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Deep processing method of titanium slag

A technology of deep processing and titanium slag, applied in the field of comprehensive recovery of coal-based direct reduction, can solve the problems of poor selectability, high production cost, and many impurities, and achieve improved crystallization degree, high added value of products, and good economic benefits Effect

Active Publication Date: 2013-04-10
SICHUAN LOMON MINING & METALLURGY +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The advantage of this method is that the process flow is relatively simple, and the disadvantage is that the electric furnace slag TiO 2 The grade is 45%, there are many impurities, high acid consumption, and a large amount of three wastes, so the production of titanium dioxide is seriously polluted, the production cost is high, and the economic benefit is poor
In order to provide high-quality raw materials for the production of titanium dioxide, a titanium selection test was carried out on the direct reduction electric furnace smelting slag of vanadium-titanium magnetite. The study found that the titanium mineral phase and other mineral phases in the electric furnace smelting slag have fine grains and poor crystallization differentiation. Grinding and dissociation is difficult, and the options are poor

Method used

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  • Deep processing method of titanium slag
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Experimental program
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Effect test

Embodiment 1

[0032] Before the vanadium-titanium magnetite electric furnace smelts the slag, the temperature of the titanium-containing electric furnace slag is raised to 1750°C, and the temperature is kept for 10 minutes. The thermal insulation device can be a slag bag with a thermal insulation layer, and the thermal insulation slag bag can be provided with a layer of refractory and heat insulating bricks. After the titanium-containing electric furnace slag is naturally cooled to 1100°C in the thermal insulation device, the electric furnace Separation of crystal growth device, natural cooling to room temperature, crushing, grinding to 45μm, flotation of titanium, titanium concentrate TiO 2 Grade 80.13%, TiO 2 The recovery rate was 72.36%.

Embodiment 2

[0034] Before the slag is smelted in the vanadium-titanium magnetite electric furnace, the temperature of the titanium-containing electric furnace slag is raised to 1700 ° C, kept for 15 minutes, the slag outlet is opened, and the slag is placed in the heat preservation device for the electric furnace slag heat preservation mineral growth, and the temperature is naturally lowered to After 1000°C, separate the electric furnace slag from the thermal insulation crystal growth device, water-cool to room temperature, crush, grind to 55μm, and float titanium and titanium concentrate TiO 2 Grade 77.69%, TiO 2 The recovery rate is 74.65%.

Embodiment 3

[0036] Before the slag is smelted in the vanadium-titanium magnetite electric furnace, the temperature of the titanium-containing electric furnace slag is raised to 1650°C, kept for 20 minutes, the slag outlet is opened, and the slag is put into the electric furnace slag heat preservation crystal growth device for electric furnace slag heat preservation mineral growth , after natural cooling to 1000°C, separate the electric furnace slag from the thermal insulation growth device, cool naturally to room temperature, crush and grind to 65 μm, and select titanium by flotation, titanium concentrate TiO 2 Grade 72.93%, TiO 2 The recovery rate is 76.29%.

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Abstract

The invention relates to a deep processing method of titanium slag, which comprises the following steps: carrying out the heat preservation after the electrical furnace slag containing titanium is heated before deslagging by utilizing the high-temperature heat of the electrical furnace titanium slag; placing the slag into a heat-preservation crystal growing device for the electrical furnace slag anosovite to be naturally cooled; and growing mineral crystal grains of anosovite in the electrical furnace slag through heat preservation and slow cooling so as to establish the foundation for obtaining anosovite type high-titanium raw materials with high quality through crushing, ore grinding, dissociating and floatation. in the deep processing method provided by the invention, the physical heatof the electrical furnace titanium slag is only utilized and simultaneously a physical separation method at the later stage is adopted to obtain the slag with high titanium content, and the slag withhigh titanium content is suitable for being taken as the raw material of the electrical furnace slag anosovite and the raw material of titanium white by utilizing a chlorination method. The method can effectively enhance the average particle size of the electrical furnace slag anosovite from about 10 mu m to 80-90 mu m, can enhance the mineral crystallization differentiation degree of the electrical furnace smelting slag, and optimizes the substance composition of the electrical furnace slag mineral phase, thereby having good separation properties of the electrical furnace smelting slag, and the produced titanium ore concentrate TiO2 has the grade of 72-80% and has the advantages of high product additional value, low energy consumption and good economic benefit.

Description

technical field [0001] The invention belongs to the field of comprehensive recovery of coal-based direct reduction, in particular to a deep processing method for smelting titanium slag in an electric furnace of vanadium-titanium magnetite and ilmenite. Background technique [0002] Titanium dioxide is considered to be a white pigment with the best performance in the world, and it is widely used in coatings, plastics, papermaking, printing ink, chemical fiber, rubber, cosmetics and other industries. China is currently the second largest consumer of titanium dioxide after the United States, and the growth momentum is rapid and the potential is also very large. With the development of the national economy and the improvement of people's living standards, the market demand will increase sharply. The quality and benefit of titanium dioxide production are closely related to the raw material grade of titanium dioxide. [0003] The distribution rate of titanium in the vanadium-tit...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22B7/04
CPCY02P10/20
Inventor 傅文章洪秉信范先国胡晓王建冲黄建平
Owner SICHUAN LOMON MINING & METALLURGY
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