Medium-to-high grade neodymium-iron-boron magnet with composite addition of gadolinium and holmium

A compound additive and high-grade technology, applied in the direction of magnetic objects, magnetic materials, inductors/transformers/magnets, etc., can solve the problem of increasing the production cost of medium and high-performance NdFeB magnets, and can not effectively reduce production costs, squareness and magnetic energy To solve the problem of low product quality, to alleviate the shortage of raw materials, shorten the production cycle, and improve the powder output speed

Inactive Publication Date: 2009-10-07
宁波同创强磁材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] With the rapid development of the industry, medium and high-grade NdFeB magnets that meet higher requirements for use are also being continuously improved, but the praseodymium neodymium (PrNd) alloys, dysprosium (Dy) and so on used in traditional medium and high-grade NdFeB magnets Rare earth raw materials are often in short supply and resources are increasingly scarce, and their prices have also skyrocketed, which increases the production cost of medium and high-performance NdFeB magnets; and the existing medium and high-grade NdFeB magnets still have poor corrosion resistance and squareness Problems such as low sum magnetic energy product and slow powder output speed in the powder making process during the preparation process
[0004] In order to reduce the cost, the Chinese application patent publication number is CN101071667A "NdFeB Rare Earth Permanent Magnet Material Containing Gadolinium and Its Manufacturing Method", which uses the addition of gadolinium (Gd) in NdFeB to partially replace the relatively expensive neodymium to reduce the cost. cost, which improves the heat resistance of the magnet, but its addition amount is only 0.05-0.2wt%, which still cannot effectively reduce the production cost

Method used

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  • Medium-to-high grade neodymium-iron-boron magnet with composite addition of gadolinium and holmium
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  • Medium-to-high grade neodymium-iron-boron magnet with composite addition of gadolinium and holmium

Examples

Experimental program
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Effect test

Embodiment 1

[0026] Ingredients: ingredients according to the following ratio (each component is weight percentage): 30% praseodymium neodymium alloy (praseodymium content is 25%), 1% boron, 0.5% gadolinium, 0.5% holmium, 0.5% aluminum, 0.1% zirconium , 0.2% titanium, 0.5% cobalt, 0.2% copper, and the balance is a small amount of unavoidable impurities in iron and materials; in order to reduce the melting point of the ingredients, boron, gadolinium, holmium, zirconium and other substances are used to ensure the weight of each of the above ingredients in the ingredients When the percentage is constant, it is added in the form of alloy; boron iron alloy, wherein the weight percentage of boron is 18.5%; gadolinium iron alloy, wherein the weight percentage of gadolinium is 74%; holmium iron alloy, wherein the weight percentage of holmium is 79.8%; zirconium Iron alloy in which zirconium is 50% by weight.

[0027] Taking the smelting of 100Kg NdFeB alloy as an example, the distribution ratio of...

Embodiment 2

[0040]Ingredients: ingredients according to the following ratio: 26.5% praseodymium neodymium alloy (wherein the weight percentage of neodymium is 75%), 1% boron, 1.5% gadolinium, 3% holmium, 0.4% aluminum, 0.1% zirconium, 0.2% titanium, 0.5% % cobalt, 0.2% copper, and the balance is iron; in order to reduce the melting point of the ingredients, boron, gadolinium, holmium, zirconium and other substances are added in the form of alloys under the condition that the above-mentioned respective weight percentages in the ingredients are kept constant; boron Iron alloys containing 18.5% by weight of boron; iron-gadolinium alloys containing 74% by weight of gadolinium; iron-holmium alloys containing 79.8% by weight of holmium; iron-zirconium alloys containing 50% by weight of zirconium.

[0041] Taking the smelting of 100Kg NdFeB alloy as an example, the distribution ratio of each component is shown in Table 2-1:

[0042] Each component distribution ratio in the embodiment one of tabl...

Embodiment 3

[0051] Ingredients: ingredients according to the following ratio: 23% praseodymium neodymium alloy (wherein the weight percentage of neodymium is 75%), 1% boron, 3.5% dysprosium, 5% holmium, 0.5% gadolinium, 0.4% aluminum, 0.1% zirconium, 0.2 %titanium, 0.2% copper, 0.5% cobalt, and the balance is iron; in order to reduce the melting point of ingredients, boron, dysprosium, gadolinium, holmium, zirconium and other materials are used under the condition that the above-mentioned respective weight percentages in the ingredients are constant. The form of alloy is added; Boron iron alloy, wherein the weight percentage of boron is 18.5%; Dysprosium iron alloy, wherein the weight percentage of dysprosium is 79.5%; Gadolinium iron alloy, wherein the weight percentage of gadolinium is 74%; Holmium iron alloy, wherein the weight percentage of holmium is 79.8%; zirconium iron alloy, wherein the weight percentage of zirconium is 50%.

[0052] Taking the smelting of 100Kg NdFeB alloy as an...

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Abstract

The invention discloses a medium-to-high grade neodymium-iron-boron magnet with composite addition of gadolinium and holmium, which is composed of the following components by weight percentage: 20 percent-33 percent of praseodymium-neodymium alloy, 0.5 percent-10 percent of gadolinium, 0.5 percent-10 percent of holmium, 0.9 percent-1.2 percent of boron, 0.1 percent-0.8 percent of aluminum, 0.1 percent-0.5 percent of copper, 0.1 percent-0.5 percent of zirconium, 0.1 percent-0.5 percent of titanium, 0 percent-10 percent of dysprosium, 0 percent-3.0 percent of cobalt and the balance of iron and a small amount of inevitable impurities in materials. The medium-to-high grade neodymium-iron-boron magnet with composite addition of gadolinium and holmium has high corrosion resistance, square degree and magnetic energy product; furthermore, the powder discharging speed of the powder production procedure in the preparation process is fast, thereby shortening the production cycle, improving the magnetic performances of the magnet and enhancing the enterprise competitiveness.

Description

technical field [0001] The invention relates to the technical field of neodymium iron boron permanent magnet materials, in particular to medium and high grade neodymium iron boron magnets compounded with gadolinium Gd holmium Ho. Background technique [0002] As an emerging industry, NdFeB permanent magnet materials have developed rapidly around the world because of their good cost performance, and are widely used in international and domestic emerging industries and pillar industries, such as computer industry, information industry, Communication industry, automobile industry, nuclear magnetic resonance imaging industry, office automation, etc. [0003] With the rapid development of the industry, medium and high-grade NdFeB magnets that meet higher requirements for use are also being continuously improved, but the praseodymium-neodymium (PrNd) alloys, dysprosium (Dy) and so on used in traditional medium-high grade NdFeB magnets Rare earth raw materials are often in short s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01F1/057H01F41/02B22F3/10
Inventor 赵红良范逢春
Owner 宁波同创强磁材料有限公司
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