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Conductive glass of dye-sensitized solar cell

A solar cell and conductive glass technology, applied in capacitor electrodes, circuits, photovoltaic power generation, etc., can solve the problems of long electron transmission distance, reduction of fill factor and photoelectric conversion efficiency, and lower photoelectric conversion efficiency

Inactive Publication Date: 2009-08-26
SOUTHEAST UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Dye-sensitized solar cells are a new type of amorphous silicon solar cells, which have the advantages of being cheaper and more environmentally friendly than silicon solar cells, but because the photoanode is completely exposed to the electrolyte, Ti0 2 and the photogenerated electrons on the conductive glass substrate will interact with the I in the electrolyte 3 - Recombination occurs to form a dark reaction, thereby reducing the photoelectric conversion efficiency. At the same time, as the battery area gradually increases, the volt-ampere characteristics of the battery have changed significantly. Compared with the small battery, the fill factor and photoelectric conversion efficiency are greatly reduced. Mainly The reason is the influence of the surface resistance of the conductive glass, that is, the electron transmission distance is too long, which leads to an increase in the loss of electrons during the transmission process.

Method used

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  • Conductive glass of dye-sensitized solar cell

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] A conductive glass for a dye-sensitized solar cell, comprising a conductive glass layer and a titanium dioxide barrier film layer, characterized in that a low-resistance grid electrode is arranged between the conductive glass layer and the titanium dioxide barrier film layer, and the titanium dioxide barrier film layer will The low resistance gate electrode is isolated from the external environment.

[0017] Wherein: the conductive glass layer is FTO conductive glass.

[0018] Low-resistance grid electrode: using medium-temperature silver paste as material, it is printed on the upper surface of FTO glass at one time by screen printing method, and the low-resistance grid is printed into a mesh shape. The printing method is: use JG6080 screen printing machine, 300-mesh screen, and sinter at 450°C for half an hour after printing to make a low-resistance grid. The line width of the obtained low-resistance grid is 0.5mm.

[0019] Titanium dioxide barrier layer: dense titani...

Embodiment 2

[0021] A conductive glass for a dye-sensitized solar cell, comprising a conductive glass layer and a titanium dioxide barrier film layer, characterized in that a low-resistance grid electrode is arranged between the conductive glass layer and the titanium dioxide barrier film layer, and the titanium dioxide barrier film layer will The low resistance gate electrode is isolated from the external environment.

[0022] Wherein: the conductive glass layer is FTO conductive glass.

[0023] Low-resistance grid electrode: using medium-temperature silver paste as material, it is printed on the upper surface of the bottom plate FTO glass at one time by screen printing method, and the low-resistance grid is printed into a mesh shape. The printing method is: use JG6080 screen printing machine, 300-mesh screen, and sinter at 450°C for half an hour after printing to make a low-resistance grid. The line width of the obtained low-resistance grid is 0.5mm.

[0024] Titanium dioxide barrier fi...

Embodiment 3

[0026] A conductive glass for a dye-sensitized solar cell, comprising a conductive glass layer and a titanium dioxide barrier film layer, characterized in that a low-resistance grid electrode is arranged between the conductive glass layer and the titanium dioxide barrier film layer, and the titanium dioxide barrier film layer will The low resistance gate electrode is isolated from the external environment.

[0027] Wherein: the conductive glass layer is FTO conductive glass.

[0028] Low-resistance grid electrode: using medium-temperature silver paste as material, it is printed on the upper surface of the bottom plate FTO glass at one time by screen printing method, and the low-resistance grid is printed into a mesh shape. The printing method is: use JG6080 screen printing machine, 300-mesh screen, and sinter at 450°C for half an hour after printing to make a low-resistance grid. The line width of the obtained low-resistance grid is 0.5mm.

[0029] Titanium dioxide barrier fi...

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Abstract

A conductive glass of a dye-sensitized solar cell comprises a conductive glass layer, the upper surface of the conductive glass layer is provided with a low-resistance grid electrode and a compact titanium dioxide barrier film layer sequentially from bottom to top, and the compact titanium dioxide barrier film layer isolates the low-resistance grid electrode from the external environment; the performance of the cell is proximate to the performance of a small area cell, and the low-resistance grid is unlikely to be oxidized and corroded by electrolytic solution; meanwhile the technique is simple, and the cost is low; the conductive glass is applicable to large area dye-sensitized solar cell.

Description

1. Technical field [0001] The invention belongs to the technical field of conductive glass technology, in particular to a conductive glass suitable for large-area dye-sensitized solar cells. 2. Background technology [0002] Dye-sensitized solar cells are a new type of amorphous silicon solar cells, which have the advantages of being cheaper and more environmentally friendly than silicon solar cells, but because the photoanode is completely exposed to the electrolyte, Ti0 2 and the photogenerated electrons on the conductive glass substrate will interact with the I in the electrolyte 3 - Recombination occurs to form a dark reaction, thereby reducing the photoelectric conversion efficiency. At the same time, as the battery area gradually increases, the volt-ampere characteristics of the battery have changed significantly. Compared with the small battery, the fill factor and photoelectric conversion efficiency are greatly reduced. Mainly The reason is the effect of the surfac...

Claims

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Application Information

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IPC IPC(8): H01G9/004H01G9/04H01G9/20H01M14/00H01L51/44H01L51/48C03C17/36
CPCY02E10/542Y02E10/549
Inventor 孙岳明宋铂王育乔奚俊婷蒋银花吴小娟
Owner SOUTHEAST UNIV
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