873 results about "Microwave digestion" patented technology

Disclosed herein are methods of modifying a reaction rate on a semiconductor substrate in a processing chamber which utilize a phased-array of microwave antennas. The methods may include energizing a plasma in a processing chamber, emitting a beam of microwave radiation from a phased-array of microwave antennas, and directing the beam into the plasma so as to cause a change in a reaction rate on the surface of a semiconductor substrate inside the processing chamber. Also disclosed herein are particular embodiments of phased-arrays of microwave antennas, as well as semiconductor processing apparatuses which include a phased-array of microwave antennas configured to emit a beam of microwave radiation into a processing chamber.

This process occurs in the presence of activated carbon or its equivalent by decomposing adsorbed hazardous materials, such as hydrazine and microorganisms, on the carbon surface by radiofrequency energy in the microwave range at near ambient conditions of temperature and pressure. Further microwave oxidation to nonhazardous gases occurs in the presence of a microwaves enhanced oxidation catalyst.

The invention discloses an analysis and detection method for impurity elements such as aluminum, calcium, ion, molybdenum, niobium, titanium, tungsten and the like in chromium carbide. The method comprises adding a chromium carbide sample into a dissolving cup, adding hydrofluoric acid, sulphuric acid and nitric acid sequentially, stirring, charging into a sealed high-pressure jar; putting the sealed high-pressure jar into a microwave extinguishing instrument for two times of microwave extinguishment; taking the high-pressure jar out of the microwave extinguishing instrument for cooling, transferring the dissolved chromium carbide liquid sample into a volumeric flask, diluting to a predetermined index, stirring; preparing a chromium substrate matched mixed standard solution series of aluminum, calcium, iron, molybdenum, niobium, titanium and tungsten; measuring element emission power of aluminum, calcium, iron, molybdenum, niobium, titanium, tungsten or the like in a blank liquid sample, a chromium carbide liquid sample and the prepared series mixed standard solution by an inductively coupled plasma atomic emission spectrometer in the same time, obtaining the analysis result by checking a standard working curve or by linear equation calculation. The invention adopts two times of microwave extinguishment using the mixed acid, solves the problem of hardness in chromium carbide decomposition, having a measurement range from 0.010% to 1.00%, which is high in accuracy, and good in precision.

The invention provides a composite energy field heating device. The composite energy field heating device comprises a microwave heating device and a hot-pressing tank, wherein the microwave heating device comprises a microwave generator, a microwave cavity and a microwave local shielding part; the microwave generator is used for sending microwaves into the microwave cavity; a wave absorbing material is arranged in the microwave cavity; the microwave local shielding part is positioned in the microwave cavity, and is used for covering the outer surface of the wave absorbing material; the microwave local shielding part is composed of a shielding microwave region and a transmission microwave region; the transmission microwave region comprises one or more seams, so that microwaves in the microwave cavity can enter the wave absorbing material through the seams for being absorbed; the microwave cavity is integrally arranged in the hot-pressing tank; a ventilating window or a ventilating wall which consists of one or more metal honeycomb plates is arranged on the microwave cavity; and the ventilating window or the ventilating wall can be used for enabling smooth air flow inside and outside the microwave cavity in the hot-pressing tank while shielding the microwaves. The composite energy field heating device can truly realize consistent temperature on all parts in the wave absorbing material, so that high-quality cured products are provided for the aviation and aerospace fields.

A microwave heating apparatus includes a microwave generation part 10 using a semiconductor element, and first and second heating chambers 100a, 100b to each of which a microwave generated in the microwave generation part is fed. A reflected microwave returned from at least one of the first and second heating chambers 100a, 100b to the microwave generation part is transmitted to the other heating chamber by a circulation type non-reciprocal circuit 118, so that generated power of the microwave generation part is substantially completely consumed upon heating of an article to be heated.

The invention provides a SiO2 nanoscale porous material with aerogel property prepared by microwave reaction and a preparation method thereof; the nanoscale porous material comprises silicon dioxide skeletons (1) and bubble-shaped nanoscale pores (2), wherein the foam-shaped nanoscale pores (2) are arranged among the silicon dioxide skeletons (1). The preparation method comprises four steps, namely preparation of silicon dioxide sol, preparation of wet gel, aging of mother solution and drying at normal pressure and the preparation of silicon dioxide sol comprises the following steps: adopting organosiloxane, organic solvent, water and acid catalysis as raw materials; mixing each components in a defined ratio in a container while adopting microwave radiation to perform hydrolytic polycondensation reaction or adopting microwave radiation to perform hydrolytic polycondensation reaction after mixing the components. Owning to adopting microwave radiation technology, a lot of bubbles are generated in silicon dioxide sol, a large quantity of nanoscale bubble-shaped pores are formed on the silicon dioxide substrate, and meanwhile silicon dioxide space skeletons are retained so that silicon dioxide porous material with extremely large specific area and higher intensity can be obtained. In addition, because carbon dioxide supercritical drying process is not needed, the production cost is greatly reduced.

The invention provides a digestion method and a detection method for iron ore. The digestion method comprises the following steps: adding an iron ore sample in which hydrofluoric acid and nitric acid (or sulfuric acid) are mixed, then carrying out high-pressure closed microwave digestion to obtain a suspension; and heating the suspension in an unclosed system to secure the second digestion with residual nitric acid (or residual sulfuric acid) and added perchloric acid and hydrogen peroxide, thereby obtaining a solution which is digested fully. The detection method comprises the following steps: preparing a solution with the digested solution, and detecting the prepared solution by inductive coupling plasma atomic emission spectrometry, thereby obtaining content of each element of the iron ore sample. The invention has the advantages of high efficiency, high accuracy, and simple and fast process. Especially, the invention realizes accurate detection of key element content in iron ore, such as As, Pb, Zn, W, Sn, Ca, Mg, Cu, Co, Ni, Cr and Mo which affect product quality of iron and steel smelting and vanadium/titanium extraction.

The invention provides an online automatic monitoring system of total nitrogen and total phosphorus in seawater and a monitoring method thereof. The system comprises an automatic seawater liquid feedcontroller, an ultraviolet microwave digestor, a total nitrogen measuring flow passage, a total phosphorus measuring flow passage and a spectrophotometer, wherein the automatic seawater liquid feed controller is connected with the ultraviolet microwave digestor by a liquid feed pipeline; digested sample flows into an electronic cooler from a liquor drainage pipeline of the ultraviolet microwave digestor to be cooled and respectively enters into the total nitrogen measuring flow passage and the total phosphorus measuring flow passage; the total nitrogen measuring flow passage comprises a nitrate ion reducing device, a sample reaction pipeline is connected with the spectrophotometer, and the front end of the sample reaction pipeline is provided with a nitrite color reagent injecting valve; and the total phosphorus measuring flow passage comprises the structure that the sample reaction pipeline is connected with the spectrophotometer, and the front end of the sample reaction pipeline is provided with an orthophosphate color reagent injecting valve. The invention can complete work procedures such as automatically sampling seawater, digesting, reducing, washing, measuring, and the like,at one time.

The invention discloses a method that can simultaneously analyze various elements, aims at solving the defects that currently the analysis of various elements cannot be finished at one time, and consequently the analysis time is long and the reagent usage is large, and discloses a method that can simultaneously measure the elements of silicon, aluminum, calcium and barium and comprises the following steps: a test sample is preprocessed through the acid dissolution method, microwave-digested, naturally cooled, and then placed into a volumetric flask with scales, diluted and shaken until well distributed, a solution with a standard working curve is prepared, an atomic emission spectrograph of inductance coupled plasmas is started and led to reach the measurement requirement, a plasma torch is lighted, the relative standard deviation of the plasma torch is led to be less than 5 percent, wavelength of each element is chosen, the working curves are plotted, and the content of each element is computed. The method combines the microwave digesting sample dissolution technique with the atomic emission spectrograph of inductance coupled plasmas, can simultaneously analyze nine elements including silicon, etc., is accurate and quick, has greatly reduced reagent usage, and reduces the environmental pollution that is caused by chemical reagents.

A microwave ablation system incorporates a microwave thermometer that couples to a microwave transmission network connecting a microwave generator to a microwave applicator to measure noise temperature. The noise temperature is processed to separate out components the noise temperature including the noise temperature of the tissue being treated and the noise temperature of the microwave transmission network. The noise temperature may be measured by a radiometer while the microwave generator is generating the microwave signal or during a period when the microwave signal is turned off. The microwave ablation system may be configured as a modular system having one or more thermometry network modules that are connectable between a microwave applicator and a microwave generator. Alternatively, the modular system includes a microwave generator, a microwave applicator, and a microwave cable that incorporate a microwave thermometry network module.

The invention relates to a zinc ferrite-loaded carbon nano tube catalyst prepared by a microwave-hydrothermal method and an application of the catalyst in degrading organic pollutants in water. A preparation method of the catalyst comprises the steps of dissolving FeCl3 and ZnCl2 into deionized water, adding a pretreated carbon nano tube into a solution, performing ultrasonic treatment for 1.0-3.0min, adjusting the pH to 7.5-11.5, stirring and transferring into a polytetrafluoroethylene reaction tank, putting the reaction tank into a microwave digester, performing hydrothermal reaction under the pressure of 0.3-1.5MPa for 10-40min, washing a product obtained by the reaction with the deionized water until the product is neutral, filtering the product, drying the product under the constant temperature of 70 DEG C, grinding the product, and screening the product with a screen of 100 meshes to obtain the zinc ferrite-loaded carbon nano tube catalyst. The catalyst provided by the invention is combined with microwaves to degrade the organic pollutants in water; the catalyst preparation speed is high, the degrading efficiency is high, the rate is high, and the cost is low; no intermediate product or secondary pollution is generated.

The invention relates to a method for detecting chromium, nickel, arsenic, selenium, cadmium and lead in cigarette side-stream smoke. The method is characterized in that a fishtail cover is connected with a quartz fiber filter disc in series to collect particulate matters in the cigarette side-stream smoke, a triple-tandem nitrite acid solution is used for collecting gas phase matters in the side-stream smoke, a microwave digestion method is used for digesting samples, and the contents of chromium, nickel, arsenic, selenium, cadmium and lead in the particulate matter and gas phase matter samples are detected through ICP-MS (Inductively Coupled Plasma Mass Spectrometry). The method overcomes the defects of sample collecting and processing methods and detecting techniques in the prior art and fills the blank of domestic detecting techniques for heavy metal in the side-stream smoke. The fishtail cover is connected with the purified quartz fiber filter disc in series to collect the particulate matters in the side-stream smoke, so that the background interference is effectively reduced. A three-stage absorption bottle collects the gas phase matters in the side-stream smoke, so that the gas phase matters can be completely collected. The microwave digestion method treats the samples, so that the digestion effect is good, and the element loss is few. The ICP-MS is adopted for determination, so that the method is fast and accurate, high in sensitivity, good in repeatability and high in recovery rate.

The invention discloses a method for simultaneous measurement of 17 trace elements in reconstituted tobacco by using inductively coupled plasma mass spectrometry. According to the invention, microwave digestion and inductively coupled plasma mass spectrometry are combined together to measure 17 trace elements in reconstituted tobacco; a reconstituted tobacco sample is subjected to microwave digestion, and then ICP-MS measurement is quantitatively carried out through combination of a standard mode, collision/reaction cell technology and an internal standard method. Measurement results show that: 17 target elements have good linearity, a correlation coefficient r is no less than 0.9995, a detection limit is 0.001 to 0.065 mu g/L, an added standard recovery rate is 79.31 to 123.07%, and relative standard deviation is 1.15 to 6.38%. The method provided by the invention has the advantages of simple operation, short analysis time, stability, accuracy, etc. and can be used for analysis and test of large-batch reconstituted tobacco samples in the tobacco industry.

A method for detecting cadmium content in cigarette used tipping paper is characterized in that the method can quickly and accurately detect the chromium content in the cigarette used tipping paper by the following steps: adopting mixed acid to carry out microwave digestion for a sample, removing the acid and fixing volume, conducting detection with a graphite furnace atomic absorption spectrophotometer, etc. The method overcomes the shortcoming of the prior art in processing the sample. Compared with the traditional electric heating plate digestion manner, the microwave digestion manner can reduce the usage of samples and strong acid, improve digestion ability, cause less loss to elements to be detected in the sample and small damage to an operator, and facilitate operation. The digestion system of compound acid is completely applicable to the special material of the cigarette used tipping paper. The acid removing process is quick and easy, and a matrix modifier is adopted to eliminate interference. After being detected by optimal heating up programs, ashing temperature and atomization temperature related to atomic absorption spectrometry, the special material of the cigarette used tipping paper is recovered with high rate, and detected with accurate result. The working efficiency and the economic benefits are significantly improved.

The invention discloses a solid-phase dispersed microwave extraction method of residual sample base and solid-phase dispersed microwave extraction filler and extraction solvent, which comprises the following steps: 1) mixing the detected sample and solid-phase dispersed microwave extraction filler; grinding evenly; 2) adding the extraction solvent in the microwave generator to proceed the microwave radiation; 3) removing the solid impurity to obtain the extract with residue; removing the solid impurity through eccentric action; proceeding rotary evaporation condensation for the extract; dissolving fitful residue as solvent; purifying through the special right mixed purifying agent to analyze the sampling usage for instrument. The invention can extract object compound with different chemical properties effectively.

A disclosed rapid determination method for multiple component contents in mold flux comprises the following steps: 1) carbon-removing pretreatment on mold flux; 2) sample dissolving by microwave digestion; 3) preparation of standard solutions of to-be detected components; 4) drafting of standard curves; and 5) determination on contents of the various components in mole flux. By combining microwave digestion sample dissolving technology and inductively coupled plasma emission spectrometry, the multiple component contents in mold flux are determined by one time; the rapid determination method has the advantages of being complete and rapid in reaction and low in blank value; the use amount of an agent is reduced by 50% or more; because microwave digestion is performed under the enclosed condition, the loss of to-be determined elements is reduced and laboratory pollution is reduced; the temperature is strictly controlled in the process of digestion, so that the accuracy of determination results is guaranteed; and the determination result is accurate and reliable, the operation is simple, the analysis speed is improved by 50% or more, the determination period is substantially shortened, and the rapid determination method satisfies comprehensive utilization of mold flux and practical operational requirements in production field.

A microwave ablation system incorporates a microwave thermometer that couples to a microwave transmission network connecting a microwave generator to a microwave applicator to measure noise temperature. The noise temperature is processed to separate out components the noise temperature including the noise temperature of the tissue being treated and the noise temperature of the microwave transmission network. The noise temperature may be measured by a radiometer while the microwave generator is generating the microwave signal or during a period when the microwave signal is turned off. The microwave ablation system may be configured as a modular system having one or more thermometry network modules that are connectable between a microwave applicator and a microwave generator. Alternatively, the modular system includes a microwave generator, a microwave applicator, and a microwave cable that incorporate a microwave thermometry network module.

The invention relates to the field of medical jurisprudence inspection, in particular to a diatom inspection method in medical jurisprudence. The method at least comprises the following steps: (1) microwave digestion: adding concentrated nitric acid and hydrogen peroxide solution into the inspected sample to carry out microwave digestion; (2) vacuum filtration: carrying out vacuum filtration on the digestion solution, adding ultrapure water, carrying out vacuum filtration continually until the surface of the filter membrane is approximately neutral, adding absolute ethyl alcohol, and carrying out vacuum filtration to remove moisture from the filter membrane; (3) a scanning electron microscope automatically takes pictures and stores the pictures; and (4) qualitative and quantitative analysis on diatom: carrying out inspection, classification and statistic treatment on the diatom in the on-spot pictures in an artificial identification way or computer automated identification way. The invention has the advantages of high detection sensitivity, high accuracy of qualitative and quantitative analysis, simpleness, high efficiency and environmental protection, can effectively avoid pollution, greatly improves the working environment for diatom inspection technicians in medical jurisprudence, and reduces the labor intensity, thereby having wide application prospects in drowning diagnosis practice in medical jurisprudence.

The invention discloses a method for detecting of the heavy metal lead content of the teas, the major steps include that: the tea samples to be measured are carried out the microwave digestion in the presence of H2O2 and nitric acid with a certain proportion, 0.1mol/L of NH4Cl solution dilution digestion liquid is used, the mercury plating liquid is added till the concentration of mercury ions in the solution achieves 4 multiplied by 10 to <4>mol/L, and the solution is detected by combining a screen-printing electrode with a data collection and processing system. The invention applies the electrochemical analysis method, adopts the three-electrode-to-one screen-printing electrode, uses the method of mercury plating in situ and takes the square wave stripping voltammetry as the tection method, so the invention has the advantages of simple, rapid, sensitive, accurate and economic.

The invention relates to a method for analyzing and measuring typical metal in a circuit board of discarded electrical equipment and relates to the technology for pre-treating the circuit board of discarded electrical equipment and detecting and analyzing the content of the typical metal element. The method comprises the following steps: collecting a sample of the circuit board part of discarded electrical equipment and then performing the operations of surface dressing, cleaning, and rough and fine grinding on the sample; adding a proper amount of digestion reagent into the prepared sample, digesting the prepared sample by using a microwave digestion device and then extracting metal matter from the discarded circuit board; and using an inductively coupled plasma emission spectrometer to analyze the nature and quantity of the digested sample. According to the method, the operations of sample grinding and digesting are simple, the reagent consumption is less, the analysis result is accurate and reliable, the detection concentration range is wide, the technical problem of difficultly pre-treating the circuit board sample is solved, and the method is suitable for quickly identifying and accurately measuring the typical metal elements in the circuit boards of various discarded electrical products (such as televisions, refrigerators, washing machines, computers, printers, and the like) and the typical metal elements in the corner wastes generated in the circuit board production process.

The invention discloses a method of digesting, settling and separating tungsten-based samples and a detection method for tungsten-based samples. The method of digesting, settling and separating tungsten-based samples comprises the following steps: putting a tungsten-based sample in a container, adding water and nitric acid into the container, keeping the container airtight, carrying out microwavedigestion and settlement-separation on the sample under gradient temperatures, and restarting microwave for rinsing and deposition after the temperature of the solution decreases and is close to the boiling point of water so as to obtain a sample solution for detection and precipitates of tungstic acid. The detection method for tungsten-based samples in the invention is to analyze the digested sample solution with at least one analytical method selected from the group consisting of inductively coupled plasma mass spectrometry, inductively coupled plasma atomic emission spectrometry, flame atomic absorption spectrometry, graphite oven atomic absorption spectrometry and spectrophotometry so as to obtain the content of elements in the tungsten-based sample.

The invention relates to a carbon/silicon/carbon composite material and preparation method and application thereof. The composite material takes a carbon material as a core, and a nanometer silicon layer and a nanometer carbon layer wrap a surface of the carbon material. According to the preparation method of the carbon/silicon/carbon composite material, a silicon oxide layer is coated on the surface of the carbon material by a mode of absorbing organosilane with microwave, the preparation period is greatly shortened, and the production efficiency is improved; a silicon oxide is reduced to silicon by mechanical ball-grinding of nanometer metal particles with high reduction performance under a room temperature, and the energy consumption is reduced; and a carbon layer is coated on a siliconlayer by high-temperature roasting to obtain the carbon/silicon/carbon composite material. During the charge-discharge process of the carbon/silicon/carbon composite material, the volume change of asilicon electrode material can be effectively controlled, the electrode structure is maintained complete, and the carbon/silicon/carbon composite material is large in cycle capacity and long in service lifetime and has wide application market.