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57results about How to "Ease of large-scale industrial application" patented technology

Method for processing and separate-recycling printing and dyeing wastewater

The invention discloses a method for processing and separate recycling of printing and dyeing wastewater, which comprises the following steps: after the printing and dyeing wastewater is firstly processed by an anaerobic reactor, a hypoxia reactor and an aerobic reactor, the separate recycling of part of the water is used for a desizing process of printing and dyeing technology; then, after the rest wastewater is processed by an aerator biofilter, the separate recycling of the part of the water is used for a boiling-off process of the printing and dyeing technology; then, after the rest wastewater is processed by an ultrafiltration reactor, the separate recycling of the part of the water is used for bleaching process and mercerization process of the printing and dyeing technology; finally, the rest water is processed by an anti-permeability reactor and the separate recycling of the part of the water is used for dyeing process, printing process and ordering process. After being processed by the invention, the printing and dyeing wastewater can be carried out the separate recycling quickly and high-efficiently and the recycling rate of the wastewater reaches more than 70 percent; meanwhile, the fee of processing and recycling the wastewater can be saved; the service life of advanced treatment equipment can be prolonged, which is easy for a large-scale industrialized application.
Owner:NANJING UNIV

3D direct writing zirconium oxide ceramic ink

The invention relates to 3D direct writing zirconium oxide ceramic ink, which comprises zirconium oxide particles, a solvent, a binder, a dispersant and a salt, wherein the particle size of the zirconium oxide particles is 0.1-2 [mu]m, the solid content of the zirconium oxide particles in the ink is 40-58 vol%, the dispersant is one or a variety of materials selected from polyacrylic acid, polyvinyl acid, ammonium polyacrylate, polyvinyl acid salt, polyacrylate, polycarboxylate and polyacetyl imine, the dispersant accounts for 0.1-2% of the mass of the zirconium oxide particle dry powder, andthe salt is one or a variety of materials selected from ammonium chloride, zinc acetate, sodium chloride, magnesium chloride, potassium chloride, barium chloride, ammonium bicarbonate, anhydrous calcium chloride, potassium carbonate, sodium bicarbonate, sodium carbonate, anhydrous sodium carbonate, anhydrous sodium acetate, anhydrous calcium chloride, copper sulfate, basic copper carbonate, ammonium sulfate, ammonium bicarbonate, potassium aluminum sulfate and sodium citrate, and accounts for 0.001-0.1% of the mass of the ink. According to the present invention, the 3D direct writing zirconiumoxide ceramic ink can be printed at the room temperature, has high solid content while can flow out of the fine spraying nozzle and cannot cause the clogging, can be quickly cured into the fine wirewith a certain strength, and has good rheological property.
Owner:CENT SOUTH UNIV

Macrostructure and microstructure controllable hydroxyapatite porous ceramic, preparation method thereof and application of ceramic

The invention discloses a macrostructure and microstructure controllable hydroxyapatite porous ceramic, a preparation method thereof and an application of the ceramic. The hydroxyapatite porous ceramic is subjected to 3D (three-dimensional) direct-writing to obtain a three-dimensional structure, and freeze pouring regulation is performed to obtain a microstructure porous structure. A raw materialA is added into a solvent containing dispersing agents and mixed with the solvent to obtain suspension liquid, and then gel is added into the suspension liquid and mixed with the suspension liquid toobtain slurry. The raw material A comprises hydroxyapatite powder, the slurry passes 3D direct-writing equipment and is controlled to be in a gel state when passing the direct-writing equipment, the slurry is printed and frozen to obtain a green body with a three-dimensional structure, and the green body is freeze-dried and sintered to obtain the macrostructure and microstructure controllable hydroxyapatite porous ceramic. Direct-writing and freeze pouring technologies are initiatively and efficiently combined, the obtained hydroxyapatite porous ceramic is used as a bone scaffold, and the customization requirements of different bone tissues can be met.
Owner:CENT SOUTH UNIV

Mangneto modified ceramsite filler, preparation method thereof and application of modified filler in wastewater processing

The invention which discloses a mangneto modified ceramsite filler, a preparation method thereof and an application of the modified filler in wastewater processing belongs to the wastewater processing field. The modified filler is a magnetic filler which treats ceramsite as a base material and contains mixed magnetic powder, a biological affinity substance and a dispersant. The preparation methodof the modified filler comprises the following steps: 1, respectively immersing ceramsite in an acid liquor and an alkali liquor; 2, adding modification materials, and processing; and 3, mixing, and molding calcining. A method for improving the biological processing of the wastewater with the modified filler is characterized in that: the mangneto modified ceramsite filler is filled in an aerobic reactor according to a packing ratio of 35-50%, the wastewater is introduced, the retention time is 4-6, the volume loading is controlled at 0.5-2kgCOD / (m<3>.d), and the gas-water ratio in the aeration process is 5-15:1. Characteristics of the mangneto modified ceramsite filler are fully utilized in the invention to allow the wastewater processing efficiency to be improved, the wastewater processing cost to be saved, the service life of advanced processing equipment to be prolonged and large scale industrialization application to be easy.
Owner:NANJING UNIV

3D direct writing zirconium oxide colloid ink

The invention relates to 3D direct writing zirconium oxide colloid ink, which comprises the following raw materials: zirconium oxide particles, a solvent, a binder, an acid agent, an alkali agent anda dispersant, wherein the particle size of the zirconium oxide particles is 0.05-2 [mu]m, the solid content of the zirconium oxide particles in the ink is 40-56 vol%, the dispersant is one or a variety of materials selected from polyacrylic acid, polyvinyl acid, ammonium polyacrylate, polyethyleneimine, polyacrylate, polyvinyl acid salt and polycarboxylate, the dispersant accounts for 0.1-4 wt% ofthe mass of the zirconium oxide particle dry powder, the amount of the acid does not exceed 0.1% of the mass of the ink, the amount of the alkali does not exceed 0.1% of the mass of the ink, and a molar ratio of the hydrogen ion to the hydroxide ion in the acid agent and the alkali agent is (0.01-4):1. According to the present invention, with the application of the 3D direct writing zirconium oxide colloid ink to print at the room temperature, the high solid content can be provided while the 3D direct writing zirconium oxide colloid ink can be outflow from the fine spraying nozzle and the clogging cannot occur, the 3D direct writing zirconium oxide colloid ink can be rapidly cured into the fine wire with a certain strength so as to be used for various modeling, and the 3D direct writing zirconium oxide colloid ink has good rheological property.
Owner:CENT SOUTH UNIV

Method and device for preparing fluorinated graphene and high purity lithium fluoride as by-product

The invention relates to a method and device for preparing fluorinated graphene and high purity lithium fluoride as a by-product. The method comprises 1, putting graphene oxide in a fluorination furnace, carrying out vacuum-pumping on the fluorination furnace, feeding fluorine-containing gas into the fluorination furnace and carrying out a fluorination reaction process, and 2, feeding protection gas into the fluorination furnace to cool the materials and to replace the fluorine-containing gas, wherein the cooled materials in the furnace is fluorinated graphene, feeding the replaced fluorine-containing gas into a high purity lithium hydroxide solution for an absorption reaction and separating high purity lithium fluoride when the system pH is in a range of 2-3. The method and device can realize preparation of high-grade fluorinated graphene and preparation of high purity lithium fluoride from a fluorine resource, realize recovery and reuse of excess fluorine-containing gas in the high purity lithium hydroxide solution, greatly improve a fluorine raw material utilization rate, save a fluorine resource and solve the environmental bottleneck problems. The lithium fluoride as a by-product is used for preparation of a lithium ion battery key material lithium hexafluorophosphate, becomes a novel economic growth point and has good economic benefits and environmental benefits.
Owner:DO FLUORIDE CHEM CO LTD

Method for reacting gas and solid particles

ActiveCN101884897AAvoid agglomeration into dense lumpsUniform contact reactionChemical/physical processesGas solidSolid particle
The invention discloses a method for reacting gas and solid particles, which comprises the step of contacting the gas with the solid particles. The contact is performed in reaction equipment, and the reaction equipment comprises a reaction kettle, a feed inlet and a gas outlet. The interior of the reaction kettle also comprises a stirrer; and a gas-solid separator is arranged on the gas outlet. The pore diameter and the porosity of the pores contained in the gas-solid separator guarantee that the gas can pass the pores and the solid particle cannot pass the pores. A stirring rod of the stirrer extends out of the reaction kettle, and the contacting position of the stirring rod and the reaction kettle is sealed, so that the reaction kettle does not communicate with the outside. The solid particles and the gas or substances capable of generating gas are added into the reaction kettle through the feed inlet, and the solid particles and the gas or the gas generated by the substances capable of generating gas contact to perform the reaction of the gas and the solid particles under the stirring of the stirrer. The contact reaction of the gas and the solid particles is more uniform and the phenomenon that the solid particles are coalesced into dense blocks is avoided. Therefore, the method for reacting the gas and the solid particles can lower the labor intensity and reduce the environmental pollution, obviously reduces the production cost, and is easy for large-scale industrial application.
Owner:CHINA PETROLEUM & CHEM CORP +1

Inner-cooling inert anode for electrolytic aluminum

InactiveCN103820817AAffect production qualityAvoid defects such as high impact costCurrent distributionThermal stability
The invention relates to an inert anode for electrolytic aluminum, and belongs to the field of electrolytic aluminum equipment. The inner-cooling inert anode for the electrolytic aluminum comprises a conductive rod and a metal or metal matrix composite anode connected with the conductive rod, wherein an inner cavity of the metal or metal matrix composite anode adopts a hollow structure, and is communicated with an external circulatory cooling system and a heat exchanger via a cooling medium inlet and a cooling medium outlet which are formed in the metal or metal matrix composite anode. The inert anode has the following advantages that 1, the advantages of excellent conductivity, thermal conductivity, machining property, uniform anode current distribution and the like of a metal inert anode are inherited; the defects that the metal inert anode pollutes molten aluminum during electrolytic aluminum production and is high in cost are overcome; 2, the advantages of good thermal stability of metal oxide ceramic and metal ceramic anodes and easiness in large-scale industrial application are provided; the defects that a metal oxide ceramic inert anode is poor in conductivity and low in thermal vibration resistance, and connection between the metal oxide ceramic inert anode and a metal component of a power supply system is difficult are overcome; and 3, the novel inert anode can fully meet a technical requirement of the electrolytic aluminum production, and is very small in consumption.
Owner:饶云福 +5

Method for processing and separate-recycling printing and dyeing wastewater

The invention discloses a method for processing and separate recycling of printing and dyeing wastewater, which comprises the following steps: after the printing and dyeing wastewater is firstly processed by an anaerobic reactor, a hypoxia reactor and an aerobic reactor, the separate recycling of part of the water is used for a desizing process of printing and dyeing technology; then, after the rest wastewater is processed by an aerator biofilter, the separate recycling of the part of the water is used for a boiling-off process of the printing and dyeing technology; then, after the rest wastewater is processed by an ultrafiltration reactor, the separate recycling of the part of the water is used for bleaching process and mercerization process of the printing and dyeing technology; finally, the rest water is processed by an anti-permeability reactor and the separate recycling of the part of the water is used for dyeing process, printing process and ordering process. After being processed by the invention, the printing and dyeing wastewater can be carried out the separate recycling quickly and high-efficiently and the recycling rate of the wastewater reaches more than 70 percent; meanwhile, the fee of processing and recycling the wastewater can be saved; the service life of advanced treatment equipment can be prolonged, which is easy for a large-scale industrialized application.
Owner:NANJING UNIV

Mangneto modified ceramsite filler, preparation method thereof and application of modified filler in wastewater processing

The invention which discloses a mangneto modified ceramsite filler, a preparation method thereof and an application of the modified filler in wastewater processing belongs to the wastewater processing field. The modified filler is a magnetic filler which treats ceramsite as a base material and contains mixed magnetic powder, a biological affinity substance and a dispersant. The preparation method of the modified filler comprises the following steps: 1, respectively immersing ceramsite in an acid liquor and an alkali liquor; 2, adding modification materials, and processing; and 3, mixing, and molding calcining. A method for improving the biological processing of the wastewater with the modified filler is characterized in that: the mangneto modified ceramsite filler is filled in an aerobic reactor according to a packing ratio of 35-50%, the wastewater is introduced, the retention time is 4-6, the volume loading is controlled at 0.5-2kgCOD / (m<3>.d), and the gas-water ratio in the aeration process is 5-15:1. Characteristics of the mangneto modified ceramsite filler are fully utilized in the invention to allow the wastewater processing efficiency to be improved, the wastewater processing cost to be saved, the service life of advanced processing equipment to be prolonged and large scale industrialization application to be easy.
Owner:NANJING UNIV

Preparation and usage methods of high-temperature CO2 modified calcium-based adsorbent

The invention discloses preparation and usage methods of a high-temperature CO2 modified calcium-based adsorbent and a preparation method of a calcium-based CO2 adsorbent. Oil sand pyrolysis residues are selected as a main calcium source and is modified through the processes such as oil sand pyrolysis residue and kaolinite mixing and compounding, high-temperature calcination and ethanol solution hardening and tempering for forming to obtain a modified calcium-based CO2 adsorbent; the modified calcium-based CO2 adsorbent is large in adsorption capacity and has the good effect of removing CO2 in high-temperature flue gas of a thermal power plant and high cyclic adsorption stability, and the high-temperature CO2 adsorption removal rate after 25 times of cyclic regeneration is still kept to 65% or above. The preparation method has the advantages that the calcium source is the oil sand pyrolysis residues, and the preparation process is simple, quick and convenient to operate, low in cost and friendly to the environment and is used for adsorption and separation of high-temperature gas CO2; the CO2 in the flue gas can be directly adsorbed, and the advance influence of carbon emission on the environment and climate is reduced; the purpose of using waste to treat waste can be achieved, the methods conform to low-carbon green economy, and the effect is obviously improved compared with other calcium-based CO2 adsorbents.
Owner:CHINA UNIV OF MINING & TECH

A hydroxyapatite porous ceramic with controllable macroscopic and microscopic structures, its preparation method and application

The invention discloses a hydroxyapatite porous ceramic with controllable macroscopic and microscopic structures and its preparation method and application. The hydroxyapatite porous ceramic first obtains a three-dimensional structure through 3D direct writing molding, and then freezes it by casting The microporous structure is regulated and controlled, and the preparation method is disclosed as adding raw material A to a solvent containing a dispersant and mixing to obtain a suspension, and then adding a gelling agent to the suspension and mixing to obtain a slurry; the raw material A contains hydroxyphosphorus Limestone powder, pass the slurry through the 3D direct writing equipment, and control the slurry to be in a gel state when passing through the direct writing equipment, print and freeze to obtain a green body with a three-dimensional structure, the green body is freeze-dried, and sintered to obtain a macroscopic The hydroxyapatite porous ceramics with controllable microstructure, the invention is the first to realize the efficient combination of direct writing molding and freeze casting technology; the obtained hydroxyapatite porous ceramics can be used as bone scaffolds, which can meet the customization of different bone tissues need.
Owner:CENT SOUTH UNIV

Method for simultaneously extracting limonin and crude fat from pomelo nucleus by using solvent acetone

The present invention relates to a method for simultaneously extracting limonin and crude fat from pomelo nucleus by using a solvent acetone. The method comprises: (1) pretreatment: peeling pomelo nucleus to obtain pomelo nucleus kernel, drying the pomelo nucleus kernel, and breaking; (2) extraction: adding an acetone solvent to the broken pomelo nucleus kernel, extracting 1-7 times, and recovering the solvent to obtain a mixture; and (3) separation: adding an ethanol aqueous solution with a volume fraction of 50-95% to the mixture, stirring, carrying out static layering or centrifugation to obtain crude fat and an ethanol solution containing limonin, and recovering the solvent in the solution to obtain limonin. According to the present invention, limonin and crude fat are simultaneously extracted from the pomelo nucleus by using the one solvent acetone, wherein the recovery rates of limonin and crude fat can respectively achieve more than 95% under the preferred conditions, the product is easy to separate, and acetone is the renewable solvent, has the low boiling point, and is easily recycled; the method is easy to enlarge, can be used for large-scale production, does not requirecomplicated equipment, and is easy to operate; and the prepared limonin can be used as the drug preparation raw material, and the crude fat can be used as food and feed after being refined, and can beused as the raw material for the preparation of fine chemicals, slow release fertilizers or controlled release fertilizers.
Owner:ZHONGKAI UNIV OF AGRI & ENG

Silicon melt external refining device and method

The invention relates to a silicon melt external refining device and method and belongs to the technical field of industrial silicon purification. A ladle bottom of the device is equipped with two gas nozzles, and an included angle theta between each nozzle circle center and a ladle bottom circle center meets a relationship of 90 degrees<=theta<=180 degrees; and the distance between each nozzle circle center and the ladle bottom circle center, nozzle radius r and ladle bottom radius R meet a relationship shown in the description. Compressed air or refining gas is continuously introduced into the two gas nozzles arranged on the ladle bottom; silicon melt which is smelted from a submerged arc furnace is placed into a ladle; with the increase of silicon melt discharged from the ladle, refining agents are added and the refining gas component and flow are adjusted; external blowing and slagging refining are performed; dross on the surface of the silicon melt is skimmed; and pouring is performed on the silicon melt to obtain a high-purification industrial silicon product. The device and method provided by the invention ensure the dynamic conditions of the silicon melt in the specially-made ladle, eliminate stirring dead angles, and effectively increase qualities of the silicon product.
Owner:KUNMING UNIV OF SCI & TECH

Three-dimensional porous carbon supported bismuth sulfide/bismuth oxide composite catalyst as well as preparation method and application thereof

The invention relates to the technical field of energy chemical industry and nanometer materials, and discloses a three-dimensional porous carbon supported bismuth sulfide / bismuth oxide composite catalyst and a preparation method and application thereof. In the catalyst, bismuth sulfide and bismuth oxide are loaded on porous carbon nanosheets in the form of nanorods, and the bismuth sulfide nanorods and the bismuth oxide nanorods are staggered; and the surface of the porous nanosheet is of a porous structure, the pore diameter is 50-100 microns, the length of the bismuth sulfide or bismuth oxide nanorod is 3-10 microns, and the diameter is 80-120 nm. The preparation method comprises the following steps: roasting carrageenan to obtain porous carbon nanosheets, mixing the porous carbon nanosheets with a bismuth nitrate solution, carrying out a hydrothermal reaction, washing the precipitate with water, and conducting drying to obtain the composite catalyst. The catalyst is prepared by using biomass carrageenan as a raw material, and the catalyst is used as a cathode material for electrochemical CO2 reduction to prepare an HCOOH product. The catalyst has high selectivity and catalytic activity.
Owner:QUZHOU RES INST OF ZHEJIANG UNIV +1
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