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Fiber pervasion swelling agent and method for dyeing the same

A technology of bulking agent and fiber, which is applied in the field of fiber treatment and enhanced fiber penetration and expansion, and can solve the problems of increasing vat dye leuco, leuco acid stability, aggravated polyester microfiber damage, and decreased leather strength. Achieve the effects of exempting from environmental protection and human hazards, enhancing coloring rate, and increasing stability

Active Publication Date: 2010-10-13
INST OF WOOL & HEMP TEXTILE SCI SHANGHAI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Some foreign related patents have made some improvements in solving the above problems, but there are certain problems: R.C.SHAH (Textile Chemist and Colorist, VOL4, N011, NOV7, 1972, P59-61) can delay the oxidation speed of hydrosulfite by adding protective colloid , thereby increasing the stability of vat dye leucosomes and leuco acids
However, due to the aggravation of polyester microfiber damage caused by high temperature, the strength of leather is reduced, and at the same time, the energy consumption in production is high. This means of improving color fastness by temperature is greatly limited.
[0009] Traditional penetrants such as pull open powder BX, Pingping plus O, and penetrant OPE phosphate are all hydrophilic, and they can neither make the water-insoluble solid dye particles effectively wet and penetrate, nor make the crystallization area of ​​the fiber Effective swelling to accept dyes; combined with hydrophilic dispersants including sodium lignin sulfonate, dispersant IW, dispersant N, dispersant MF, and dispersant CNF together with the above penetrating agents, it cannot achieve both Wet dye suspension particles and puffed fibers make the suspension dye uniform and have good color matching

Method used

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  • Fiber pervasion swelling agent and method for dyeing the same
  • Fiber pervasion swelling agent and method for dyeing the same
  • Fiber pervasion swelling agent and method for dyeing the same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0067] Embodiment 1: Polyester fiber and polyurethane composition synthetic leather dyeing

[0068] Synthetic leather composed of 0.02 denier polyester fiber and polyurethane, unit weight 700g / M 2 , Dye with C.1.VAT.Brown.5#, 6% (2006.11 / 22) with vat dye leuco, leuco acid dyeing process.

[0069] (A) make the reducing solution of the present invention according to Table 1, that is, three combinations of composite reducing agent (i.e. hydrosulfite 10.8g / L and sodium sulfite 5.4g / L, 27g / L in total), solid NaOH and water to prepare the reducing solution, wherein three combinations Composite reducing agent concentration is 27.0g / L, and NaOH concentration is 11.5g / L, adjusts leucosome to dyestuff reduction with dry vat method, reducing solution: dyestuff=37.5:1 (weight ratio), after 8 minutes heating water (with Dye-reducing leuco body fluid (1:1) is used until the mixing temperature is 50°C;

[0070] (B) add dispersing agent such as lignosulfonate ammonium salt and defoamer (the...

Embodiment 2

[0077] Embodiment 2: Synthetic leather dyeing composed of superfine polyamide and polyurethane

[0078] 0.02 denier superfine polyamide:polyurethane=65%:35% by weight mixed fiber was dyed.

[0079] Make reducing solution of the present invention by table 1, wherein hydrosulfur powder: thiourea dioxide: sodium sulfite=1.0:1.0:1.0 dyeing process is the same as embodiment 1, just does not pass through the step (B) dyeing pre-dyeing stage lye in embodiment 1 to adjust the dye bath pH treatment, directly add acidic buffer solution in the reducing leuco body, adjust the dye into leuco acid, add the osmotic swelling agent of the present invention: 0.00025 parts by weight of lauryl azone, 2.0 parts by weight of N-methylpyrrolidone, diacetone alcohol 8.0 parts by weight, 10.0 parts by weight of ethyl salicylate, 9.0 parts by weight of isopropyl salicylate, dye with leuco-chromic acid, heat up to 105°C at 1°C / 2min, and keep warm for 40 minutes. The color fastness is very good.

[0080...

Embodiment 3

[0084] Embodiment 3: Polyurethane polymer composition synthetic leather dyeing

[0085] Polyurethane polymer dyed. Prepare reducing solution of the present invention by table 1, wherein hydrosulfur powder: thiourea dioxide: sodium sulfite=2:4:1, dyeing process is the same as embodiment 1, just do not pass through the step (B) dyeing pre-dyeing stage in embodiment 1 and adjust with lye Dyeing bath pH treatment, in the step (A) in embodiment 1, directly add acidic buffering agent, adjust dyestuff into leucoic acid, add osmotic swelling agent of the present invention: lauryl azone 0.0002 weight part, N-methyl 4 parts by weight of pyrrolidone, 6.0 parts by weight of diacetone alcohol, 8.0 parts by weight of ethyl salicylate, 10.0 parts by weight of isopropyl salicylate, dyed with reduced leucochromic acid, 1 ° C / 2 min to 85 ° C, at 85 ° C Keep warm for 45-60 minutes for dyeing, the color fastness is very good.

[0086] The following table 4 is the dyeing result of the present ...

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Abstract

The invention discloses a fiber penetrating swelling agent which comprises the compositions in weight portion: 0.00016 to 0.0006 portion of laurocapram, 1 to 5 portions of N-methyl pyrrolidone, 5 to 10 portions of diacetone alcohol, 5 to 15 portions of ethyl salicylate, and 5 to 10 portions of isopropyl salicylate. The invention also discloses a method for dyeing by the fiber penetrating swelling agent, comprising the following steps that: a reducing agent and sodium hydrate are used for reducing the dye by a vatting method; the weight ratio of a reducing solution to the dye is 37.5: 0.8 to 2.0; a leveling agent and the fiber penetrating swelling agent are added to dye or a buffering agent is added to adjust the pH value and is dyed by vat acid, the temperature is reduced and the mixtureis washed; the mixture is subjected to oxidizing to develop color, fixing, reducing temperature and washing; the fresh water bath is performed, the fiber penetrating swelling agent is reduced and washed, and the temperature is reduced and the fiber penetrating swelling agent is produced. The fiber penetrating swelling agent ensures that the dye insoluble in water is effectively moistened and penetrated, and the fiber crystallizing area is effectively swelled to receive the dye; the fiber penetrating swelling agent ensures that a suspended solid is dyed evenly, has good homochromatism, improves the degree of dyeing, and solves the 'white core' problem of fiber.

Description

technical field [0001] The invention relates to the technical field of fiber treatment, especially the technical field of enhancing the permeable bulking property of fibers. Background technique [0002] Vat dyes have good color fastness, especially good color fastness to sunlight and soaping, but there are still some problems such as poor permeability, suspension dyeing color flower and unstable leuco body when dyed with leuco acid and leuco body. The problem is not resolved. [0003] The vat dye leuco dyeing method is to turn the insoluble vat dye into a water-soluble dye through alkali treatment, but at this time, the dyed sodium salt is no longer the original color, so it is called leuco, and the dye leuco is dyed The method is called leucosome staining. After dyeing, use the oxidation method to return to the original insoluble color development state. Leuco dyeing with traditional vat dyes, because the pH is around 12.0, will cause too much damage to the fiber, and i...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06P1/22D06M13/352D06P1/642D06M13/224
Inventor 武达机张德良方磊周勤谦姚民富
Owner INST OF WOOL & HEMP TEXTILE SCI SHANGHAI
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