Nitrogen-doped directionally solidified casting monocrystalline silicon and preparation method thereof
A technology of directional solidification and monocrystalline silicon, which is applied in the field of semiconductors, can solve the problems of reducing the manufacturing cost of solar cells and low mechanical strength, and achieve the effects of high mechanical strength, cost reduction and manufacturing cost reduction
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Embodiment 1
[0023] First spread the dislocation-free monocrystalline silicon block with a thickness of 20mm on the bottom of the crucible, then place 240kg of polysilicon in the crucible, and add 20mg of dopant boron to realize furnace loading. Vacuum the furnace chamber and feed nitrogen gas, the purity of nitrogen gas is 99.999%, the pressure of nitrogen gas is 10Torr, and the flow rate is 100L / min. The 5mm thick monocrystalline silicon block is heated and kept at a temperature above 1430°C, so that the 5mm thick monocrystalline silicon block close to the polysilicon, all the polysilicon and boron are melted into liquid, forming a silicon melt. Then pour cooling water into the bottom of the crucible, and raise the heat preservation cover in the furnace at a speed of 1mm / min, so that the silicon melt gradually solidifies directionally from the bottom up, and passes through the unmelted 15mm thick single crystal silicon laid on the lower part of the bottom of the crucible The block is use...
Embodiment 2
[0028]First spread the dislocation-free monocrystalline silicon block with a thickness of 10mm to the bottom of the crucible, then place 240kg of polysilicon in the crucible, and add 20mg of dopant boron to realize furnace loading. Vacuum the furnace chamber and feed nitrogen gas, the purity of nitrogen gas is 99.9999%, the pressure of nitrogen gas is 10Torr, and the flow rate is 10L / min. The 3mm thick single crystal silicon block is heated and kept at a temperature above 1450°C, so that the 3mm thick single crystal silicon block close to the polysilicon, all the polysilicon and boron are melted into liquid, forming a silicon melt. Then blow cooling helium into the bottom of the crucible, and lift the insulation cover at a speed of 3mm / min, so that the silicon melt gradually solidifies from the bottom upwards, and passes through the unmelted 7mm thick monocrystalline silicon block laid on the lower part of the bottom of the crucible Nitrogen-doped single crystal silicon is for...
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