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Biomass gasification-activation combination and preparation method of active porous carbon material

A biomass carbon and porous carbon technology, applied in chemical instruments and methods, inorganic chemistry, carbon compounds, etc., can solve the problem of high tar content, and achieve the effect of prolonging the cracking time, long contact time and good activation effect.

Active Publication Date: 2013-08-07
秦恒飞 +1
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] The purpose of the present invention is to provide a biomass gasification-activation furnace to solve the problem of high tar content in the biomass gasification product-combustible gas, and to use black water waste liquid and oxygen-containing gas as activators at the same time Activation reaction with biomass charcoal produces pure combustible gas and obtains activated carbon

Method used

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  • Biomass gasification-activation combination and preparation method of active porous carbon material

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Use wood chips as the raw material, convey the raw material into the feed port (2) by belt conveyor, turn on the leveler (4), level the material surface, start the induction fan (20) at the head of the activation furnace, start to ignite, and wait for the gasification layer When the temperature reaches 600°C, start the movable furnace screen (8) and rotate the activation furnace (11) at the same time, adjust the air volume of the induced draft fan through the frequency converter, and control the gasifier gas outlet temperature at 450-700°C. At this time, the tar and black water The waste liquid exists in the form of superheated steam, and then the steam of biomass charcoal, tar and black water waste liquid enters the activation furnace through the inlet (10). 800°C, the combustible gas produced passes through the waste heat boiler (19), and part of the water vapor obtained by exchanging heat between the high-temperature gas and the waste heat boiler is used to supply the...

Embodiment 2

[0024] Using sawdust and wood shavings as raw materials, the raw materials are sent into the feed port (2) by wind power, the leveler (4) is turned on, the material surface is leveled, the induced draft fan (20) of the activation furnace head is started, the ignition is started, and the heat is controlled. The delamination temperature is about 550°C, the gasification layer temperature reaches about 750°C, the activation furnace temperature is about 900°C, and the rest of the steps and methods are the same as in the first embodiment. The composition of the obtained combustible gas is: CO 2 9.8%, CO2 3.2%, H 2 18.9%, CH 4 5.2%, the calorific value of gas is 7.4MJ / Nm 3 ;Tar content is 5mg / Nm 3 , the methylene blue adsorption value of activated carbon is 11-15ml / 0.1g, the iodine adsorption value is 800-1000mg / g, and the BET specific surface area is 1086m 2 / g.

Embodiment 3

[0026] Use fruit tree branches as raw materials, convey the raw materials into the feed port (2) by belt conveyor, open the leveler (4), level the material surface, start the induction fan (20) at the activation furnace head, start ignition, and control the pyrolysis layer The temperature is about 600°C, the temperature of the gasification layer reaches about 850°C, the temperature of the activation furnace is about 900°C, and the rest of the steps and methods are the same as in the first embodiment. The composition of the obtained combustible gas is: CO 2 10.9%, CO26.7%, H 2 20.3%, CH 4 3.9%, the calorific value of gas is 7.6MJ / Nm 3 ;Tar content is 9mg / Nm 3 , the methylene blue adsorption value of activated carbon is 10-13ml / 0.1g, the iodine adsorption value is 800-1000mg / g, and the BET specific surface area is 987m 2 / g.

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Abstract

The invention belongs to the technical field of thermal conversion of biomass energy and specifically relates to a biomass gasification-activation combination for decoking and a preparation method of an active porous carbon material, in particular to a gasification-activation furnace which does not produce tar oil or black water waste liquor and the preparation method of the active porous carbon material. Compared with the traditional gasification process, no tar oil or black water waste liquor is produced, final products are combustible gas and active carbon, and the problems that black liquid exists in the traditional gasification technology for polluting a water source, the content of the tar oil in the combustible gas is high, the purification is difficult, a pipeline is blocked, a generator set can not operate normally continuously, the added value of a gasification product is low and the like are solved.

Description

technical field [0001] The invention belongs to the technical field of thermal conversion of biomass energy, and specifically relates to a method for preparing biomass gasification-activation combined decoking and active porous materials. Background technique [0002] At present, the main equipment of biomass gasification technology includes fixed-bed gasifier and fluidized-bed gasifier. The structure of current gasification equipment, combustible gas purification technology, and structure of purification equipment have been exposed during the pilot test and engineering process. Problems have hindered the promotion of biomass gasification technology. There are three main problems: First, although the gasification equipment is diverse, the adaptability is not strong. Different gasifiers have different requirements for the type of raw material, the particle size of the raw material, and the moisture content of the raw material, and the engineering has not been truly realized. ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01B31/10C10J3/62C10J3/66C10J3/60C10J3/86C01B31/08C10J3/84C01B32/336
CPCY02P20/129
Inventor 秦恒飞阙明华
Owner 秦恒飞