG02B5/0226G02B1/105Y10T428/25C08G73/02G02B5/0278G02B5/0242Y10T428/1041G02B1/14C09K2323/031
Inventor 加藤进也近藤俊一米山博之朝仓彻也佐竹亮
Owner FUJIFILM CORP