Makrolon/modified polyester blending rolling base material and preparation method thereof

A technology of polycarbonate and calendered substrates, applied in the field of calendered substrates, can solve problems such as low heat-resistant softening point, poor processing performance, and environmental pollution, and achieve high Vicat softening point, good printing performance, and high surface quality Effect

Inactive Publication Date: 2011-12-21
上海达凯塑胶有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] ID cards, transportation cards, etc. are important documents that are indispensable in people's daily life. The card base materials for the above-mentioned documents are usually made of polyvinyl chloride or polyvinyl chloride blend materials, although they have high flame retardancy, etc. Advantages, but it also has the disadvantages of low heat-resistant softening point, low impact resistance, easy to produce toxic substances after decomposition, serious environmental pollution, non-wear resistance, poor processing performance, etc., which cannot meet the high heat resistance and high impact resistance of materials in the high-end market. , high wear resistance and environmental performance requirements

Method used

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  • Makrolon/modified polyester blending rolling base material and preparation method thereof
  • Makrolon/modified polyester blending rolling base material and preparation method thereof
  • Makrolon/modified polyester blending rolling base material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Recipe: (weight)

[0035] Polycarbonate 61.32%

[0036] Modified copolyester 18.33%

[0037] Modified copolyester additive 7.97%

[0038] Compatibilizer 4051 3.07%

[0039] Titanium dioxide 6.13%

[0040] Calcium Carbonate 3.12%

[0041] Everlasting Violet 0.06%

[0042] The raw materials are respectively metered into the kneader, kneaded at a temperature of 115°C, the kneader speed is 600 rpm, then cooled and stirred at a temperature of 85°C, and then calendered by a five-roller calender. The processing temperatures are: 1 Roll No. 190°C, Roll No. 2 200°C, Roll No. 3 210°C, Roll No. 4 205°C, Roll No. 5 200°C.

[0043] Prepare the calendered base material for smart cards with the thickness and squareness shown in Table 1, and use the Q / GHJN1-2004 standard for detection, and the technical parameters of the front and back sides are shown in Table 2; use the Q / GHJN 1-2004 standard for detection , and the mechanical properties are shown in Table 3.

[0044] Table 1 ...

Embodiment 2

[0051] Recipe: (weight)

[0052] Polycarbonate 64.37%

[0053] Modified copolyester 15.25%

[0054] Modified copolyester additive 5.64%

[0055] Compatibilizer 4051 4.00%

[0056] Titanium dioxide 5.34%

[0057] Calcium Carbonate 5.35%

[0058] Ultramarine 504 0.05%

[0059] The raw materials are respectively metered into the kneader, kneaded at a temperature of 120 ° C, the kneader speed is 650 rpm, and then cooled and stirred at a temperature of 95 ° C, and then calendered by a five-roller calender. The processing temperatures are: 1 Roll No. 200°C, Roll No. 2 210°C, Roll No. 3 220°C, Roll No. 4 215°C, Roll No. 5 210°C

[0060] Prepare the calendered base material for the smart card into the thickness and squareness shown in Table 4, and use the Q / GHJN1-2004 standard for testing, and the technical parameters of the front and back sides are shown in Table 5; use the Q / GHJN 1-2004 standard for testing , the mechanical properties are shown in Table 6.

[0061] Table 4 T...

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Abstract

The invention provides a markrolon / modified polyester blending rolling base material and a preparation method thereof. The markrolon / modified polyester blending rolling base material comprises the following components by weight percent: 55-65% of makrolon, 15-20% of modified polyester, 4-8% of modified copolyesters additive, 3-5% of compatilizer 4051, 4-7% of titanium white, 2-6% of calcium carbonate and 0.01-0.1% of pigment. The vicat softening point of the invention can be 115 DEG C+ / -2 (50-5kg of vicat A), the tensile strength is larger than 45Mpa, the tensile yield strength is larger than750KJ / m<2>; and the invention meets the rolling technology requirement by improving the formula lubrication systems, can meet the requirement of the processes such as material application, card making technology of smart card base materials and the like.

Description

technical field [0001] The invention relates to a calendered base material with polycarbonate / modified copolyester as the main material. Background technique [0002] ID cards, transportation cards, etc. are important documents that are indispensable in people's daily life. The card base materials for the above-mentioned documents are usually made of polyvinyl chloride or polyvinyl chloride blend materials, although they have high flame retardancy, etc. Advantages, but it also has the disadvantages of low heat-resistant softening point, low impact resistance, easy to produce toxic substances after decomposition, serious environmental pollution, non-wear resistance, poor processing performance, etc., which cannot meet the high heat resistance and high impact resistance of materials in the high-end market. , high wear resistance and environmental performance requirements. Contents of the invention [0003] The technical problem to be solved in the present invention is to di...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L69/00C08L67/00C08K13/02C08K3/22C08K3/26C08K5/10B29C43/58
Inventor 钱铭义
Owner 上海达凯塑胶有限公司
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