Waste water centralized processing method in chemical industrial park
A technology for centralized treatment and chemical parks, applied in the direction of oxidized water/sewage treatment, water/sewage treatment, chemical instruments and methods, etc., can solve threats, water environment hazards in chemical parks, and affect the quality of effluent water, etc., to prolong the service life , easy large-scale industrial application, cost-saving effect
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Embodiment 1
[0021] Introduce chemical wastewater into the electrolytic cell for electrolysis, adjust the pH value of the wastewater to 6.0, control the electrolysis time to 30min, and the electrolysis pressure to 10V; then control the COD concentration of the effluent to 1000mg / L by diluting with water, and use dilute sulfuric acid or Ca( Oh) 2 Adjust the pH value to 6.0, add ammonium chloride to adjust the ammonia nitrogen concentration in the wastewater to 50mg / L, add potassium phosphate to adjust the phosphate concentration in the wastewater to 10mg / L, and add the trace element compound CoCl 2 ·6H 2 O, MnCl 2 4H 2 O, ZnCl 2 、NiCl 2 ·6H 2 O and (NH 4 ) 6 Mo 7 o 24 The mixture enters the high-efficiency biological fluidized bed, so that the concentration is 20-40μg / L, the residence time is 18h, and the ceramsite is used as the biological carrier; finally, the COD concentration of the effluent is controlled to 100mg / L, and the ozone-activated carbon process is used for treatment....
Embodiment 2
[0023] The chemical wastewater enters the electrolytic tank for electrolysis, adjusts the pH value of the wastewater to 7.0, controls the electrolysis time to 20 minutes, and the electrolysis pressure to 8V; then controls the COD concentration of the effluent to 1500mg / L, adjusts the pH value to 7.0, and adds ammonium sulfate to adjust the wastewater The ammonia nitrogen concentration is 75mg / L, adding potassium dihydrogen phosphate to adjust the phosphate concentration in the wastewater to 15mg / L, adding the trace element compound CoCl 2 ·6H 2 O, MnCl 2 4H 2 O, ZnCl 2 、NiCl 2 ·6H 2 O and (NH 4 ) 6 Mo 7 o 24 The mixture, so that the concentration is 1-20μg / , enters the intermittent aerated biological particle bed, and each operation cycle of the intermittent aerated biological particle bed includes water inflow, reaction, sedimentation, drainage and no-load, and the control time is 0.5 h, 10h, 3h, 0.5h, 2h, every 16h is a cycle, and zeolite is used as the biological c...
Embodiment 3
[0025] The chemical wastewater is introduced into the electrolytic tank for treatment, the pH value of the wastewater is adjusted to 9.0, the electrolysis time is controlled to 60min, and the electrolysis pressure is 5V; then the COD concentration of the effluent is controlled to 500mg / L, the pH value is adjusted to 7.0, and ammonium sulfate is added to adjust the wastewater The concentration of ammonia nitrogen is 25mg / L, adding sodium dihydrogen phosphate to adjust the phosphate concentration of wastewater to 5mg / L, adding trace element compound CoCl 2 ·6H 2 O, MnCl 2 4H 2 O, ZnCl 2 、NiCl 2 ·6H 2 O and (NH 4 )6Mo 7 o 24The mixture, so that the concentration is 60-80μg / L, enters the high-efficiency biological fluidized bed, the residence time is 24h, and activated carbon is used as the biological carrier; finally, the COD concentration of the effluent is controlled to 100mg / L, and the ozone-activated carbon process is used for treatment. The dosage is 5 mg / L, the resi...
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