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Method for preparing magnesium alloy

A magnesium alloy and magnesium powder technology, applied in the field of metal materials, can solve problems such as difficult control of Si phase nucleation and growth, influence on the mechanical properties of magnesium alloys, coarse microstructure of heat-resistant magnesium alloys, etc., and achieve fine and uniform microstructure, microscopic The structure is uniform and fine, and the effect of improving the mechanical properties at room temperature

Active Publication Date: 2012-04-18
CHANGZHOU INST OF ENERGY STORAGE MATERIALS &DEVICES
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The microstructure of the Mg-Al-Si series heat-resistant magnesium alloy prepared by casting method in the prior art is coarse, and the Mg 2 The nucleation and growth process of the Si phase is difficult to control, resulting in the formation of Mg 2 The Si phase is large in size and appears in the shape of a thick Chinese character block, which leads to the unsatisfactory mechanical properties of this alloy at room temperature. The strength at room temperature is only about 240MPa, which is difficult to meet the continuous demand of modern industry for heat-resistant magnesium alloy materials.
[0005] Starting from the powder, the method of combining mechanical pulverization and powder metallurgy sintering is a common method for preparing high-performance alloy materials. Although the method of combining these two preparation technologies can control the microstructure of magnesium alloys, there are still Mg 2 The technical problem that the Si phase nucleation and growth process is not easy to control makes the generated Mg 2 The size of the Si phase is relatively large, appearing in the shape of a thick Chinese character block, and the use of powder metallurgy sintering technology will cause the oxidation of metal magnesium, so that a large amount of oxides are included in the alloy, which greatly affects the mechanical properties of the magnesium alloy

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preparation example Construction

[0023] The embodiment of the present invention discloses a method for preparing a magnesium alloy, comprising the following steps:

[0024] a) Mg 2 Si nano powder, zinc powder, aluminum powder and magnesium powder are high-energy ball milled for 1-2 hours to obtain a mixed powder, which includes: 2.2-3.6 wt% magnesium silicide, 0.5-1.5 wt% zinc, 4.5-5.5 wt% aluminum and 90.5-91.9wt% magnesium;

[0025] b) press-molding the mixed powder to obtain a green body;

[0026] c) heating the green body under the protection of an inert gas at a heating temperature of 420-450° C., keeping it warm for 30-50 minutes, extruding after heating, and water-cooling the extruded green body to obtain the final magnesium alloy.

[0027] In order to obtain fine reinforcement phase particles, the present invention directly adds heat-resistant phase magnesium silicide nano powder, and the magnesium silicide nano powder is obtained by ball milling micron-sized magnesium silicide powder. Compared wit...

Embodiment 1

[0043] a) 4.34 grams of magnesium silicide nano powder, 2 grams of zinc powder, 10 grams of aluminum powder and 183.66 grams of magnesium powder were mixed in a high-energy ball mill tank for 1.5 hours to obtain a mixed powder;

[0044] b) placing the mixed powder in a steel mold and applying a pressure of 300MPa to obtain a molded green body;

[0045] c) Place the shaped green body in a muffle furnace, heat it under argon gas at a temperature of 420° C., and keep it warm for 30 minutes, then take out the green body and place it in the extrusion cylinder of an extruder. 10:1, the extrusion speed is 1mm / s, the green body is extruded under the conditions of 600T pressure, and the magnesium alloy is obtained after water cooling.

[0046] After the magnesium alloy prepared in Example 1 was polished, its room temperature strength and strength at 150 degrees were tested, and the results are shown in Table 1.

[0047] Scanning electron microscope analysis is carried out to the magne...

Embodiment 2

[0049] a) 4.88 grams of magnesium silicide nano powder, 2 grams of zinc powder, 10 grams of aluminum powder and 183.12 grams of magnesium powder were mixed in a high-energy ball mill tank for 1.5 hours to obtain a mixed powder;

[0050] b) placing the mixed powder in a steel mold and applying a pressure of 320MPa to obtain a molded green body;

[0051] c) Place the shaped green body in a muffle furnace and heat it under argon at a heating temperature of 430°C. After holding the heat for 40 minutes, take out the green body and place it in the extrusion cylinder of the extruder. 10:1, the extrusion speed is 1mm / s, the green body is extruded under the conditions of 600T pressure, and the magnesium alloy is obtained after water cooling.

[0052] After the magnesium alloy prepared in Example 2 was polished, its room temperature strength and strength at 150 degrees were tested, and the results are shown in Table 1.

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Abstract

The invention provides a method for preparing a magnesium alloy. The method comprises the following steps of: a) performing high-energy ball milling on magnesium silicide nano powder, zinc powder, aluminum powder and magnesium powder for 1 to 2 hours to obtain mixed powder, wherein the mixed powder comprises 2.2 to 3.6 weight percent of magnesium silicide, 0.5 to 1.5 weight percent of zinc, 4.5 to 5.5 weight percent of aluminum and 90.5 to 91.9 percent of magnesium; b) pressing the mixed powder to form a blank; and c) heating the blank under the protection of inert gas at the temperature of between 420 and 450 DEG C, preserving the heat for 30 to 50 minutes, extruding after heating, performing water cooking on the extruded blank, and thus obtaining the magnesium alloy. The magnesium alloyprepared by directly adding the magnesium silicide nano powder into the raw materials and adopting the method of combining high-energy ball milling for preparing the powder and hot extruding has fineand uniform microstructure, reinforcing phase particles are uniformly distributed in the matrix structure, and the room temperature mechanical property of the magnesium alloy is improved.

Description

technical field [0001] The invention relates to the technical field of metal materials, in particular to a preparation method of a magnesium alloy. Background technique [0002] Magnesium alloy is an alloy composed of magnesium as the base and adding other elements. It is the third important metal structure material after steel and aluminum alloy. Due to the advantages of light weight, high specific strength, high specific stiffness, vibration damping, good electromagnetic shielding and radiation resistance, magnesium alloys play an important role in the fields of automobiles, electronic appliances, transportation, aerospace and national defense. role. [0003] Ordinary magnesium alloys have poor high-temperature mechanical properties. When the temperature rises, its strength decreases greatly, so it is difficult to use it at high temperature for a long time. Improving the high-temperature mechanical properties of magnesium alloys has been an important topic in magnesium a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C1/04C22C23/02
Inventor 汤华国马贤锋赵伟刘建伟
Owner CHANGZHOU INST OF ENERGY STORAGE MATERIALS &DEVICES
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