Method for preparing flyash-supporting nanometer titanic oxide composite photochemical catalyst material
A technology of nano-titanium dioxide and composite materials, applied in the field of preparation of fly ash-loaded nano-titanium dioxide composite materials, to achieve the effect of easy source, good synergy, and solution to storage and processing problems
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Embodiment 1
[0014] First dissolve diethylamine in deionized water to form a homogeneous solution, then add tetramethylammonium hydroxide, and obtain a homogeneous stable solution A under stirring; deionized water is 50ml, diethylamine and tetramethylammonium hydroxide The mass concentrations of deionized water are 3% and 0.5%, respectively.
[0015] Mix titanyl sulfate powder with deionized water and stir to form a white slurry liquid, deionized water is 100ml, TiO 2 The mass content of deionized water is 10%. Then add 10g of fly ash powder to make the fly ash fully contact with the slurry liquid to obtain the mixture B.
[0016] Then A and B were mixed, aged for 8h, and then washed, vacuum-dried and heat-treated at 500°C to obtain a fly ash-loaded nano-titanium dioxide composite. The composite material was subjected to a photocatalytic degradation experiment according to the above method, and it was found that the degradation rate of butachlor could reach 95%.
Embodiment 2
[0018] First dissolve diethylamine in deionized water to form a homogeneous solution, then add tetramethylammonium hydroxide, and obtain a homogeneous stable solution A under stirring; deionized water is 50ml, diethylamine and tetramethylammonium hydroxide The mass concentrations of deionized water are 2.2% and 0.75%, respectively.
[0019] Mix titanyl sulfate powder with deionized water and stir to form a white slurry liquid, deionized water is 100ml, TiO 2 The mass content of deionized water is 15%. Then add 15g of fly ash powder to make the fly ash fully contact with the slurry liquid to obtain the mixture B.
[0020] Then A and B were mixed, aged for 8h, and then washed, vacuum-dried and heat-treated at 500°C to obtain a fly ash-loaded nano-titanium dioxide composite. Its degradation rate of butachlor can reach 90%.
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