Method for simultaneously measuring arsenic and stibium in Chinese medicinal manyprickle acathopanax root
A technology of Acanthopanax and traditional Chinese medicine, which is applied in the preparation of test samples, fluorescence/phosphorescence, material excitation analysis, etc., can solve the problems of unreported research on heavy metal content, and achieve international competitiveness, less pollution, and low prices Effect
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Embodiment 1
[0018] The method for simultaneously determining arsenic and antimony in the traditional Chinese medicine Acanthopanax senticosus, sample processing: Accurately weigh the samples to be tested of Acanthopanax senticosus plants or series products of Acanthopanax senticosus, place them in the inner tank of microwave digestion, add digestion: liquid nitric acid and over The mixed solution of hydrogen oxide, with a volume ratio of 5:1, is put into the outer tank, and the outer tank cover is tightened, and placed in the microwave digestion system. According to the set optimal working conditions, until the digestion is complete, cool down, dilute to a 25mL stoppered colorimetric tube pre-added with 2.0mL hydrochloric acid and 2.0mL thiourea, and measure by atomic fluorescence method.
[0019] A method for simultaneously determining arsenic and antimony in the traditional Chinese medicine Acanthopanax senticosus, the determination of the microwave digestion procedure:
[0020] Digesti...
Embodiment 2
[0023] A method for simultaneously measuring arsenic and antimony in the Chinese medicine Acanthopanax senticosus described in Example 1, the drawing of the arsenic and antimony working curve: first dilute the arsenic standard solution GBW(E)080390 10 times, pipette 1.0mL of the diluted arsenic Put the standard solution and 1.0mL antimony standard solution GBW(E)080545 in a 100mL volumetric flask, add 10mL hydrogen chloride HCl in advance, and use ultrapure water to make up the volume, which is 10μg?mL -1 Arsenic and antimony mixed standard stock solution. Take this solution and dilute to 0.1μg?mL -1 , made of mixed standard solution of arsenic and antimony. Draw 0.0, 0.5, 1.0, 2.0, 4.0, 5.0mL of arsenic-antimony mixed standard solution respectively, and set the volume to a 50mL colorimetric tube. Add 5.0mL hydrogen chloride HCl and 10.0mL thiourea to the colorimetric tube in advance to obtain a concentration of 0.0 , 1.0, 2.0, 4.0, 8.0, 10.0 μg?L -1 Mixed standard solution...
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