Shoe press belt for papermaking
A shoe-shaped press, polyurethane layer technology, applied in the direction of paper making, paper machine, pressing part, etc., can solve the problem of harsh use environment of shoe-shaped press belts
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[0054] Hereinafter, in order to evaluate the physical properties of the polyurethane forming the shoe press belt, a polyurethane test piece was produced.
reference example 1
[0056] Urethane prepolymer obtained by reacting p-phenylene diisocyanate (PPDI) with polytetramethylene glycol (PTMG) (NCO% is 5.51%, viscosity at 55°C is 1,800cps, preheating temperature Is 66°C), and a curing agent mixture composed of 97 mol% of 1,4-butanediol (1,4-BD) and 3 mol% of trimethylolpropane (TMP) (H / NCO equivalent ratio 0.95), the mixture was poured into a mold preheated to 127°C, heated to 127°C, the upper mold was removed from the mold after 0.5 hours of pre-curing at this temperature, and 16 hours at 127°C Post-curing was performed to obtain a cured polyurethane sheet having a JIS A hardness of 98.1 degrees. Using this sheet, a test piece (thickness: 3.4 mm) was produced.
reference example 2
[0058] The urethane prepolymer obtained by reacting 4,4'-methylene bis(phenyl isocyanate) (MDI) and polytetramethylene glycol (PTMG) (NCO% is 8.85%, at 100°C) The viscosity is 400cps, the preheating temperature is 80℃), and the curing is composed of 97 mol% of 1,4-butanediol (1,4-BD) and 3 mol% of trimethylolpropane (TMP) The agent mixture is mixed (H / NCO equivalent ratio is 0.90), the mixture is poured into a mold preheated to 115°C, heated to 115°C, and the upper mold is removed from the mold after curing at this temperature for 1 hour Further, post-curing was performed at 115°C for 16 hours to obtain a cured polyurethane sheet having a JIS A hardness of 92.2 degrees. Using this sheet, a test piece (thickness: 3.4 mm) was produced.
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