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Automotive resin composition and its preparation method

A resin composition and composition technology, applied in the field of automotive thermoplastic resin composition and its preparation, resin composition and its preparation, can solve the problems of high elastomer price, affecting the heat resistance and rigidity of the composition, and achieve Excellent heat resistance and rigidity, ease of chain breakage, and low cost

Active Publication Date: 2014-03-05
SHANGHAI KUMHO SUNNY PLASTICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The above-mentioned prior art resin composition affects the heat resistance and rigidity of the composition due to the introduction of block copolymers or other elastomers
At the same time, the price of some elastomers is higher

Method used

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  • Automotive resin composition and its preparation method
  • Automotive resin composition and its preparation method
  • Automotive resin composition and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] In parts by weight, 70 parts of polypropylene, 30 parts of polystyrene, AlCl 3 0.1 part and 0.5 part of styrene monomer are placed in a single-screw extruder to prepare a masterbatch of a graft copolymer of polypropylene and polystyrene, the reaction temperature is controlled at 160-240° C., and the screw speed is 20-50 rev / min. The diameter of the screw of the single-screw extruder is 25 mm, and the ratio of length to diameter is 25, and nitrogen protection is set at the hopper of the extruder. In terms of parts by weight, 40 parts of polypropylene, 10 parts of polystyrene and 50 parts of the above-mentioned masterbatch are placed in a single-screw extruder, the processing temperature is controlled at 160-240 °C, and the screw speed is 20-50 rev / min. That is the graft copolymer of polypropylene and polystyrene.

Embodiment 2

[0031] In parts by weight, 70 parts of polyethylene, 30 parts of polystyrene, AlCl 3 0.1 part and 0.5 part of styrene monomer are placed in a single-screw extruder to prepare a masterbatch of a graft copolymer of polyethylene and polystyrene, and the reaction temperature is controlled at 160-240° C., and the screw speed is 20-50 rev / min. The diameter of the screw of the single-screw extruder is 25 mm, and the ratio of length to diameter is 25, and nitrogen protection is set at the hopper of the extruder. In terms of parts by weight, put 40 parts of polyethylene, 10 parts of polystyrene and 50 parts of the above-mentioned masterbatch into a single-screw extruder, control the processing temperature at 160-240 ° C, and the screw speed at 20-50 rev / min, That is, a graft copolymer of polyethylene and polystyrene is obtained.

Embodiment 3

[0034] Prepare raw materials according to the following components and parts by weight:

[0035]

[0036] in

[0037] The polyphenylene ether resin is poly(2,6-dimethyl-1,4-phenylene) ether;

[0038] The polyolefin resin is polypropylene;

[0039] The graft copolymer of polyalkenyl aromatic resin and polyolefin is polystyrene-g-polypropylene;

[0040] The impact modifier is SEBS;

[0041] The additive is an antioxidant.

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Abstract

The invention relates to an automotive thermoplastic resin composition and its preparation method. The composition contains the following ingredients of: by weight, 30-60 parts of polyphenylene oxide resin, 30-60 parts of polyene resin, 5-20 parts of poly(alkenyl aromatic) resin and polyolefin graft copolymer, 0-10 parts of a impact resistant modifier, and 0.2-1.0 part of an auxiliary. The preparation method of the composition comprises the following steps of: (a) mixing polyphenylene oxide resin, polyene resin, poly(alkenyl aromatic) resin and polyolefin graft copolymer, an additive and a processing aid to form a mixture; and (b) adopting a double screw extruder which is provided with two vacuum-pumping parts, arranging one vacuum-pumping device at the end of a conveying segment and at the beginning of a fusing segment, arranging the other vacuum-pumping device at the metering segment, and controlling the processing temperature within 200-280 DEG C. The automotive resin composition provided by the invention has advantages of good heat resistance, excellent ridigity, low price and simple method, and is suitable for continuous production.

Description

technical field [0001] The invention relates to a resin composition and a preparation method thereof, in particular to a thermoplastic resin composition for automobiles and a preparation method thereof. The invention belongs to the field of polymer materials and their molding processing. Background technique [0002] Polyphenylene ether resin (PPE) is an amorphous engineering plastic with excellent heat resistance, thermal creep resistance, electrical insulation, dimensional stability and hydrolysis resistance; however, PPE has high melt viscosity, difficult molding and poor oil resistance . Polyolefin resins are excellent in processability, oil resistance, water resistance, and acid and alkali corrosion resistance, but inferior in heat resistance, rigidity, and low-temperature impact resistance. Therefore, mixing polyphenylene ether resin and polyolefin resin to form a composition can improve the processability and oil resistance of polyphenylene ether resin and the heat r...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L71/12C08L23/12C08L23/06C08L23/16C08L87/00C08G81/02C08J3/22B29C47/92B29C48/92
CPCB29C48/92B29C2948/92019B29C2948/924B29C2948/92514B29C2948/9259B29C2948/92704B29C2948/92885B29C2948/92895
Inventor 单桂芳邱卫美周霆罗明华辛敏琦
Owner SHANGHAI KUMHO SUNNY PLASTICS