Fiber pervasion swelling agent and method for dyeing the same
A technology of bulking agent and fiber, which is applied in the field of fiber treatment and enhanced fiber penetration and expansion, and can solve the problems of increasing vat dye leuco, leuco acid stability, aggravated polyester microfiber damage, and decreased leather strength. Achieve the effects of exempting from environmental protection and human hazards, enhancing coloring rate, and increasing stability
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Embodiment 1
[0067] Embodiment 1: Polyester fiber and polyurethane composition synthetic leather dyeing
[0068] Synthetic leather composed of 0.02 denier polyester fiber and polyurethane, unit weight 700g / M 2 , Dye with C.1.VAT.Brown.5#, 6% (2006.11 / 22) with vat dye leuco, leuco acid dyeing process.
[0069] (A) make the reducing solution of the present invention according to Table 1, that is, three combinations of composite reducing agent (i.e. hydrosulfite 10.8g / L and sodium sulfite 5.4g / L, 27g / L in total), solid NaOH and water to prepare the reducing solution, wherein three combinations Composite reducing agent concentration is 27.0g / L, and NaOH concentration is 11.5g / L, adjusts leucosome to dyestuff reduction with dry vat method, reducing solution: dyestuff=37.5:1 (weight ratio), after 8 minutes heating water (with Dye-reducing leuco body fluid (1:1) is used until the mixing temperature is 50°C;
[0070] (B) add dispersing agent such as lignosulfonate ammonium salt and defoamer (the...
Embodiment 2
[0077] Embodiment 2: Synthetic leather dyeing composed of superfine polyamide and polyurethane
[0078] 0.02 denier superfine polyamide:polyurethane=65%:35% by weight mixed fiber was dyed.
[0079] Make reducing solution of the present invention by table 1, wherein hydrosulfur powder: thiourea dioxide: sodium sulfite=1.0:1.0:1.0 dyeing process is the same as embodiment 1, just does not pass through the step (B) dyeing pre-dyeing stage lye in embodiment 1 to adjust the dye bath pH treatment, directly add acidic buffer solution in the reducing leuco body, adjust the dye into leuco acid, add the osmotic swelling agent of the present invention: 0.00025 parts by weight of lauryl azone, 2.0 parts by weight of N-methylpyrrolidone, diacetone alcohol 8.0 parts by weight, 10.0 parts by weight of ethyl salicylate, 9.0 parts by weight of isopropyl salicylate, dye with leuco-chromic acid, heat up to 105°C at 1°C / 2min, and keep warm for 40 minutes. The color fastness is very good.
[0080...
Embodiment 3
[0084] Embodiment 3: Polyurethane polymer composition synthetic leather dyeing
[0085] Polyurethane polymer dyed. Prepare reducing solution of the present invention by table 1, wherein hydrosulfur powder: thiourea dioxide: sodium sulfite=2:4:1, dyeing process is the same as embodiment 1, just do not pass through the step (B) dyeing pre-dyeing stage in embodiment 1 and adjust with lye Dyeing bath pH treatment, in the step (A) in embodiment 1, directly add acidic buffering agent, adjust dyestuff into leucoic acid, add osmotic swelling agent of the present invention: lauryl azone 0.0002 weight part, N-methyl 4 parts by weight of pyrrolidone, 6.0 parts by weight of diacetone alcohol, 8.0 parts by weight of ethyl salicylate, 10.0 parts by weight of isopropyl salicylate, dyed with reduced leucochromic acid, 1 ° C / 2 min to 85 ° C, at 85 ° C Keep warm for 45-60 minutes for dyeing, the color fastness is very good.
[0086] The following table 4 is the dyeing result of the present ...
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