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Iron-carbon micro-electrolysis-dynamic membrane wastewater deep treatment process

A technology of iron-carbon micro-electrolysis and treatment process, which is applied in the direction of water/sewage multi-stage treatment, water/sludge/sewage treatment, chemical instruments and methods, etc. Agglomeration and other problems can be achieved to improve the removal effect, improve the filtration flux, and achieve the effect of long operation cycle

Active Publication Date: 2012-03-14
TONGJI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, the main problem in the actual operation of micro-electrolysis is that after a period of operation of the iron filings processing device, a passivation film is formed on the surface of the filler, and the iron filings are easy to agglomerate and channeling occurs, which greatly reduces the treatment effect; micro-electrolysis treatment Wastewater is usually carried out under acidic conditions, resulting in a large amount of iron dissolution, and at the same time adding alkali to neutralize a large amount of precipitated substances

Method used

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Examples

Experimental program
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Effect test

Embodiment 1

[0028] Printing and dyeing wastewater treatment

[0029] During the implementation process, it was carried out in a printing and dyeing factory. The water quality of the inflow and outflow of the experiment is shown in Table 1.

[0030]

[0031] Table 1 Process inlet and outlet water quality

[0032] project COD (mg / L) pH Chroma (times) Ammonia nitrogen (mg / L) Total phosphorus (mg / L) Conditioning pond raw water 426-580 7.5-8.0 800-1000 30-40 4-7 Micro-electrolysis pretreatment of effluent 158-207 7.3-8 20 12-14 0.3-0.8 Aerobic dynamic membrane effluent <50

8.02-8.09 <15

1.8-3.6 0.2-0.45

[0033] (1) Wastewater iron-carbon micro-electrolysis pretreatment

[0034] Use waste sulfuric acid to adjust the pH value of the raw wastewater to 5-6, enter the reaction tank filled with iron-carbon fillers and perform aeration, the dissolved oxygen is 2-3mg / L, and the residence time is 1.5h. After pretreatment, adjust the pH valu...

Embodiment 2

[0048] Coking wastewater treatment

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Abstract

The invention relates to an iron-carbon micro-electrolysis-dynamic membrane wastewater deep treatment process. The process comprises the following steps: pretreating pollutants in industrial wastewater by iron-carbon micro-electrolysis so as to remove partial pollutants and improve the biochemical performance of the wastewater; then, carrying out microorganism degradation by mainly using mixed liquids in a hydrolysis acidification pool and an aerobic dynamic membrane reaction pool so as to remove the pollutants; and finally, completing the solid-liquid separation and water discharge process of the mixed liquid with a dynamic membrane assembly. The invention aims at providing the iron-carbon micro-electrolysis-dynamic membrane wastewater deep treatment process which is simple in process flow and efficient; the process can be effectively used for removing the difficultly-degradable organic substances in the industrial wastewater and improving the biochemical performance of the wastewater, and has obvious decoloring effect and good solid-liquid separation effect; the effluent is clear and does not contain suspended particles; and the process is suitable for standard-reaching discharge and deep treatment of various industrial wastewaters (such as dyeing and printing wastewater, pharmaceutical wastewater, heavy metal wastewater, coking wastewater, paper-making wastewater and the like), and the index of the quality of the treated effluent can meet the water quality standard of reused water.

Description

technical field [0001] The invention belongs to the technical fields of degradation and removal of industrial wastewater pollutants and advanced treatment and reuse, and specifically relates to an iron-carbon micro-electrolysis-dynamic membrane advanced treatment process for industrial wastewater. Background technique [0002] According to the first national survey of pollution sources completed in 2010, the annual production of industrial wastewater in my country is 73.833 billion tons, the discharge volume is 23.673 billion tons, and the annual wastewater treatment volume is 45.852 billion tons. The main pollutants produced in industrial wastewater: 31.4535 million tons of chemical oxygen demand, 2.0167 million tons of ammonia nitrogen, 541,500 tons of petroleum, 123,800 tons of volatile phenols, and 24,300 tons of heavy metals. my country's water resources are scarce, and the advanced treatment and reuse of industrial wastewater has become the choice of many regions as a ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/14
Inventor 张亚雷褚华强潘碌亭周雪飞
Owner TONGJI UNIV
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