Production process of damping underwater acoustic transmission plastic functional master batch

A technology of functional masterbatch and production process, which is applied in the field of production process of damping underwater sound-transmitting plastic functional masterbatch, can solve the problem that sound transmission, pressure resistance, vibration reduction, weather resistance, corrosion resistance are difficult to achieve balance, and polyurethane resistance is difficult to achieve. Poor aging performance, poor rubber aging resistance and other problems, to achieve the effect of improving processing performance, reducing extrusion viscosity, and good compatibility

Inactive Publication Date: 2020-08-11
合肥凯大新型材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In order to meet the ever-increasing requirements of sonar technology, people have carried out a lot of research and development in the aspects of sound transmission theory and material structure design. The shape design of the plastic structure achieves the effect of sound transmission, such as musical instrument audio, etc., but the existing rubber or thermoplastic polyurethane as the underwater sound transmission material has poor aging resistance, water resistance, and often fails to meet the requirements in terms of strength, such as CN201310598615.4 A high-performance underwater acoustic sound-permeable rubber material and its preparation method discloses "the preparation of an underwater acoustic sound-permeable rubber material with high sound permeability and temperature stability, high water tightness and excellent physical and mechanical properties
", but the aging resistance of rubber is poor. For example, CN201310598615.4 discloses a high-performance hydroacoustic sound-permeable rubber material and its preparation method "preparing a rubber material with high sound permeability and temperature stability, high water tightness and excellent physical and mechanical properties. Hydroacoustic sound-permeable rubber material
", but the aging resistance of rubber is poor. CN201910195562.9 A fluorosilane-modified polyether-type polyurethane water sound-transmitting material and its preparation method has excellent water resistance, cold resistance and sound transmission performance, but the resistance of polyurethane The aging performance is poor, and the sources of sound-transmitting polymers are greatly restricted and restricted. At present, there are no products and corresponding technologies of water-acoustic sound-permeable plastics with good performance on the market. The existing ones are represented by rubber or thermoplastic polyurethane. Sound-transmitting materials are also difficult to achieve a balance in sound transmission, pressure resistance, vibration reduction, weather resistance, corrosion resistance, etc., and the preparation process is complicated, the cost is high, and the use of materials is limited. At present, most of them are polyurethane elastic and rubber, which cannot It is widely applicable to the existing plastic materials with a huge amount of application. In order to solve the above problems, on the basis of the urgent need to develop underwater sound-permeable plastics with balanced performance, it is urgent to develop a damping underwater sound-permeable plastic functional matrix. Granule production process to meet existing technical needs and performance requirements

Method used

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  • Production process of damping underwater acoustic transmission plastic functional master batch
  • Production process of damping underwater acoustic transmission plastic functional master batch
  • Production process of damping underwater acoustic transmission plastic functional master batch

Examples

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Embodiment 1

[0022] The first step is to pulverize the raw material SEBS on a pulverizer, then wash it with ethanol for 4 hours, and then dry it in an oven at 60°C. The irradiation conditions will treat the processed SEBS powder at room temperature in an air atmosphere. 60CO-γ-ray irradiation, the irradiation dose is: 60kGy, the irradiated powder is placed in a low-temperature box, and stored at −24°C for 12 hours to obtain the irradiated powder, and 100 parts by weight are weighed. The powder is placed in a reaction kettle containing 100 parts of methacrylic acid aqueous solution with a mass fraction of 6%, and 0.6 parts of 4mmol / L copper chloride aqueous solution is added as a polymerization inhibitor, sealed with nitrogen gas for 15 minutes, and stirred in a constant temperature stirring water bath at 60°C Carry out the grafting reaction for 20 minutes, filter the material, extract it with a mixed solution of ethanol and water for 48 hours, and then dry it in a vacuum oven at 60°C to a c...

Embodiment 2

[0024] The first step is to pulverize the raw material SEBS on a pulverizer, then wash it with ethanol for 4 hours, and then dry it in an oven at 60°C. The irradiation conditions will treat the processed SEBS powder at room temperature in an air atmosphere. 60 CO-γ-ray irradiation, the irradiation dose is: 60kGy, put the irradiated powder into a low-temperature box, and store it at −24°C for 10 hours to obtain the irradiated powder. Weigh 100 parts of the irradiated powder by weight. The powder is placed in a reaction kettle containing 100 parts of methacrylic acid aqueous solution with a mass fraction of 6%, and 0.6 parts of 4mmol / L copper chloride aqueous solution is added as a polymerization inhibitor, sealed with nitrogen gas for 10 minutes, and stirred in a constant temperature stirring water bath at 50°C Carry out the grafting reaction for 20 minutes, filter the material, extract it with a mixed solution of ethanol and water for 24 hours, and then dry it in a vacuum oven ...

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Abstract

The invention belongs to the field of high polymer materials, and relates to a production process of a damping underwater acoustic transmission plastic functional master batch. The production processis simple; raw material sources are wide; blending and modifying can be carried out with polyolefin plastic; the underwater acoustic transmission plastic can be prepared; when sound waves pass throughthe modified underwater acoustic transmission plastic, the sound waves are transmitted, just like a force acts on the underwater acoustic transmission plastic, the underwater acoustic transmission plastic generates elastic deformation and plastic deformation, after modification of the functional master batch, plastic deformation enables sound energy decline to be weakened, attenuation of sound energy is reduced along with increase of elasticity, hysteresis loss of the functional master batch can be reduced, the chain rotation degree of a molecular chain of a blend is increased, flexibility isenhanced, then attenuation of sound is weakened, and the effect of acoustic transmission of underwater sound is achieved.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, in particular to a production process of a sound-permeable plastic functional masterbatch for damping underwater sound. Background technique [0002] Functional masterbatch refers to the concentrate of various plastic additives. Adding additives directly in plastic processing is not easy to disperse, and the use efficiency is not high. Therefore, functional masterbatches are added in the form of color masterbatches, flame retardant masterbatches, etc. In the military, with the continuous development of underwater stealth technology, the sound wave scattering of underwater weapons and equipment is getting smaller and smaller, making it more and more difficult to be found and located. The long-distance and high-precision priority to find the enemy is the key to defeating the enemy with underwater weapons and equipment, which puts forward higher requirements for underwater detection techno...

Claims

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Application Information

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IPC IPC(8): C08L51/00C08L33/08C08L33/10C08L51/08C08L23/06C08K5/14C08L23/12C08F287/00C08F220/06C08F283/06C08F222/38
CPCC08F283/06C08F287/00C08L23/12C08L51/006C08L2205/025C08L2205/035C08L2207/066C08L33/08C08L33/10C08L51/08C08L23/06C08K5/14C08F220/06C08F222/385
Inventor 张海涛
Owner 合肥凯大新型材料科技有限公司
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