The invention relates to a multifunctional environment simulation test chamber for an on-line detecting textile material total organic volatile, comprising a main chamber body, an ultraviolet lamp, an ultrasonic humidifier, a VOC (Volatile Organic Compounds) sensor, an electric heater, a refrigerating compressor and a circulating fan. The main chamber body is provided with a sample injecting switch at the top end, an airtight door at the front surface, a cleaning drainage valve and an exhaust sampling electromagnetic valve at the bottom and the ultraviolet lamp inside; the ultrasonic humidifier is arranged on one side of the airtight door, the VOC sensor is arranged on the side surface of the main chamber body, the electric heater is connected with the main chamber body by a circulating air pipe, the refrigerating compressor is arranged on the lower part of the main chamber body, and the circulating fan is arranged below the electric heater. The invention has good stability and low cost, is easy to maintain, can detect the air for a long time, and is a fabric photocatalytic activity on-line VOC detection system comprising a special sensor, a basic evaluator, a data program, an on-line detection meter and the like by utilizing an on-line detection method.