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Alkaloid composite filter tip addition material capable of reducing hydrocyanic acid in cigarette mainstream smoke

A technology for mainstream cigarette smoke and adding materials, applied in e-liquid filter, tobacco, food science and other directions, can solve the problems of reducing the release of hydrocyanic acid, no reports, etc., and achieve the effect of fast and stable adsorption capacity

Inactive Publication Date: 2012-12-05
CHONGQING CHINA TOBACCO IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The absorption method mainly adopts alkali absorption and complex absorption. Since all of them are absorbed by chemical reagents, the additive has potential smoking safety problems (such as patent document CN101669678). Use trimethylaminoacetylhydrazide chloride or (2-bromoethyl) trimethyl ammonium bromide, patent document CN101524186 uses transition metal hydrochloride), the adsorption method mainly uses granular activated carbon, silica gel and metal oxides to adsorb hydrogen cyanide, but activated carbon fibers treated with alkaloids are used in cigarette filters at the same time The use of absorption and adsorption methods to reduce the release of hydrocyanic acid in mainstream cigarette smoke has not been reported, and because the appearance of activated carbon fibers is similar to that of acetate fibers, it is relatively easy to meet the requirements for use on filters, so the invention of activated carbon fibers Making alkaloid composite cigarette filter after modification

Method used

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  • Alkaloid composite filter tip addition material capable of reducing hydrocyanic acid in cigarette mainstream smoke
  • Alkaloid composite filter tip addition material capable of reducing hydrocyanic acid in cigarette mainstream smoke

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preparation example Construction

[0016] General preparation method of the present invention is as follows:

[0017] 1. Combining one or more Chinese herbal medicines in the above-mentioned Coptis chinensis, Phellodendron phellodendri, three needles, and Huangtian bamboo in any proportion as the extraction raw material of plant alkaloids, extracting the alkaloids by acid water extraction, and drying them by crystallization Made into powder.

[0018] 2. Heat the alkaloid additive to 0.01% to 0.1% (mass percentage) sodium hydroxide solution to dissolve at 40°C. The amount of alkaloid dissolved is 0.1% to 15% of the weight of the activated carbon fiber carrier in advance.

[0019] 3. Put the activated carbon fiber in the 40°C solution prepared in Embodiment 3, soak it at a constant temperature and stir it for 1-2 hours, filter and wash it, and dry it in an oven at 60-100°C for 1-2 hours to obtain the activated carbon fiber loaded with alkaloids Material.

[0020] 4. Add the prepared filter tip additive materia...

Embodiment 1

[0023] The specification 1 (specific surface area 1250m 2 / g,) of viscose-based activated carbon fiber is used as a composite filter additive material, loaded with 10% of the selected activated carbon fiber weight Phellodendron alkaloid, and then heated to 40 Dissolve at ℃, use activated carbon fiber of specification 1 to absorb alkaloids in the solution, filter, and dry. The amount of activated carbon fiber material added is 20 mg / cig. Cigarettes without any filter modification materials are used as reference products, and smoked according to the standard Conditions The cigarette smoking test was carried out on a smoking machine, and the amount of hydrocyanic acid released was tested according to the standard YC / T 253-2008, and the amount of tar was tested according to the standard GB / T 19609-2004. Two parallel samples were taken for each sample, and the results are shown in Table 1.

[0024] Table 1 The results of material 1 reducing the amount of hydrocyanic acid releas...

Embodiment 2

[0028] The specification 2 (specific surface area 1500m 2 / g) of viscose-based activated carbon fiber is used as a composite filter additive material, and the load is selected from alkaloids with 12% weight of activated carbon fibers. After mixing in proportion, extract plant alkaloids, heat the extracted alkaloids with 0.01% to 0.1% (mass percentage) sodium hydroxide solution to 40°C to dissolve, use specification 2 activated carbon fibers to absorb the alkaloids in the solution, filter ,dry. The dosage of the activated carbon fiber material is 18 mg / cig, and the cigarette without any filter modified material is used as the reference substance, and the cigarette smoking test is carried out on the smoking machine according to the standard smoking conditions, and according to the standard YC / T 253- In 2008, the release of hydrocyanic acid was tested, and the amount of tar was tested according to the standard GB / T 19609-2004. There were two parallel samples for each samp...

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Abstract

The invention relates to filter tip addition material capable of selectively reducing the release amount of hydrocyanic acid in cigarette mainstream smoke and a preparation method thereof, new material which can effectively adsorb acidic gas can be obtained by loading plant alkaloids onto activated carbon fiber, the alkaloids are extracted from one or multiple Chinese herbal medicines of golden thread, amur corktree bark, root of Anhwei barberry and leatherleaf mahonia leaf and have anti-bacterial and anti-tumor activity, the extracted alkaloids are dissolved in 0.01%-0.1% of sodium hydroxidesolution and loaded on the activated carbon fiber by heating and stirring, then water washing and drying are further performed, and modified activated carbon fiber material containing basic groups isfinally obtained. The material is added into cigarette filter sticks and can reduce the content of the hydrocyanic acid in the cigarette mainstream smoke by more than 25%, and reduce the tar content by more than 25%, and an alkaloid additive has the characteristics of high boiling point, no smell, safety in administration and the like; simultaneously, as the selected activated carbon fiber material can stably adhere the alkaloids, the adverse effects to the organoleptic quality of cigarettes can be avoided, and the purposes of reducing harm and reducing tar can be further achieved.

Description

technical field [0001] The invention belongs to the technical field of cigarette materials, and in particular relates to a filter tip additive material for selectively reducing the release of hydrocyanic acid and tar in mainstream smoke of cigarettes, a preparation method and application thereof. Applying the material to cigarette filters can effectively reduce the content of hydrocyanic acid and tar in mainstream smoke without negatively affecting the sensory quality of cigarettes. Background technique [0002] Hydrocyanic acid (HCN) is a colorless toxic gas or liquid with a bitter almond smell. It has a low boiling point and is volatile. It exists in the form of a gas at room temperature. The threshold value of human body is only 10ppm. It is a very active inhibitor of several human respiratory enzymes. At the same time, it can combine with ferricytochrome oxidase in the human body to generate cyanide ferricytochrome oxidase and lose the function of transferring oxygen, ca...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): A24D3/06A24D3/10D06M13/00D06M101/40
Inventor 吴金凤李学刚
Owner CHONGQING CHINA TOBACCO IND CO LTD
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