Heat stabilizing lubricant for polyvinyl chloride 105D cable material and preparation method thereof

A technology of polyvinyl chloride and heat stabilization, applied in the field of composition and preparation of heat stabilizers, can solve the problems of difficult control of product internal quality, low heat stability efficiency, harmful to human health, etc., and achieve dispersibility and compatibility Excellent, good production stability, low labor intensity

Inactive Publication Date: 2010-06-30
蒋马小
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the traditional tri-salt and di-salt monomer heat stabilizers are powdery, and there are disadvantages such as backward production technology, large energy consumption, many operating procedures during use, repeated weighing or grinding before use; in PVC resin Poor dispersibility, undispersed white spots, difficult to control the internal quality of the product, large dosage, low thermal stability efficiency, general processability; serious toxic lead dust flying in the process of production and use, not only very harmful

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0049] (1) Take each component according to the following process proportioning:

[0050] Stearic acid 85.3Kg Salicylic acid 10.31Kg Diethylene glycol 13.91Kg

[0051] Huang Dan 496.5Kg Paraffin 59Kg Glacial acetic acid 1.9Kg

[0052] Cyanuric acid 68Kg Bisphenol A 17Kg.

[0053] (2) Put 13.04Kg of stearic acid, 1.08Kg of salicylic acid, and 6.52Kg of diethylene glycol into the reactor, start stirring and heating, and when the temperature in the reactor rises to 150°C, condense and collect and escape from the reactor The water vapor is used to control the temperature rise rate in the reactor to 10°C / H. When the reaction time is about 6 hours, when the temperature in the reactor is 190°C and no water vapor escapes, stop heating, cool the material below 100°C, and filter out the material as auxiliary agent 1.

[0054] (3) Put 0.77Kg of stearic acid, the remaining salicylic acid and the remaining diethylene glycol into the reactor, and prepare auxiliary agent 2 according to the ...

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PUM

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Abstract

The invention discloses a heat stabilizing lubricant for a polyvinyl chloride 105D cable material and a preparation method thereof. The heat stabilizing lubricant is prepared from the following raw materials in percentage by weight: 5.67 to 14.18 percent of stearic acid, 0.69 to 1.71 percent of salicylic acid, 0.93 to 2.31 percent of diglycol, 33.02 to 82.54 percent of yellow lead, 3.93 to 9.81 percent of paraffin, 0.13 to 0.3 percent of glacial acetic acid, 4.52 to 11.30 percent of cyanuric acid, and 1.13 to 2.83 percent of bisphenol A. The method for preparing the heat stabilizing lubricant comprises the following steps: preparing an aid 1 from 7.65 to 19.11 percent of stearic acid, 5.24 to 13.1 percent of salicylic acid and 23.44 to 58.59 percent of diglycol; preparing an aid 2 from 0.45 to 1.13 percent of stearic acid, the rest of salicylic acid, and the rest of diglycol; preparing an intermediate from 7.2 to 18 percent of yellow lead, the rest of stearic acid, and the paraffin; preparing a synthetic material from the rest of yellow lead, the glacial acetic acid, and the cyanuric acid; preparing a composite material from 15.35 to 38.36 percent of intermediate, 25 to 62.5 percent of aid 1, and the synthetic material; and reacting the composite material, the rest of intermediate, the rest of aid 1, the aid 2 and the bisphenol A in a kneading machine, and performing extrusion molding.

Description

technical field [0001] The invention relates to a thermally stable lubricant for polyvinyl chloride 105D cable materials, including the composition and preparation method of the thermal stabilizer. Background technique [0002] Polyvinyl chloride is also called PVC. Its molecules are relatively polar molecules. Due to the large intermolecular force, its softening temperature and melting temperature are high, and its glass transition temperature is high. Therefore, it generally needs to be heated to above 150-160°C. In order to make it plasticized, the processing temperature is usually between 160 and 210 °C. However, PVC resin is extremely unstable to heat. It is easy to degrade and dehydrochloride at the processing temperature. This reaction causes PVC to produce polyene sequences of colored conjugated double bonds, resulting in discoloration, brittleness and corrosion of equipment. In severe cases, it will make processing impossible. [0003] In order to inhibit the dehy...

Claims

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Application Information

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IPC IPC(8): C08K11/00C08L27/06
Inventor 蒋马小
Owner 蒋马小
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