Effective component of vervain and preparation method thereof
An effective component, the technology of Verbena, is applied in the field of traditional Chinese medicine extracts for the treatment of tumor diseases, and can solve problems such as side effects and involvement of normal cells
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Embodiment 1
[0075] Embodiment 1 Verbena effective component preparation
[0076] The preparation method of the active components of Verbena of the present invention comprises the following steps: adding ethyl acetate and ethanol (1:1) after the Verbena medicinal material is pulverized, heating and refluxing for 1 hour, extracting twice, and combining the filtrates to obtain an extract; Concentrate into an extract, dissolve and load the sample with ethanol, and pass through the ODS-C18 column. First, use 30% EtOH (5BV; 1BV≈250ml) as the mobile phase to obtain eluent I, and then replace it with 95% EtOH (5BV) as the mobile phase phase, to obtain eluent II, and concentrate and dry the eluent II to obtain a sample; continue to separate the sample obtained by preparative liquid chromatography; separation conditions for preparative chromatography: the chromatographic column is a preparative column ZorbaxSB-C18; 21.2mm×250mm, The mobile phase is water A and acetonitrile B, and the gradient eluti...
Embodiment 2
[0079] The analysis of embodiment 2 Verbena effective components
[0080] The HPLC-ELSD joint analysis to the Verbena effective component of embodiment 1
[0081] Chromatographic conditions Chromatographic column Agilent Zorbax SB-C18 column (4.6mm × 150mm, 5 μm); using gradient elution, mobile phase A is 0.2% glacial acetic acid aqueous solution, mobile phase B is acetonitrile solution containing 0.2% glacial acetic acid; gradient elution The procedure is as follows: at 0 minutes, mobile phase A is 90% 0.2% glacial acetic acid aqueous solution, mobile phase B is 10% 0.2% glacial acetic acid in acetonitrile solution; at 10 minutes, mobile phase A is 50% 0.2% glacial acetic acid Aqueous solution, mobile phase B is 50% 0.2% glacial acetic acid acetonitrile solution; 30 minutes, mobile phase A is 5% 0.2% glacial acetic acid aqueous solution, mobile phase B is 95% 0.2% glacial acetic acid acetonitrile solution; 35 In minutes, the mobile phase A was 5% 0.2% glacial acetic acid in...
Embodiment 3
[0084] Embodiment 3 Verbena effective component preparation
[0085] Take the active component C08 of Verbena in Example 1, mix 0.5g with 10.5g polyethylene glycol-6000 evenly, heat and melt, move the material to the drip irrigation after the material, and drop the medicine liquid into the liquid paraffin at 6-8°C , degreasing, made 400 dropping pills.
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