Method for processing high-toxicity high-concentration highly salt-containing organic waste water with biochemistry combination process of catalytic oxidation
A technology of catalytic oxidation and combined process, applied in the field of water treatment, can solve the problems of high treatment cost, difficult biological treatment to play a role, huge treatment facilities, etc., to achieve the effect of improving the degree of biodegradability
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Embodiment 1
[0036] Example 1: The ultra-high salinity pesticide wastewater with a salinity of 10% first enters the three-effect vacuum distillation desalter treatment unit in the combined treatment technology, the pressure of the first distillation tower is 10kg, and the temperature is 90°C ;The pressure of the second distillation tower is 7kg and the temperature is 75°C; the pressure of the third distillation tower is 3kg and the temperature is 60°C; The effluent of the device ensures that the salt content is 0.9%, and the crystallized salt is recycled and reused. After testing, the water quality changes after treatment by this treatment unit are shown in the table below:
[0037] serial number
[0038] The waste water with a salt content of 0.9% from the three-effect distillation desalter 1 is pretreated by the grid well 10 and the regulating pool 2, and then lifted into the micro-electrolytic catalytic oxidation pool 3 by the submersible lift pump 11, and the residence time o...
Embodiment 2
[0047] Embodiment 2: the organic wastewater with a salt content of 6% first enters the three-effect vacuum distillation desalter treatment unit in the combined treatment technology, the pressure of the first distillation tower is 9kg, and the temperature is 85°C; the second distillation The pressure of the tower is 6.5kg and the temperature is 70°C; the pressure of the third distillation tower is 3.5kg and the temperature is 55°C; in this treatment unit, the ultra-high salt content is removed, and the effluent of the desalter after treatment ensures The salt content is 0.6%, and the crystallized salt is recycled and reused. After testing, the water quality changes after treatment by this treatment unit are shown in the table below:
[0048] serial number
Indicator name
The processing unit is flooded
The treatment unit effluent
Removal rate
Remark
1
salt content
6%
0.6%
90%
2
COD Cr
4000mg / l
2...
Embodiment 3
[0062] Embodiment 3: process high salinity (CaCl 2 be the main salt) the organic waste water technology of 3% salinity, the specific implementation is expressed as follows: high salinity (CaCl 2is the main salt) organic wastewater technology first enters the three-effect distillation desalter treatment unit in the combined treatment technology, the pressure of the first distillation tower is 8kg, and the temperature is 85°C; the pressure of the second distillation tower is 5kg, and the temperature is 65°C; the pressure of the third distillation tower is 3kg, and the temperature is 50°C; in this treatment unit, the ultra-high salt content is removed, and the salt content of the treated desalter effluent is guaranteed to be 0.5%, and the crystallized salt is processed Recycle and reuse. After testing, the water quality changes after treatment by this treatment unit are shown in the table below:
[0063] serial number
Indicator name
The processing unit is flood...
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