Preparation method of plastic product and plastic product

A technology for plastic products and plastics, applied in the field of surface metallization of non-metallic materials, can solve problems such as high energy requirements and complex metallization processes on plastic surfaces, and achieve the effects of low energy requirements, high binding force and low cost

Active Publication Date: 2012-06-13
BYD CO LTD
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Problems solved by technology

[0006] The present invention solves the technical problems of complex pla...

Method used

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preparation example Construction

[0015] The invention provides a kind of preparation method of plastic product, comprises the following steps:

[0016] 1) forming a plastic substrate; the plastic substrate is a thermoplastic or thermosetting plastic containing an electroless plating catalyst, and the electroless plating catalyst is evenly distributed in the thermoplastic or thermosetting plastic; the electroless plating catalyst is a compound shown in formula I, II or III;

[0017] CuFe 2 o 4-δ ................................... Formula I

[0018] Ca 0.25 Cu 0.75 TiO 3-β ................................Formula II

[0019] TiO 2-σ ...................................Formula III

[0020] Among them, δ is the degree of oxygen deficiency in the compound shown in formula I, 0.05≤δ≤0.8; β is the degree of oxygen deficiency in the compound shown in formula II, 0.05≤β≤0.5; σ is the degree of oxygen deficiency in the compound shown in formula III The degree of oxygen deficiency in the compound, 0.05≤σ≤1.0;

...

Embodiment 1

[0058] (1) Under continuous stirring, prepare Cu(NO 3 ) 2 and Fe(NO 3 ) 3 The mixed solution with a concentration of 0.5mol / L was dripped into the potassium hydroxide solution at a rate of 1ml / min with a peristaltic pump, and the temperature was rapidly raised to 80°C, and the stirring was continued for 24 hours. During the stirring process, the pH was kept within 10-11. The product was washed with distilled water and acetone, filtered, dried at 120°C for 24 hours, and ground to 300 mesh.

[0059] (2) Preparation of electroless plating catalyst:

[0060] In high purity N 2 The product of step (1) was calcined at 1000°C under protection for 4 hours, ground for 10 hours until the average particle size of the powder was 700nm, and the electroless plating catalyst CuFe of this embodiment was obtained. 2 o 4-δ , chemical analysis method to measure the degree of oxygen deficiency δ = 0.35.

[0061] (3) Plastic matrix molding:

[0062] With the CuFe of PC / ABS resin, step (2) ...

Embodiment 2

[0067] (1) Preparation of Ca by solid phase sintering method 0.25 Cu 0.75 TiO 3 :

[0068] CaCO3, CuO, TiO 2 The powder is dosed according to the stoichiometric ratio and mixed evenly, transferred to a ball mill for ball milling, using anhydrous alcohol as the grinding medium, milled for 8 hours, pre-calcined at 800°C for 10 hours after infrared drying, and obtained Ca 0.25 Cu 0.75 TiO 3 .

[0069] (2) Preparation of electroless plating catalyst:

[0070] Ca 0.25 Cu 0.75 TiO 3 , the calcination time is 4h, and the average particle size of the powder is ground to 500nm to obtain the electroless plating catalyst Ca of the present embodiment 0.25 Cu 0.75 TiO 3-β , chemical analysis method to measure the degree of oxygen deficiency β = 0.16.

[0071] 3) Plastic matrix molding:

[0072] The Ca of PP resin, step (2) 0.25 Cu 0.75 TiO 3-β (β=0.16), antioxidant 1076 and polyethylene wax are mixed in a mass ratio of 100:10:0.2:0.1, extruded and granulated, and injection...

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Abstract

The invention provides a preparation method of a plastic product and a plastic product. The method comprises steps of: 1) moulding a plastic matrix containing a chemical plating catalyst compound with a formula III; 2) removing plastic on a selected zone of the plastic matrix and exposing the chemical plating catalyst on a corresponding zone; 3) carrying out chemical copper facing or chemical nickel plating, continuing to carry out at least one time of chemical plating and / or electroplate to form a metal level on the plastic matrix surface. The preparation method provided by the invention has simple technology, low energy demand and low cost; besides, the chemical plating catalyst is distributed into the plastic matrix, so the coating formed after chemical plating has quite high bondingforce with the plastic matrix.

Description

[0001] This application is a divisional application with the applicant being BYD Co., Ltd., the filing date is August 19, 2010, the application number is 201010260236.0, and the invention title is "a preparation method of a plastic product and a plastic product". technical field [0002] The invention belongs to the field of surface metallization of non-metallic materials, and in particular relates to a preparation method of a plastic product and a plastic product. Background technique [0003] A metal layer is formed on the surface of the plastic, which is used as a channel for electromagnetic signal transmission, and is widely used in automobiles, industries, computers, communications and other fields. The selective formation of a metal layer on the plastic surface is a core link in the manufacture of such plastic products. There are many methods for plastic surface metallization production lines. In the prior art, metal nuclei are first formed on the surface of the plasti...

Claims

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Application Information

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IPC IPC(8): C23C18/20C23C18/16C23C18/38C23C18/32
Inventor 宫清周良苗伟峰张雄
Owner BYD CO LTD
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