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A NiZnCu ferrite material and preparing method thereof

A ferrite material and formula technology, applied in the field of magnetic materials, can solve the problems of long pre-sintering temperature and holding time, difficult to control the weighing of ingredients, increased power consumption, etc., to achieve high magnetic permeability and Q value stability, production Good batch consistency and the effect of reducing the burn-in temperature

Inactive Publication Date: 2009-10-07
贵阳晶华电子材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] (1) Some technical solutions add various auxiliary materials to the formula to improve the magnetic properties, resulting in complex formulas and harsh process conditions, making it difficult to realize industrial production;
[0005] (2) Some schemes introduce a variety of auxiliary materials, and the weighing of ingredients in industrial production is difficult to control, which will cause obvious differences in each batch of materials;
[0006] (3) Due to the introduction of a variety of auxiliary materials, it is not easy to mix the powder raw materials uniformly in industrial production, resulting in unstable performance of the powder, which affects the stability and reliability of the devices made by ferrite powder users
[0007] (4) For NiZnCu ferrite, the smaller the particle size distribution of the powder, the better the performance, so the sol-gel method is used to prepare high-performance NiZnCu ferrite, the purpose is to prepare nano-scale ferrite raw powder for pre-production Burning; while the sol-gel method has high cost and complicated process control, which is not easy for industrialized mass production
[0008] (5) If ball milling is used, only increase the ball milling time to grind fine powder, which will increase power consumption and cost
The ball milling medium may also bring in impurities, which will make the performance of the powder worse.
[0009] (6) Some schemes have a higher pre-firing temperature, and the temperature range is not wide, and the pre-firing temperature holding time is also longer, which is not conducive to increasing production and reducing costs

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Embodiment 1: by molecular formula (Ni 0.15 Zn 0.65 Cu 0.2 O)Fe 1.99 o 3 Calculated as the weighing of the oxide containing each metal ion, produce 7 batches, each batch of 100kg, each oxide powder gross weight is 99.5kg, add the organic additive stearic acid that weight is 0.1kg, use The average particle size is 1 μm after ball milling and mixing in a horizontal ball mill for 6 hours. The pre-calcination temperatures for the production of 7 batches are 650°C, 700°C, 750°C, 800°C, 850°C, 900°C, and 950°C, and the highest temperature is kept for 2 hours. After burning, add 0.4kg of organic additive stearic acid, pulverize with a horizontal ball mill for 6 hours to an average particle size of 1.4 μm, and dry to obtain finished powder. Add 1% PVA and 2% Bi to the finished powder 2 o 3 After granulation, it is pressed into a magnetic ring for testing. The green body of the magnetic ring has an outer diameter of 42 mm, an inner diameter of 30 mm, and a thickness of 4 m...

Embodiment 2

[0027] Embodiment 2: by molecular formula (Ni 0.15 Zn 0.65 Cu 0.2 O)Fe 1.99 o 3 Calculated as the weighing of the oxide containing each metal ion, 7 batches were produced, each batch was 100kg, the total weight of each oxide powder was 99.5kg, the auxiliary material was CoO with a weight of 0.1kg and the added weight was 0.1kg Stearic acid, an organic additive, was mixed with a horizontal ball mill for 6 hours and the average particle size was 1 μm. The pre-calcination temperatures of the 7 batches were 650°C, 700°C, 750°C, 800°C, 850°C, 900°C, and 950°C. ℃, heat preservation at the highest temperature for 2 hours, add 0.3 kg of organic additive stearic acid after pre-calcination, ball mill for 6 hours with a horizontal ball mill to an average particle size of 1.4 μm, and dry to obtain the finished powder. Add 1% PVA and 3% Bi to the finished powder 2 o 3 After granulation, it is pressed into a magnetic ring for testing. The green body of the magnetic ring has an outer d...

Embodiment 3

[0029] Embodiment 3: by molecular formula (Ni 0.4 Zn 0.5 Cu 0.2 O)Fe 1.97 o 3Calculated as the weight weighing of oxides containing each metal ion, 7 batches were produced, each batch was 100kg, the total weight of each oxide powder was 94kg, and the auxiliary materials were CoO and MnO with a total weight of 4kg 2 、Al 2 o 3 , SiO 2 and the organic additives stearic acid and sodium oleate with a total weight of 1 kg, mixed with a horizontal ball mill for 4 hours, the average particle size is 1 μm, and the pre-calcination temperatures of 8 batches are 600 ° C, 650 ° C, 700 ° C, and 750 ° C respectively , 800°C, 850°C, 900°C, 950°C, keep the temperature for 1.5h at the highest temperature, add organic additives stearic acid and sodium oleate with a total weight of 1kg after pre-calcination, and use a horizontal ball mill to pulverize for 6h to an average particle size of 1.4μm , and dried to obtain finished powder. Add 1% PVA and 3% Bi to the finished powder 2 o 3 Afte...

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PUM

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Abstract

The invention discloses a NiZnCu ferrite material, which is a ferrite material made by adding organic additives and inorganic oxide additives in the base raw material prescription of Fe[2] O [3], NiO, or Ni [2] O [3], CuO, ZnO. The reparing method includes: adding the raw material and the organic additives into the inorganic oxide additives, mixing with water, drying, sifting; presintering; joining the organic additives again, adding water for ball milling, mixing; drying and then sifting, to obtain the inventive NiZnCu ferrite material. Granulation, molding and sintering is required during manufacturing magnet ring. Compared with the existing technology, this invention adds organic additives twice to make the prescription and process simpler, reduce the cost and presintering temperature, improve the sintering activity of the presintering material so that the sintering temperature scope becomes wider, and obtain a NiZnCu ferrite material with a good consistency of production batches, suitability for industrial production, high magnetic permeability and Q value stability.

Description

technical field [0001] The invention relates to a magnetic material, and also to a production method of the magnetic material, in particular to a NiZnCu ferrite material and a preparation method thereof. Background technique [0002] In recent years, the rapid development of electronic equipment in the direction of miniaturization, networking and multimedia has opened up many new uses for ferrite ceramic materials. Among them, one of the chip components developed rapidly to adapt to the surface mount technology - the multilayer chip inductor uses soft ferrite as the magnetic medium. Soft ferrite materials can be divided into NiZn, MnZn, NiZnCu and other ferrites according to their composition. Soft ferrite material has high magnetic permeability, high resistivity, low loss and good wear resistance. Among them, the NiZnCu ferrite has the advantages of good density, which can greatly reduce the size of the device and realize the miniaturization of the ferrite device, so it h...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01F1/34H01F1/37C04B35/26C04B35/64B22F3/10
Inventor 王荣辉
Owner 贵阳晶华电子材料有限公司
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