Surface glaze, white enamel and preparation method thereof

A surface glaze and enamel technology, applied in the field of enamel, can solve the problems of unstable color of the porcelain surface, heat resistance of organic antibacterial agents, influence on human health, etc., and achieve the effect of good antibacterial and antifungal effect and stable color.

Inactive Publication Date: 2011-06-08
SHIJIAZHUANG ZHENGZHONG TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, enamel has poor anti-bacteria and mold performance, and will absorb various harmful bacteria and molds, which will affect human health.
The antibacterial agents used by people are organic antibacterial agents and inorganic antibacterial agents. Among them, organic antibacterial agents are not heat-resistant and suitable for processing temperatures below 300 ° C. They are not suitable for high-temperature processing of enamel products. After the conventional glaze making method and commonly used materials are fused into porcelain blocks, the color of the porcelain surface is unstable or the antibacterial effect is poor due to reasons such as redox or its own color.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0018] The invention provides a method for preparing white surface glaze, which uses Na 2 O-B 2 O 3 -SiO 2 -F is glass substrate, TiO 2 As an opacifier, it includes the following steps:

[0019] a) Will contain 10%~20% Na by weight 2 O, 8%~25%B 2 O 3 , 35%~55% SiO 2 , 15%~25%TiO 2 , 1%~5%CaF 2 , 0%~3%MgO, 0.05%~2%CuO, 0.5%~4%P 2 O 5 , 0%~5%CaO, 1%~6%Al 2 O 3 The raw materials are mixed and melted at 1200℃~1300℃, and water quenched into a frit with a diameter of 1mm~3mm. Among them, CuO can be antibacterial and mildew proof, but Cu is a non-ferrous metal. Adding 1 / 1000 will make the white porcelain layer appear blue. Blue, while TiO 2 During firing, white anatase will be generated, and yellow rutile will inevitably be generated. Cyan and yellow are complementary colors. Therefore, when the amount of CuO is added, the generated cyan and yellow will be complementary. Weaken or disappear, so that the whole porcelain layer is still white, and after firing into the porcelain layer, Cu 2...

Embodiment 1

[0024] Will contain 16.5% Na by weight 2 O, 10% B 2 O 3 , 40% SiO 2 , 25%TiO 2 , 3%CaF 2 , 1% MgO, 0.5% CuO, 1% P 2 O 5 , 3% Al 2 O 3 After mixing, the raw materials are melted at 1200°C, and water quenched into a frit with a diameter of 1mm to 3mm.

[0025] The mass ratio is 100:3:6:0.4:48 frit, nano-ZnO, clay, K 2 CO 3 It is ground with water to form a surface glaze slurry, and then the surface glaze slurry is sprayed on a metal blank with a base glaze, and fired at 800°C to obtain an enamel with a white porcelain layer.

Embodiment 2

[0027] Will contain 20% Na by weight 2 O, 15% B 2 O 3 , 34% SiO 2 , 20% TiO 2 , 4%CaF 2 , 1% CuO, 1% P 2 O 5 , 5% Al 2 O 3 After mixing, the raw materials are melted at 1250°C, and water quenched into a frit with a diameter of 1mm to 3mm.

[0028] Grind the frit with a mass ratio of 98:1.5:5:0.4:43, nano-ZnO, bentonite, KCl and water into a top glaze slurry, and then spray the top glaze slurry on the metal billet with a base glaze at 820℃ Fire down to obtain an enamel with a white porcelain layer.

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Abstract

The invention provides a method for preparing an enamel surface glaze. The method comprises the following steps of: (a) mixing the following raw materials in percentage by weight: 10-20 percent of Na2O, 8-25 percent of B2O3, 35-55 percent of SiO2, 15-25 percent of TiO2, 1-5 percent of CaF2, 0-3 percent of MgO, 0.05-2 percent of CuO, 0.5-4 percent of P2O5, 0-5 percent of CaO, and 1-6 percent of Al2O3, melting at 1200-1300 DEG C and quenching in water to be fusion cakes with the diameter of 1-3 mm; and (b) grinding the nano ZnO with the prepared fusion cakes, a suspending agent, an electrolyte and water in a milling addition mode into the surface glaze. The enamel surface glaze provided by the invention is doped with CuO and added with ZnO in a milling way, and the coating of the prepared enamel has favorable bacterium and mildew resistance, white color and stable luster.

Description

Technical field [0001] The invention relates to the field of enamel, in particular to a preparation method of surface glaze slurry, white enamel, and surface glaze slurry and white enamel. Background technique [0002] Porcelain enamel is a composite material in which inorganic vitreous materials are fused to the base metal and firmly combined with the metal. The coating of enamel is generally composed of two layers. The layer in contact with the metal blank is the intermediate layer, that is, the base glaze. The base glaze is a transition layer that combines with the metal blank. It has strong adhesion. The top glaze is coated on the base glaze. On top, it can cover the background color and give the product a smooth and beautiful surface and excellent physical and chemical properties. Traditional enamel products are widely used in daily life, medicine, chemical industry, environmental protection and other fields. They have good physical and chemical properties, inherent mechani...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C8/16C23D5/00
Inventor 丁文战陆介平
Owner SHIJIAZHUANG ZHENGZHONG TECH
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