Preparation of catalyst for processing industrial wastewater and using method thereof

A technology for industrial wastewater and catalysts, applied in the direction of physical/chemical process catalysts, molecular sieve catalysts, chemical instruments and methods, etc., can solve the problems of energy consumption, high cost, and large energy consumption in electrolytic oxidation processes, and reduce catalyst separation and recovery problems, improve the binding strength, and avoid the effects of decreased activity

Active Publication Date: 2008-09-10
FUZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, these methods have their own disadvantages: the wet catalytic oxidation process requires high temperature and consumes a lot of energy; the electrolytic oxidation process not only consumes energy, but also has low processing capacity; Advanced treatment of oxidized pollutants, but the treatment capacity is very limited; room temperature catalytic oxidation process has weak treatment capacity and limited applicable objects
However, the long-term use of the catalyst in the solution will cause the loss of active components and additives, resulting in the catalyst being easily deactivated and unable to achieve industrialization.

Method used

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  • Preparation of catalyst for processing industrial wastewater and using method thereof
  • Preparation of catalyst for processing industrial wastewater and using method thereof
  • Preparation of catalyst for processing industrial wastewater and using method thereof

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preparation example Construction

[0011] The preparation steps of the present invention are as follows:

[0012] (1) The molecular sieve powder is placed in a water-soluble metal salt solution that can be decomposed into a P-type semiconductor oxide at a high temperature, and the weight ratio of the two is 1:5 to 1:50, and it is fully stirred at a temperature of 10 to 95°C for 8 to 8. After standing for 48 hours, filter off excess solution, dry at 60-200°C at low temperature, and then bake at 300-800°C for 2-6 hours to obtain a powder with a weight content of 0.5-10% P-type semiconductor oxide catalyst;

[0013] (2) Forming of the catalyst: adding 5-20 wt% binder and 1-3 wt% pore-enlarging agent to the powder catalyst prepared in step (1) in a percentage by weight of 77-94 wt%, and mixing uniformly, in the mixture Add a dilute nitric acid solution with a concentration of 2 to 10% that accounts for 30 to 50 wt% of the mixture, mix well and extrude into strips with an extruder, dry at 80 to 150°C and dry at 400...

Embodiment 1

[0020] Preparation of MnO by Ion Exchange Method 2 / ZSM-5 catalyst

[0021] Weigh 50 grams of H-ZSM-5 molecular sieve with a silicon-aluminum ratio of 25 into a beaker, add 1.0 L of an aqueous solution containing 6.0 grams of manganese sulfate, stir at 80°C for 24 hours, let it stand and pour off the supernatant, and put it at 120°C After lower drying, the temperature was increased to 300°C at a rate of 2°C / min for 4 hours. Grind the catalyst prepared by roasting into powder, add 15 grams of hydrated alumina (pseudoboehmite), 3 grams of organic pore-enlarging agent, mix well, add 40 mL of dilute nitric acid solution with a concentration of 5.0 V%, and continue kneading to form a block shape, and then extruded into a clover shape of φ=2.0mm with an extruder. After drying at 100°C for 2 hours, the temperature was raised to 500°C at a rate of 2°C / min for 4 hours, and the clover-shaped MnO was obtained after cooling. 2 / ZSM-5 catalyst. MnO in this catalyst 2 The content is ab...

Embodiment 2

[0023] Preparation of Ag by Ion Exchange Method 2 O / Y catalyst

[0024] Take by weighing 50 grams of H-Y molecular sieves in a beaker, add 1.0L of an aqueous solution containing 3.0 grams of silver nitrate, then obtain Ag by the method in Example 1 2 Ag with O content about 3.0w% 2 O / Y catalyst.

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Abstract

The invention provides a preparation and application method for treating a catalyst of industrial waste water. The preparation method of the invention adopts a molecular sieve as a carrier, one or a plurality of P-type semiconductor oxides such as MnO2, CeO2, Ag2O, CuO, etc. is / ,are loaded on the molecular sieve in a way of ion-exchange and finally a supported catalyst containing the P-type semiconductor oxides is obtained through molding; and the catalyst is used when ozone and light are coexisted. The preparation and application method of the invention aims at the disadvantages of that active constituents of the catalyst and an addition agent in the combination technique of ozone and catalyst are lost easily, active constituents are loaded on the molecular sieve carrier in the way of ion-exchange so as to improve the combination binding capacity of the active constituents and the carrier; and an electronic addition agent can be substituted through a light electro-donating effect, so as to effectively provide electrons in a long term and promote the catalyst and the ozone to generate active matters; the coaction of the catalyst and the ozone can enhance the activity stability of the catalyst and prolong service life, thus being conducive to industrialization of the technologies.

Description

technical field [0001] The invention belongs to the field of chemical catalysts, and more specifically relates to the preparation and application method of a catalyst for treating industrial wastewater. Background technique [0002] Treatment and reuse of industrial wastewater is a major aspect of environmentally friendly production. The widely used industrial wastewater treatment technologies are conventional methods such as physical adsorption, chemical precipitation and microbial decomposition. These treatment methods cannot completely remove the pollutants in the wastewater, and the treated wastewater cannot be reused. For this reason, wastewater treated by conventional processes must undergo deep oxidation treatment through wet catalytic oxidation, electrolytic oxidation, ozone oxidation, photocatalysis, and room temperature catalysis to further reduce pollutants in wastewater. However, these methods have their own disadvantages: the wet catalytic oxidation process re...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J29/48B01J29/12B01J29/46C02F1/30C02F1/78
Inventor 付贤智刘平吴棱陈旬王绪绪戴文新员汝胜丁正新苏文悦侯乙东
Owner FUZHOU UNIV
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